Effect of prolonged electrode potential cycling on the charge transport parameters of poly(o-aminophenol) films. A study employing Rotating Disc Electrode Voltammetry and Surface R...

Autores
Tucceri, Ismael Ricardo
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The aim of this work was to study the effect of prolonged potentiodynamic cycling (PPC) on the conducting properties of poly(o-aminophenol) (POAP) film electrodes. Cyclic Voltammetry (CV), Rotating Disc Electrode Voltammetry (RDEV) and Surface Resistance (SR) were employed in this study. The attenuation of the voltammetric response of the polymer with the increase in the number of oxidation–reduction cycles allowed one to define a degree of deactivation. RDEV was employed to obtain the dependence of the electron diffusion coefficient on the degree of deactivation of the polymer. The slower electron transport with the increase in the degree of deactivation was attributed to the increase of the electron hopping distance between redox sites. The attenuation of the relative resistance changes (ΔR/R) of a gold film coated with a POAP film as the degree of deactivation increases was also associated to changes in the redox site configuration at the gold/POAP interface after PPC. POAP films maintain their conducting properties almost unaltered for about 500 potential cycles at a scan rate of 0.010 V s−1. However, a loss of conductivity was observed as the number of potential cycles was extended beyond 500.
Fil: Tucceri, Ismael Ricardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de la Plata; Argentina
Materia
Poly(O-Aminophenol) Film Electrodes
Prolonged Potential Cycling (Ppc)
Deactivation
Surface Resistance
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/5090
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/5090
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Effect of prolonged electrode potential cycling on the charge transport parameters of poly(o-aminophenol) films. A study employing Rotating Disc Electrode Voltammetry and Surface ResistanceTucceri, Ismael RicardoPoly(O-Aminophenol) Film ElectrodesProlonged Potential Cycling (Ppc)DeactivationSurface Resistancehttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The aim of this work was to study the effect of prolonged potentiodynamic cycling (PPC) on the conducting properties of poly(o-aminophenol) (POAP) film electrodes. Cyclic Voltammetry (CV), Rotating Disc Electrode Voltammetry (RDEV) and Surface Resistance (SR) were employed in this study. The attenuation of the voltammetric response of the polymer with the increase in the number of oxidation–reduction cycles allowed one to define a degree of deactivation. RDEV was employed to obtain the dependence of the electron diffusion coefficient on the degree of deactivation of the polymer. The slower electron transport with the increase in the degree of deactivation was attributed to the increase of the electron hopping distance between redox sites. The attenuation of the relative resistance changes (ΔR/R) of a gold film coated with a POAP film as the degree of deactivation increases was also associated to changes in the redox site configuration at the gold/POAP interface after PPC. POAP films maintain their conducting properties almost unaltered for about 500 potential cycles at a scan rate of 0.010 V s−1. However, a loss of conductivity was observed as the number of potential cycles was extended beyond 500.Fil: Tucceri, Ismael Ricardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de la Plata; ArgentinaElsevier2014-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/5090Tucceri, Ismael Ricardo; Effect of prolonged electrode potential cycling on the charge transport parameters of poly(o-aminophenol) films. A study employing Rotating Disc Electrode Voltammetry and Surface Resistance; Elsevier; Journal of Electroanalytical Chemistry; 717-718; 1-2014; 131-1391572-6657enginfo:eu-repo/semantics/altIdentifier/url/10.1016/j.jelechem.2014.01.023info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1572665714000307info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jelechem.2014.01.023info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:14:19Zoai:ri.conicet.gov.ar:11336/5090instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:14:19.705CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Effect of prolonged electrode potential cycling on the charge transport parameters of poly(o-aminophenol) films. A study employing Rotating Disc Electrode Voltammetry and Surface Resistance
title Effect of prolonged electrode potential cycling on the charge transport parameters of poly(o-aminophenol) films. A study employing Rotating Disc Electrode Voltammetry and Surface Resistance
spellingShingle Effect of prolonged electrode potential cycling on the charge transport parameters of poly(o-aminophenol) films. A study employing Rotating Disc Electrode Voltammetry and Surface Resistance
Tucceri, Ismael Ricardo
Poly(O-Aminophenol) Film Electrodes
Prolonged Potential Cycling (Ppc)
Deactivation
Surface Resistance
