Rate coefficients at 298 K and 1 atm for the tropospheric degradationof a series of C6,C7and C8biogenic unsaturated alcohols initiated by Clatoms

Autores
Gibilisco, Rodrigo Gastón; Bejan, Iustinian; Barnes, Ian; Wiesen, Peter; Teruel, Mariano Andres
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Rate coefficients for the gas-phase reactions of Cl atoms with a series of unsaturated biogenic alcohols at 298 ± 3 K and 1 atm have been measured by the relative technique in an environmental chamber with in situ FTIR detection of reactants. The rate coefficients obtained using 1-butene and isobutene as reference compounds were (in units of 10−10 cm3 molecule−1 s−1): k1((E)-2-hexen-1-ol) = (3.49 ± 0.82), k2((E)-3-hexen-1-ol) = (3.42 ± 0.79), k3 ((Z)-3-hexen-1-ol) = (2.94 ± 0.72), k4((Z)-3-hepten-1-ol) = (3.80 ± 0.86) and k5((Z)-3-octen-1-ol) = (4.13 ± 0.68). This work constitutes the first kinetic study of the reactions cited above. The rate coefficients are compared with those for other unsaturated alcohols and a correlation between the reactivity of unsaturated alcohols toward Cl atoms and the energy of the HOMO of the unsaturated alcohols is presented. Based on the obtained results, the atmospheric lifetimes of the unsaturated alcohols have been estimated and possible atmospheric implications assessed.
Fil: Gibilisco, Rodrigo Gastón. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Bejan, Iustinian. Universität Wuppertal. Wuppertal; Alemania. Al. I. Cuza” University. Iasi; Rumania
Fil: Barnes, Ian. Universität Wuppertal. Wuppertal; Alemania
Fil: Wiesen, Peter. Universität Wuppertal. Wuppertal; Alemania
Fil: Teruel, Mariano Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Materia
(E)-2-Hexen-1-Ol
(E)-3-Hexen-1-Ol
(Z)-3-Hexen-1-Ol
(Z)-3-Hepten-1-Ol
(Z)-3-Octen-1-Olchlorine Atom
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/31231
Acceder
id CONICETDig_e08445214c47f766cb7948302bbcc7ec
oai_identifier_str oai:ri.conicet.gov.ar:11336/31231
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Rate coefficients at 298 K and 1 atm for the tropospheric degradationof a series of C6,C7and C8biogenic unsaturated alcohols initiated by ClatomsGibilisco, Rodrigo GastónBejan, IustinianBarnes, IanWiesen, PeterTeruel, Mariano Andres(E)-2-Hexen-1-Ol(E)-3-Hexen-1-Ol(Z)-3-Hexen-1-Ol(Z)-3-Hepten-1-Ol(Z)-3-Octen-1-Olchlorine Atomhttps://purl.org/becyt/ford/1.5https://purl.org/becyt/ford/1Rate coefficients for the gas-phase reactions of Cl atoms with a series of unsaturated biogenic alcohols at 298 ± 3 K and 1 atm have been measured by the relative technique in an environmental chamber with in situ FTIR detection of reactants. The rate coefficients obtained using 1-butene and isobutene as reference compounds were (in units of 10−10 cm3 molecule−1 s−1): k1((E)-2-hexen-1-ol) = (3.49 ± 0.82), k2((E)-3-hexen-1-ol) = (3.42 ± 0.79), k3 ((Z)-3-hexen-1-ol) = (2.94 ± 0.72), k4((Z)-3-hepten-1-ol) = (3.80 ± 0.86) and k5((Z)-3-octen-1-ol) = (4.13 ± 0.68). This work constitutes the first kinetic study of the reactions cited above. The rate coefficients are compared with those for other unsaturated alcohols and a correlation between the reactivity of unsaturated alcohols toward Cl atoms and the energy of the HOMO of the unsaturated alcohols is presented. Based on the obtained results, the atmospheric lifetimes of the unsaturated alcohols have been estimated and possible atmospheric implications assessed.Fil: Gibilisco, Rodrigo Gastón. