Gluing Ionic Liquids to Oxide Surfaces: Chemical Anchoring of Functionalized Ionic Liquids by Vapor Deposition onto Cobalt(II) Oxide

Autores
Xu, Tao; Waehler, Tobias; Vecchietti, María Julia; Bonivardi, Adrian Lionel; Bauer, Tanja; Schwegler, Johannes; Schulz, Peter S.; Wasserscheid, Peter; Libuda, Joerg
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Ionic liquids (IL) hold a great potential as novel electrolytes for applications in electronic materials and energy technology. The functionality of ILs in these applications relies on their interface to semiconducting nanomaterials. Therefore, methods to control the chemistry and structure of this interface are the key to assemble new IL-based electronic and electrochemical materials. Here, we present a new method to prepare a chemically well-defined interface between an oxide and an IL film. An imidazolium-based IL, which is carrying an ester group, is deposited onto cobalt oxide surface by evaporation. The IL binds covalently to the surface by thermally activated cleavage of the ester group and formation of a bridging carboxylate. The anchoring reaction shows high structure sensitivity, which implies that the IL film can be adhered selectively to specific oxide surfaces.
Fil: Xu, Tao. Universitat Erlangen-Nuremberg; Alemania
Fil: Waehler, Tobias. Universitat Erlangen-Nuremberg; Alemania
Fil: Vecchietti, María Julia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Bonivardi, Adrian Lionel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Bauer, Tanja. Universitat Erlangen-Nuremberg; Alemania
Fil: Schwegler, Johannes. Universitat Erlangen-Nuremberg; Alemania
Fil: Schulz, Peter S.. Universitat Erlangen-Nuremberg; Alemania
Fil: Wasserscheid, Peter. Universitat Erlangen-Nuremberg; Alemania
Fil: Libuda, Joerg. Universitat Erlangen-Nuremberg; Alemania
Materia
Chemical Anchoring
Cobalt Oxide
Ester Functionalization
Ionic Liquids
Vapor Deposition
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/63448
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/63448
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Gluing Ionic Liquids to Oxide Surfaces: Chemical Anchoring of Functionalized Ionic Liquids by Vapor Deposition onto Cobalt(II) OxideXu, TaoWaehler, TobiasVecchietti, María JuliaBonivardi, Adrian LionelBauer, TanjaSchwegler, JohannesSchulz, Peter S.Wasserscheid, PeterLibuda, JoergChemical AnchoringCobalt OxideEster FunctionalizationIonic LiquidsVapor Depositionhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Ionic liquids (IL) hold a great potential as novel electrolytes for applications in electronic materials and energy technology. The functionality of ILs in these applications relies on their interface to semiconducting nanomaterials. Therefore, methods to control the chemistry and structure of this interface are the key to assemble new IL-based electronic and electrochemical materials. Here, we present a new method to prepare a chemically well-defined interface between an oxide and an IL film. An imidazolium-based IL, which is carrying an ester group, is deposited onto cobalt oxide surface by evaporation. The IL binds covalently to the surface by thermally activated cleavage of the ester group and formation of a bridging carboxylate. The anchoring reaction shows high structure sensitivity, which implies that the IL film can be adhered selectively to specific oxide surfaces.Fil: Xu, Tao. Universitat Erlangen-Nuremberg; AlemaniaFil: Waehler, Tobias. Universitat Erlangen-Nuremberg; AlemaniaFil: Vecchietti, María Julia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Bonivardi, Adrian Lionel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Bauer, Tanja. Universitat Erlangen-Nuremberg; AlemaniaFil: Schwegler, Johannes. Universitat Erlangen-Nuremberg; AlemaniaFil: Schulz, Peter S.. Universitat Erlangen-Nuremberg; AlemaniaFil: Wasserscheid, Peter. Universitat Erlangen-Nuremberg; AlemaniaFil: Libuda, Joerg. Universitat Erlangen-Nuremberg; AlemaniaWiley VCH Verlag2017-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/63448Xu, Tao; Waehler, Tobias; Vecchietti, María Julia; Bonivardi, Adrian Lionel; Bauer, Tanja; et al.; Gluing Ionic Liquids to Oxide Surfaces: Chemical Anchoring of Functionalized Ionic Liquids by Vapor Deposition onto Cobalt(II) Oxide; Wiley VCH Verlag; Angewandte Chemie; 56; 31; 6-2017; 9072-90761433-7851CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://doi.wiley.com/10.1002/anie.201704107info:eu-repo/semantics/altIdentifier/doi/10.1002/anie.201704107info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:52:35Zoai:ri.conicet.gov.ar:11336/63448instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:52:36.132CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Gluing Ionic Liquids to Oxide Surfaces: Chemical Anchoring of Functionalized Ionic Liquids by Vapor Deposition onto Cobalt(II) Oxide
title Gluing Ionic Liquids to Oxide Surfaces: Chemical Anchoring of Functionalized Ionic Liquids by Vapor Deposition onto Cobalt(II) Oxide
spellingShingle Gluing Ionic Liquids to Oxide Surfaces: Chemical Anchoring of Functionalized Ionic Liquids by Vapor Deposition onto Cobalt(II) Oxide
Xu, Tao
Chemical Anchoring
Cobalt Oxide
Ester Functionalization
Ionic Liquids
Vapor Deposition
title_short Gluing Ionic Liquids to Oxide Surfaces: Chemical Anchoring of Functionalized Ionic Liquids by Vapor Deposition onto Cobalt(II) Oxide
title_full Gluing Ionic Liquids to Oxide Surfaces: Chemical Anchoring of Functionalized Ionic Liquids by Vapor Deposition onto Cobalt(II) Oxide
title_fullStr Gluing Ionic Liquids to Oxide Surfaces: Chemical Anchoring of Functionalized Ionic Liquids by Vapor Deposition onto Cobalt(II) Oxide
title_full_unstemmed Gluing Ionic Liquids to Oxide Surfaces: Chemical Anchoring of Functionalized Ionic Liquids by Vapor Deposition onto Cobalt(II) Oxide
title_sort Gluing Ionic Liquids to Oxide Surfaces: Chemical Anchoring of Functionalized Ionic Liquids by Vapor Deposition onto Cobalt(II) Oxide
dc.creator.none.fl_str_mv Xu, Tao
Waehler, Tobias
Vecchietti, María Julia
Bonivardi, Adrian Lionel
Bauer, Tanja
Schwegler, Johannes
Schulz, Peter S.
