Effect of prolonged electrode potential cycling on the charge transport parameters of poly(o-aminophenol) films. A study employing Rotating Disc Electrode Voltammetry and Surface R...
- Autores
- Tucceri, Ismael Ricardo
- Año de publicación
- 2014
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The aim of this work was to study the effect of prolonged potentiodynamic cycling (PPC) on the conducting properties of poly(o-aminophenol) (POAP) film electrodes. Cyclic Voltammetry (CV), Rotating Disc Electrode Voltammetry (RDEV) and Surface Resistance (SR) were employed in this study. The attenuation of the voltammetric response of the polymer with the increase in the number of oxidation–reduction cycles allowed one to define a degree of deactivation. RDEV was employed to obtain the dependence of the electron diffusion coefficient on the degree of deactivation of the polymer. The slower electron transport with the increase in the degree of deactivation was attributed to the increase of the electron hopping distance between redox sites. The attenuation of the relative resistance changes (ΔR/R) of a gold film coated with a POAP film as the degree of deactivation increases was also associated to changes in the redox site configuration at the gold/POAP interface after PPC. POAP films maintain their conducting properties almost unaltered for about 500 potential cycles at a scan rate of 0.010 V s−1. However, a loss of conductivity was observed as the number of potential cycles was extended beyond 500.
Fil: Tucceri, Ismael Ricardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de la Plata; Argentina - Materia
-
Poly(O-Aminophenol) Film Electrodes
Prolonged Potential Cycling (Ppc)
Deactivation
Surface Resistance - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/5090
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oai:ri.conicet.gov.ar:11336/5090 |
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3498 |
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CONICET Digital (CONICET) |
spelling |
Effect of prolonged electrode potential cycling on the charge transport parameters of poly(o-aminophenol) films. A study employing Rotating Disc Electrode Voltammetry and Surface ResistanceTucceri, Ismael RicardoPoly(O-Aminophenol) Film ElectrodesProlonged Potential Cycling (Ppc)DeactivationSurface Resistancehttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The aim of this work was to study the effect of prolonged potentiodynamic cycling (PPC) on the conducting properties of poly(o-aminophenol) (POAP) film electrodes. Cyclic Voltammetry (CV), Rotating Disc Electrode Voltammetry (RDEV) and Surface Resistance (SR) were employed in this study. The attenuation of the voltammetric response of the polymer with the increase in the number of oxidation–reduction cycles allowed one to define a degree of deactivation. RDEV was employed to obtain the dependence of the electron diffusion coefficient on the degree of deactivation of the polymer. The slower electron transport with the increase in the degree of deactivation was attributed to the increase of the electron hopping distance between redox sites. The attenuation of the relative resistance changes (ΔR/R) of a gold film coated with a POAP film as the degree of deactivation increases was also associated to changes in the redox site configuration at the gold/POAP interface after PPC. POAP films maintain their conducting properties almost unaltered for about 500 potential cycles at a scan rate of 0.010 V s−1. However, a loss of conductivity was observed as the number of potential cycles was extended beyond 500.Fil: Tucceri, Ismael Ricardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de la Plata; ArgentinaElsevier2014-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/5090Tucceri, Ismael Ricardo; Effect of prolonged electrode potential cycling on the charge transport parameters of poly(o-aminophenol) films. A study employing Rotating Disc Electrode Voltammetry and Surface Resistance; Elsevier; Journal of Electroanalytical Chemistry; 717-718; 1-2014; 131-1391572-6657enginfo:eu-repo/semantics/altIdentifier/url/10.1016/j.jelechem.2014.01.023info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1572665714000307info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jelechem.2014.01.023info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:45:29Zoai:ri.conicet.gov.ar:11336/5090instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:45:29.998CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Effect of prolonged electrode potential cycling on the charge transport parameters of poly(o-aminophenol) films. A study employing Rotating Disc Electrode Voltammetry and Surface Resistance |
title |
Effect of prolonged electrode potential cycling on the charge transport parameters of poly(o-aminophenol) films. A study employing Rotating Disc Electrode Voltammetry and Surface Resistance |
spellingShingle |
Effect of prolonged electrode potential cycling on the charge transport parameters of poly(o-aminophenol) films. A study employing Rotating Disc Electrode Voltammetry and Surface Resistance Tucceri, Ismael Ricardo Poly(O-Aminophenol) Film Electrodes Prolonged Potential Cycling (Ppc) Deactivation Surface Resistance |
