Synthesis and characterization of Ferric Sorbate and Aluminum Sorbate as antifouling pigments for marine paints

Autores
Perez, Miriam Cristina; García, Mónica; Stupak, Mirta Elena; Blustein, Guillermo
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Biofouling is a natural process that involves the settlement and growth of organisms on natural or man-made structures and leads to material deterioration, generating severe technical and economic problems. The use of paints has been a practical method to control marine biofouling. However, some biocides currently employed have been banned because of their toxicity. There is a growing need for environmentally safe antifouling systems. The current study describes the synthesis and characterization of two new pigments, ferric sorbate and aluminum sorbate, as potential antifoulants. Laboratory assays with fouling organisms and field trials with antifouling paints were conducted. The antifouling activity of sorbate-pigment-based paints was successful and could be attributed to the combined action of a sorbate anion and low pH values generated by hydrolysis at the paint/seawater interface. After 9 months of exposure in the sea, paints containing synthetic sorbate salts had much lower fouling settlement compared to controls, indicating that these pigments are promising candidates for biofouling control.
Fil: Perez, Miriam Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigación y Desarrollo en Tecnología de Pinturas (i); Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Naturales y Museo; Argentina
Fil: García, Mónica . Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigación y Desarrollo en Tecnología de Pinturas (i); Argentina
Fil: Stupak, Mirta Elena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigación y Desarrollo en Tecnología de Pinturas (i); Argentina
Fil: Blustein, Guillermo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigación y Desarrollo en Tecnología de Pinturas (i); Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Agrarias y Forestales; Argentina
Materia
Ferric Sorbate
Aluminum Sorbate
Antifouling Pigments
Biofouling
Marine Paints
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/11263
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Synthesis and characterization of Ferric Sorbate and Aluminum Sorbate as antifouling pigments for marine paintsPerez, Miriam CristinaGarcía, Mónica Stupak, Mirta ElenaBlustein, GuillermoFerric SorbateAluminum SorbateAntifouling PigmentsBiofoulingMarine Paintshttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Biofouling is a natural process that involves the settlement and growth of organisms on natural or man-made structures and leads to material deterioration, generating severe technical and economic problems. The use of paints has been a practical method to control marine biofouling. However, some biocides currently employed have been banned because of their toxicity. There is a growing need for environmentally safe antifouling systems. The current study describes the synthesis and characterization of two new pigments, ferric sorbate and aluminum sorbate, as potential antifoulants. Laboratory assays with fouling organisms and field trials with antifouling paints were conducted. The antifouling activity of sorbate-pigment-based paints was successful and could be attributed to the combined action of a sorbate anion and low pH values generated by hydrolysis at the paint/seawater interface. After 9 months of exposure in the sea, paints containing synthetic sorbate salts had much lower fouling settlement compared to controls, indicating that these pigments are promising candidates for biofouling control.Fil: Perez, Miriam Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigación y Desarrollo en Tecnología de Pinturas (i); Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Naturales y Museo; ArgentinaFil: García, Mónica . Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigación y Desarrollo en Tecnología de Pinturas (i); ArgentinaFil: Stupak, Mirta Elena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigación y Desarrollo en Tecnología de Pinturas (i); ArgentinaFil: Blustein, Guillermo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigación y Desarrollo en Tecnología de Pinturas (i); Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Agrarias y Forestales; ArgentinaAmerican Chemical Society2014-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/11263Perez, Miriam Cristina; García, Mónica ; Stupak, Mirta Elena; Blustein, Guillermo; Synthesis and characterization of Ferric Sorbate and Aluminum Sorbate as antifouling pigments for marine paints; American Chemical Society; Industrial & Engineering Chemical Research; 53; 9; 2-2014; 3570-35770888-58851520-5045enginfo:eu-repo/semantics/altIdentifier/doi/10.1021/ie403905vinfo:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/ie403905vinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:53:11Zoai:ri.conicet.gov.ar:11336/11263instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:53:11.404CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Synthesis and characterization of Ferric Sorbate and Aluminum Sorbate as antifouling pigments for marine paints
title Synthesis and characterization of Ferric Sorbate and Aluminum Sorbate as antifouling pigments for marine paints