Wasserscheid, Peter
Libuda, Joerg
author Xu, Tao
author_facet Xu, Tao
Waehler, Tobias
Vecchietti, María Julia
Bonivardi, Adrian Lionel
Bauer, Tanja
Schwegler, Johannes
Schulz, Peter S.
Wasserscheid, Peter
Libuda, Joerg
author_role author
author2 Waehler, Tobias
Vecchietti, María Julia
Bonivardi, Adrian Lionel
Bauer, Tanja
Schwegler, Johannes
Schulz, Peter S.
Wasserscheid, Peter
Libuda, Joerg
author2_role author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Chemical Anchoring
Cobalt Oxide
Ester Functionalization
Ionic Liquids
Vapor Deposition
topic Chemical Anchoring
Cobalt Oxide
Ester Functionalization
Ionic Liquids
Vapor Deposition
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Ionic liquids (IL) hold a great potential as novel electrolytes for applications in electronic materials and energy technology. The functionality of ILs in these applications relies on their interface to semiconducting nanomaterials. Therefore, methods to control the chemistry and structure of this interface are the key to assemble new IL-based electronic and electrochemical materials. Here, we present a new method to prepare a chemically well-defined interface between an oxide and an IL film. An imidazolium-based IL, which is carrying an ester group, is deposited onto cobalt oxide surface by evaporation. The IL binds covalently to the surface by thermally activated cleavage of the ester group and formation of a bridging carboxylate. The anchoring reaction shows high structure sensitivity, which implies that the IL film can be adhered selectively to specific oxide surfaces.
Fil: Xu, Tao. Universitat Erlangen-Nuremberg; Alemania
Fil: Waehler, Tobias. Universitat Erlangen-Nuremberg; Alemania
Fil: Vecchietti, María Julia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Bonivardi, Adrian Lionel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Bauer, Tanja. Universitat Erlangen-Nuremberg; Alemania
Fil: Schwegler, Johannes. Universitat Erlangen-Nuremberg; Alemania
Fil: Schulz, Peter S.. Universitat Erlangen-Nuremberg; Alemania
Fil: Wasserscheid, Peter. Universitat Erlangen-Nuremberg; Alemania
Fil: Libuda, Joerg. Universitat Erlangen-Nuremberg; Alemania
description Ionic liquids (IL) hold a great potential as novel electrolytes for applications in electronic materials and energy technology. The functionality of ILs in these applications relies on their interface to semiconducting nanomaterials. Therefore, methods to control the chemistry and structure of this interface are the key to assemble new IL-based electronic and electrochemical materials. Here, we present a new method to prepare a chemically well-defined interface between an oxide and an IL film. An imidazolium-based IL, which is carrying an ester group, is deposited onto cobalt oxide surface by evaporation. The IL binds covalently to the surface by thermally activated cleavage of the ester group and formation of a bridging carboxylate. The anchoring reaction shows high structure sensitivity, which implies that the IL film can be adhered selectively to specific oxide surfaces.
publishDate 2017
dc.date.none.fl_str_mv 2017-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/63448
Xu, Tao; Waehler, Tobias; Vecchietti, María Julia; Bonivardi, Adrian Lionel; Bauer, Tanja; et al.; Gluing Ionic Liquids to Oxide Surfaces: Chemical Anchoring of Functionalized Ionic Liquids by Vapor Deposition onto Cobalt(II) Oxide; Wiley VCH Verlag; Angewandte Chemie; 56; 31; 6-2017; 9072-9076
1433-7851
CONICET Digital
CONICET
url http://hdl.handle.net/11336/63448
identifier_str_mv Xu, Tao; Waehler, Tobias; Vecchietti, María Julia; Bonivardi, Adrian Lionel; Bauer, Tanja; et al.; Gluing Ionic Liquids to Oxide Surfaces: Chemical Anchoring of Functionalized Ionic Liquids by Vapor Deposition onto Cobalt(II) Oxide; Wiley VCH Verlag; Angewandte Chemie; 56; 31; 6-2017; 9072-9076
1433-7851
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://doi.wiley.com/10.1002/anie.201704107
info:eu-repo/semantics/altIdentifier/doi/10.1002/anie.201704107
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley VCH Verlag
publisher.none.fl_str_mv Wiley VCH Verlag
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842269169552195584
score 13.13397

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