title_short |
Effect of prolonged electrode potential cycling on the charge transport parameters of poly(o-aminophenol) films. A study employing Rotating Disc Electrode Voltammetry and Surface Resistance |
title_full |
Effect of prolonged electrode potential cycling on the charge transport parameters of poly(o-aminophenol) films. A study employing Rotating Disc Electrode Voltammetry and Surface Resistance |
title_fullStr |
Effect of prolonged electrode potential cycling on the charge transport parameters of poly(o-aminophenol) films. A study employing Rotating Disc Electrode Voltammetry and Surface Resistance |
title_full_unstemmed |
Effect of prolonged electrode potential cycling on the charge transport parameters of poly(o-aminophenol) films. A study employing Rotating Disc Electrode Voltammetry and Surface Resistance |
title_sort |
Effect of prolonged electrode potential cycling on the charge transport parameters of poly(o-aminophenol) films. A study employing Rotating Disc Electrode Voltammetry and Surface Resistance |
dc.creator.none.fl_str_mv |
Tucceri, Ismael Ricardo |
author |
Tucceri, Ismael Ricardo |
author_facet |
Tucceri, Ismael Ricardo |
author_role |
author |
dc.subject.none.fl_str_mv |
Poly(O-Aminophenol) Film Electrodes Prolonged Potential Cycling (Ppc) Deactivation Surface Resistance |
topic |
Poly(O-Aminophenol) Film Electrodes Prolonged Potential Cycling (Ppc) Deactivation Surface Resistance |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
The aim of this work was to study the effect of prolonged potentiodynamic cycling (PPC) on the conducting properties of poly(o-aminophenol) (POAP) film electrodes. Cyclic Voltammetry (CV), Rotating Disc Electrode Voltammetry (RDEV) and Surface Resistance (SR) were employed in this study. The attenuation of the voltammetric response of the polymer with the increase in the number of oxidation–reduction cycles allowed one to define a degree of deactivation. RDEV was employed to obtain the dependence of the electron diffusion coefficient on the degree of deactivation of the polymer. The slower electron transport with the increase in the degree of deactivation was attributed to the increase of the electron hopping distance between redox sites. The attenuation of the relative resistance changes (ΔR/R) of a gold film coated with a POAP film as the degree of deactivation increases was also associated to changes in the redox site configuration at the gold/POAP interface after PPC. POAP films maintain their conducting properties almost unaltered for about 500 potential cycles at a scan rate of 0.010 V s−1. However, a loss of conductivity was observed as the number of potential cycles was extended beyond 500. Fil: Tucceri, Ismael Ricardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de la Plata; Argentina |
description |
The aim of this work was to study the effect of prolonged potentiodynamic cycling (PPC) on the conducting properties of poly(o-aminophenol) (POAP) film electrodes. Cyclic Voltammetry (CV), Rotating Disc Electrode Voltammetry (RDEV) and Surface Resistance (SR) were employed in this study. The attenuation of the voltammetric response of the polymer with the increase in the number of oxidation–reduction cycles allowed one to define a degree of deactivation. RDEV was employed to obtain the dependence of the electron diffusion coefficient on the degree of deactivation of the polymer. The slower electron transport with the increase in the degree of deactivation was attributed to the increase of the electron hopping distance between redox sites. The attenuation of the relative resistance changes (ΔR/R) of a gold film coated with a POAP film as the degree of deactivation increases was also associated to changes in the redox site configuration at the gold/POAP interface after PPC. POAP films maintain their conducting properties almost unaltered for about 500 potential cycles at a scan rate of 0.010 V s−1. However, a loss of conductivity was observed as the number of potential cycles was extended beyond 500. |
publishDate |
2014 |
dc.date.none.fl_str_mv |
2014-01 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/5090 Tucceri, Ismael Ricardo; Effect of prolonged electrode potential cycling on the charge transport parameters of poly(o-aminophenol) films. A study employing Rotating Disc Electrode Voltammetry and Surface Resistance; Elsevier; Journal of Electroanalytical Chemistry; 717-718; 1-2014; 131-139 1572-6657 |
url |
http://hdl.handle.net/11336/5090 |
identifier_str_mv |
Tucceri, Ismael Ricardo; Effect of prolonged electrode potential cycling on the charge transport parameters of poly(o-aminophenol) films. A study employing Rotating Disc Electrode Voltammetry and Surface Resistance; Elsevier; Journal of Electroanalytical Chemistry; 717-718; 1-2014; 131-139 1572-6657 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/10.1016/j.jelechem.2014.01.023 info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1572665714000307 info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jelechem.2014.01.023 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
_version_ |
1844613426703237120 |
score |
13.070432 |