spellingShingle Synthesis and characterization of Ferric Sorbate and Aluminum Sorbate as antifouling pigments for marine paints
Perez, Miriam Cristina
Ferric Sorbate
Aluminum Sorbate
Antifouling Pigments
Biofouling
Marine Paints
title_short Synthesis and characterization of Ferric Sorbate and Aluminum Sorbate as antifouling pigments for marine paints
title_full Synthesis and characterization of Ferric Sorbate and Aluminum Sorbate as antifouling pigments for marine paints
title_fullStr Synthesis and characterization of Ferric Sorbate and Aluminum Sorbate as antifouling pigments for marine paints
title_full_unstemmed Synthesis and characterization of Ferric Sorbate and Aluminum Sorbate as antifouling pigments for marine paints
title_sort Synthesis and characterization of Ferric Sorbate and Aluminum Sorbate as antifouling pigments for marine paints
dc.creator.none.fl_str_mv Perez, Miriam Cristina
García, Mónica
Stupak, Mirta Elena
Blustein, Guillermo
author Perez, Miriam Cristina
author_facet Perez, Miriam Cristina
García, Mónica
Stupak, Mirta Elena
Blustein, Guillermo
author_role author
author2 García, Mónica
Stupak, Mirta Elena
Blustein, Guillermo
author2_role author
author
author
dc.subject.none.fl_str_mv Ferric Sorbate
Aluminum Sorbate
Antifouling Pigments
Biofouling
Marine Paints
topic Ferric Sorbate
Aluminum Sorbate
Antifouling Pigments
Biofouling
Marine Paints
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Biofouling is a natural process that involves the settlement and growth of organisms on natural or man-made structures and leads to material deterioration, generating severe technical and economic problems. The use of paints has been a practical method to control marine biofouling. However, some biocides currently employed have been banned because of their toxicity. There is a growing need for environmentally safe antifouling systems. The current study describes the synthesis and characterization of two new pigments, ferric sorbate and aluminum sorbate, as potential antifoulants. Laboratory assays with fouling organisms and field trials with antifouling paints were conducted. The antifouling activity of sorbate-pigment-based paints was successful and could be attributed to the combined action of a sorbate anion and low pH values generated by hydrolysis at the paint/seawater interface. After 9 months of exposure in the sea, paints containing synthetic sorbate salts had much lower fouling settlement compared to controls, indicating that these pigments are promising candidates for biofouling control.
Fil: Perez, Miriam Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigación y Desarrollo en Tecnología de Pinturas (i); Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Naturales y Museo; Argentina
Fil: García, Mónica . Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigación y Desarrollo en Tecnología de Pinturas (i); Argentina
Fil: Stupak, Mirta Elena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigación y Desarrollo en Tecnología de Pinturas (i); Argentina
Fil: Blustein, Guillermo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigación y Desarrollo en Tecnología de Pinturas (i); Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Agrarias y Forestales; Argentina
description Biofouling is a natural process that involves the settlement and growth of organisms on natural or man-made structures and leads to material deterioration, generating severe technical and economic problems. The use of paints has been a practical method to control marine biofouling. However, some biocides currently employed have been banned because of their toxicity. There is a growing need for environmentally safe antifouling systems. The current study describes the synthesis and characterization of two new pigments, ferric sorbate and aluminum sorbate, as potential antifoulants. Laboratory assays with fouling organisms and field trials with antifouling paints were conducted. The antifouling activity of sorbate-pigment-based paints was successful and could be attributed to the combined action of a sorbate anion and low pH values generated by hydrolysis at the paint/seawater interface. After 9 months of exposure in the sea, paints containing synthetic sorbate salts had much lower fouling settlement compared to controls, indicating that these pigments are promising candidates for biofouling control.
publishDate 2014
dc.date.none.fl_str_mv 2014-02
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/11263
Perez, Miriam Cristina; García, Mónica ; Stupak, Mirta Elena; Blustein, Guillermo; Synthesis and characterization of Ferric Sorbate and Aluminum Sorbate as antifouling pigments for marine paints; American Chemical Society; Industrial & Engineering Chemical Research; 53; 9; 2-2014; 3570-3577
0888-5885
1520-5045
url http://hdl.handle.net/11336/11263
identifier_str_mv Perez, Miriam Cristina; García, Mónica ; Stupak, Mirta Elena; Blustein, Guillermo; Synthesis and characterization of Ferric Sorbate and Aluminum Sorbate as antifouling pigments for marine paints; American Chemical Society; Industrial & Engineering Chemical Research; 53; 9; 2-2014; 3570-3577
0888-5885
1520-5045
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/ie403905v
info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/ie403905v
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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