title_short Effect of prolonged electrode potential cycling on the charge transport parameters of poly(o-aminophenol) films. A study employing Rotating Disc Electrode Voltammetry and Surface Resistance
title_full Effect of prolonged electrode potential cycling on the charge transport parameters of poly(o-aminophenol) films. A study employing Rotating Disc Electrode Voltammetry and Surface Resistance
title_fullStr Effect of prolonged electrode potential cycling on the charge transport parameters of poly(o-aminophenol) films. A study employing Rotating Disc Electrode Voltammetry and Surface Resistance
title_full_unstemmed Effect of prolonged electrode potential cycling on the charge transport parameters of poly(o-aminophenol) films. A study employing Rotating Disc Electrode Voltammetry and Surface Resistance
title_sort Effect of prolonged electrode potential cycling on the charge transport parameters of poly(o-aminophenol) films. A study employing Rotating Disc Electrode Voltammetry and Surface Resistance
dc.creator.none.fl_str_mv Tucceri, Ismael Ricardo
author Tucceri, Ismael Ricardo
author_facet Tucceri, Ismael Ricardo
author_role author
dc.subject.none.fl_str_mv Poly(O-Aminophenol) Film Electrodes
Prolonged Potential Cycling (Ppc)
Deactivation
Surface Resistance
topic Poly(O-Aminophenol) Film Electrodes
Prolonged Potential Cycling (Ppc)
Deactivation
Surface Resistance
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The aim of this work was to study the effect of prolonged potentiodynamic cycling (PPC) on the conducting properties of poly(o-aminophenol) (POAP) film electrodes. Cyclic Voltammetry (CV), Rotating Disc Electrode Voltammetry (RDEV) and Surface Resistance (SR) were employed in this study. The attenuation of the voltammetric response of the polymer with the increase in the number of oxidation–reduction cycles allowed one to define a degree of deactivation. RDEV was employed to obtain the dependence of the electron diffusion coefficient on the degree of deactivation of the polymer. The slower electron transport with the increase in the degree of deactivation was attributed to the increase of the electron hopping distance between redox sites. The attenuation of the relative resistance changes (ΔR/R) of a gold film coated with a POAP film as the degree of deactivation increases was also associated to changes in the redox site configuration at the gold/POAP interface after PPC. POAP films maintain their conducting properties almost unaltered for about 500 potential cycles at a scan rate of 0.010 V s−1. However, a loss of conductivity was observed as the number of potential cycles was extended beyond 500.
Fil: Tucceri, Ismael Ricardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de la Plata; Argentina
description The aim of this work was to study the effect of prolonged potentiodynamic cycling (PPC) on the conducting properties of poly(o-aminophenol) (POAP) film electrodes. Cyclic Voltammetry (CV), Rotating Disc Electrode Voltammetry (RDEV) and Surface Resistance (SR) were employed in this study. The attenuation of the voltammetric response of the polymer with the increase in the number of oxidation–reduction cycles allowed one to define a degree of deactivation. RDEV was employed to obtain the dependence of the electron diffusion coefficient on the degree of deactivation of the polymer. The slower electron transport with the increase in the degree of deactivation was attributed to the increase of the electron hopping distance between redox sites. The attenuation of the relative resistance changes (ΔR/R) of a gold film coated with a POAP film as the degree of deactivation increases was also associated to changes in the redox site configuration at the gold/POAP interface after PPC. POAP films maintain their conducting properties almost unaltered for about 500 potential cycles at a scan rate of 0.010 V s−1. However, a loss of conductivity was observed as the number of potential cycles was extended beyond 500.
publishDate 2014
dc.date.none.fl_str_mv 2014-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/5090
Tucceri, Ismael Ricardo; Effect of prolonged electrode potential cycling on the charge transport parameters of poly(o-aminophenol) films. A study employing Rotating Disc Electrode Voltammetry and Surface Resistance; Elsevier; Journal of Electroanalytical Chemistry; 717-718; 1-2014; 131-139
1572-6657
url http://hdl.handle.net/11336/5090
identifier_str_mv Tucceri, Ismael Ricardo; Effect of prolonged electrode potential cycling on the charge transport parameters of poly(o-aminophenol) films. A study employing Rotating Disc Electrode Voltammetry and Surface Resistance; Elsevier; Journal of Electroanalytical Chemistry; 717-718; 1-2014; 131-139
1572-6657
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/10.1016/j.jelechem.2014.01.023
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1572665714000307
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jelechem.2014.01.023
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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