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Bejan, Iustinian. Universität Wuppertal. Wuppertal; Alemania. Al. I. Cuza” University. Iasi; RumaniaFil: Barnes, Ian. Universität Wuppertal. Wuppertal; AlemaniaFil: Wiesen, Peter. Universität Wuppertal. Wuppertal; AlemaniaFil: Teruel, Mariano Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaPergamon-Elsevier Science Ltd.2014-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/31231Gibilisco, Rodrigo Gastón; Bejan, Iustinian; Barnes, Ian; Wiesen, Peter; Teruel, Mariano Andres; Rate coefficients at 298 K and 1 atm for the tropospheric degradationof a series of C6,C7and C8biogenic unsaturated alcohols initiated by Clatoms; Pergamon-Elsevier Science Ltd.; Atmospheric Environment; 94; 5-2014; 564-5721352-2310CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1352231014003975info:eu-repo/semantics/altIdentifier/doi/10.1016/j.atmosenv.2014.05.050info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T14:48:27Zoai:ri.conicet.gov.ar:11336/31231instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 14:48:27.718CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Rate coefficients at 298 K and 1 atm for the tropospheric degradationof a series of C6,C7and C8biogenic unsaturated alcohols initiated by Clatoms
title Rate coefficients at 298 K and 1 atm for the tropospheric degradationof a series of C6,C7and C8biogenic unsaturated alcohols initiated by Clatoms
spellingShingle Rate coefficients at 298 K and 1 atm for the tropospheric degradationof a series of C6,C7and C8biogenic unsaturated alcohols initiated by Clatoms
Gibilisco, Rodrigo Gastón
(E)-2-Hexen-1-Ol
(E)-3-Hexen-1-Ol
(Z)-3-Hexen-1-Ol
(Z)-3-Hepten-1-Ol
(Z)-3-Octen-1-Olchlorine Atom
title_short Rate coefficients at 298 K and 1 atm for the tropospheric degradationof a series of C6,C7and C8biogenic unsaturated alcohols initiated by Clatoms
title_full Rate coefficients at 298 K and 1 atm for the tropospheric degradationof a series of C6,C7and C8biogenic unsaturated alcohols initiated by Clatoms
title_fullStr Rate coefficients at 298 K and 1 atm for the tropospheric degradationof a series of C6,C7and C8biogenic unsaturated alcohols initiated by Clatoms
title_full_unstemmed Rate coefficients at 298 K and 1 atm for the tropospheric degradationof a series of C6,C7and C8biogenic unsaturated alcohols initiated by Clatoms
title_sort Rate coefficients at 298 K and 1 atm for the tropospheric degradationof a series of C6,C7and C8biogenic unsaturated alcohols initiated by Clatoms
dc.creator.none.fl_str_mv Gibilisco, Rodrigo Gastón
Bejan, Iustinian
Barnes, Ian
Wiesen, Peter
Teruel, Mariano Andres
author Gibilisco, Rodrigo Gastón
author_facet Gibilisco, Rodrigo Gastón
Bejan, Iustinian
Barnes, Ian
Wiesen, Peter
Teruel, Mariano Andres
author_role author
author2 Bejan, Iustinian
Barnes, Ian
Wiesen, Peter
Teruel, Mariano Andres
author2_role author
author
author
author
dc.subject.none.fl_str_mv (E)-2-Hexen-1-Ol
(E)-3-Hexen-1-Ol
(Z)-3-Hexen-1-Ol
(Z)-3-Hepten-1-Ol
(Z)-3-Octen-1-Olchlorine Atom
topic (E)-2-Hexen-1-Ol
(E)-3-Hexen-1-Ol
(Z)-3-Hexen-1-Ol
(Z)-3-Hepten-1-Ol
(Z)-3-Octen-1-Olchlorine Atom
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.5
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Rate coefficients for the gas-phase reactions of Cl atoms with a series of unsaturated biogenic alcohols at 298 ± 3 K and 1 atm have been measured by the relative technique in an environmental chamber with in situ FTIR detection of reactants. The rate coefficients obtained using 1-butene and isobutene as reference compounds were (in units of 10−10 cm3 molecule−1 s−1): k1((E)-2-hexen-1-ol) = (3.49 ± 0.82), k2((E)-3-hexen-1-ol) = (3.42 ± 0.79), k3 ((Z)-3-hexen-1-ol) = (2.94 ± 0.72), k4((Z)-3-hepten-1-ol) = (3.80 ± 0.86) and k5((Z)-3-octen-1-ol) = (4.13 ± 0.68). This work constitutes the first kinetic study of the reactions cited above. The rate coefficients are compared with those for other unsaturated alcohols and a correlation between the reactivity of unsaturated alcohols toward Cl atoms and the energy of the HOMO of the unsaturated alcohols is presented. Based on the obtained results, the atmospheric lifetimes of the unsaturated alcohols have been estimated and possible atmospheric implications assessed.
Fil: Gibilisco, Rodrigo Gastón. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Bejan, Iustinian. Universität Wuppertal. Wuppertal; Alemania. Al. I. Cuza” University. Iasi; Rumania
Fil: Barnes, Ian. Universität Wuppertal. Wuppertal; Alemania
Fil: Wiesen, Peter. Universität Wuppertal. Wuppertal; Alemania
Fil: Teruel, Mariano Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
description Rate coefficients for the gas-phase reactions of Cl atoms with a series of unsaturated biogenic alcohols at 298 ± 3 K and 1 atm have been measured by the relative technique in an environmental chamber with in situ FTIR detection of reactants. The rate coefficients obtained using 1-butene and isobutene as reference compounds were (in units of 10−10 cm3 molecule−1 s−1): k1((E)-2-hexen-1-ol) = (3.49 ± 0.82), k2((E)-3-hexen-1-ol) = (3.42 ± 0.79), k3 ((Z)-3-hexen-1-ol) = (2.94 ± 0.72), k4((Z)-3-hepten-1-ol) = (3.80 ± 0.86) and k5((Z)-3-octen-1-ol) = (4.13 ± 0.68). This work constitutes the first kinetic study of the reactions cited above. The rate coefficients are compared with those for other unsaturated alcohols and a correlation between the reactivity of unsaturated alcohols toward Cl atoms and the energy of the HOMO of the unsaturated alcohols is presented. Based on the obtained results, the atmospheric lifetimes of the unsaturated alcohols have been estimated and possible atmospheric implications assessed.
publishDate 2014
dc.date.none.fl_str_mv 2014-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/31231
Gibilisco, Rodrigo Gastón; Bejan, Iustinian; Barnes, Ian; Wiesen, Peter; Teruel, Mariano Andres; Rate coefficients at 298 K and 1 atm for the tropospheric degradationof a series of C6,C7and C8biogenic unsaturated alcohols initiated by Clatoms; Pergamon-Elsevier Science Ltd.; Atmospheric Environment; 94; 5-2014; 564-572
1352-2310
CONICET Digital
CONICET
url http://hdl.handle.net/11336/31231
identifier_str_mv Gibilisco, Rodrigo Gastón; Bejan, Iustinian; Barnes, Ian; Wiesen, Peter; Teruel, Mariano Andres; Rate coefficients at 298 K and 1 atm for the tropospheric degradationof a series of C6,C7and C8biogenic unsaturated alcohols initiated by Clatoms; Pergamon-Elsevier Science Ltd.; Atmospheric Environment; 94; 5-2014; 564-572
1352-2310
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1352231014003975
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.atmosenv.2014.05.050
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd.
publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd.
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846083004963749888
score 13.22299

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