FTIR gas kinetic study of the reactions of ozone with a series of hexenols at atmospheric pressure and 298 K

Autores
Gibilisco, Rodrigo Gastón; Bejan, Iustinian; Barnes, Ian; Wiesen, Peter; Teruel, Mariano Andres
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Relative rate coefficients of the reactions of O3 with (Z)-3-hexen-1-ol, (E)-3-hexen-1-ol and (E)-2-hexen-1-ol have been determined in an environmental chamber with in situ FTIR detection of the reactants at 298 K and 760 Torr. The following rate coefficients (in units of 10−17 cm3 molecule−1 s−1) have been determined: (6.04 ± 0.95) for (Z)-CH2(OH)CH2CHCHCH2CH3; (5.83 ± 0.86) for (E)-CH2(OH)CH2CHCHCH2CH3; (5.98 ± 0.73) for (E)-CH2(OH)CHCH(CH2)2CH3. This is the first kinetic study for the reactions of O3 with (E)-2-hexen-1-ol and (E)-3-hexen-1-ol. Reactivity trends are developed and the atmospheric persistence of these compounds is calculated based on the rate coefficients
Fil: Gibilisco, Rodrigo Gastón. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Bejan, Iustinian. Bergische Universität Wuppertal; Alemania. “Al. I. Cuza” University; Rumania
Fil: Barnes, Ian. Bergische Universität Wuppertal; Alemania
Fil: Wiesen, Peter. Bergische Universität Wuppertal; Alemania
Fil: Teruel, Mariano Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Materia
Kinetic
Troposphere
Hexenols
Ozone
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/31431
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/31431
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling FTIR gas kinetic study of the reactions of ozone with a series of hexenols at atmospheric pressure and 298 KGibilisco, Rodrigo GastónBejan, IustinianBarnes, IanWiesen, PeterTeruel, Mariano AndresKineticTroposphereHexenolsOzonehttps://purl.org/becyt/ford/1.5https://purl.org/becyt/ford/1Relative rate coefficients of the reactions of O3 with (Z)-3-hexen-1-ol, (E)-3-hexen-1-ol and (E)-2-hexen-1-ol have been determined in an environmental chamber with in situ FTIR detection of the reactants at 298 K and 760 Torr. The following rate coefficients (in units of 10−17 cm3 molecule−1 s−1) have been determined: (6.04 ± 0.95) for (Z)-CH2(OH)CH2CHCHCH2CH3; (5.83 ± 0.86) for (E)-CH2(OH)CH2CHCHCH2CH3; (5.98 ± 0.73) for (E)-CH2(OH)CHCH(CH2)2CH3. This is the first kinetic study for the reactions of O3 with (E)-2-hexen-1-ol and (E)-3-hexen-1-ol. Reactivity trends are developed and the atmospheric persistence of these compounds is calculated based on the rate coefficientsFil: Gibilisco, Rodrigo Gastón. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Bejan, Iustinian. Bergische Universität Wuppertal; Alemania. “Al. I. Cuza” University; RumaniaFil: Barnes, Ian. Bergische Universität Wuppertal; AlemaniaFil: Wiesen, Peter. Bergische Universität Wuppertal; AlemaniaFil: Teruel, Mariano Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaElsevier Science2014-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/31431Teruel, Mariano Andres; Wiesen, Peter; Barnes, Ian; Bejan, Iustinian; Gibilisco, Rodrigo Gastón; FTIR gas kinetic study of the reactions of ozone with a series of hexenols at atmospheric pressure and 298 K; Elsevier Science; Chemical Physics Letters; 618; 11-2014; 114-1180009-2614CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.cplett.2014.11.003info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0009261414009373info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:03:40Zoai:ri.conicet.gov.ar:11336/31431instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:03:41.201CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv FTIR gas kinetic study of the reactions of ozone with a series of hexenols at atmospheric pressure and 298 K
title FTIR gas kinetic study of the reactions of ozone with a series of hexenols at atmospheric pressure and 298 K
spellingShingle FTIR gas kinetic study of the reactions of ozone with a series of hexenols at atmospheric pressure and 298 K
Gibilisco, Rodrigo Gastón
Kinetic
Troposphere
Hexenols
Ozone
title_short FTIR gas kinetic study of the reactions of ozone with a series of hexenols at atmospheric pressure and 298 K
title_full FTIR gas kinetic study of the reactions of ozone with a series of hexenols at atmospheric pressure and 298 K
title_fullStr FTIR gas kinetic study of the reactions of ozone with a series of hexenols at atmospheric pressure and 298 K
title_full_unstemmed FTIR gas kinetic study of the reactions of ozone with a series of hexenols at atmospheric pressure and 298 K
title_sort FTIR gas kinetic study of the reactions of ozone with a series of hexenols at atmospheric pressure and 298 K
dc.creator.none.fl_str_mv Gibilisco, Rodrigo Gastón
Bejan, Iustinian
Barnes, Ian
Wiesen, Peter
Teruel, Mariano Andres
author Gibilisco, Rodrigo Gastón
author_facet Gibilisco, Rodrigo Gastón
Bejan, Iustinian
Barnes, Ian
Wiesen, Peter
Teruel, Mariano Andres
author_role author
author2 Bejan, Iustinian
Barnes, Ian
Wiesen, Peter
Teruel, Mariano Andres
author2_role author
author
author
author
dc.subject.none.fl_str_mv Kinetic
Troposphere
Hexenols
Ozone
topic Kinetic
Troposphere
Hexenols
Ozone
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.5
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Relative rate coefficients of the reactions of O3 with (Z)-3-hexen-1-ol, (E)-3-hexen-1-ol and (E)-2-hexen-1-ol have been determined in an environmental chamber with in situ FTIR detection of the reactants at 298 K and 760 Torr. The following rate coefficients (in units of 10−17 cm3 molecule−1 s−1) have been determined: (6.04 ± 0.95) for (Z)-CH2(OH)CH2CHCHCH2CH3; (5.83 ± 0.86) for (E)-CH2(OH)CH2CHCHCH2CH3; (5.98 ± 0.73) for (E)-CH2(OH)CHCH(CH2)2CH3. This is the first kinetic study for the reactions of O3 with (E)-2-hexen-1-ol and (E)-3-hexen-1-ol. Reactivity trends are developed and the atmospheric persistence of these compounds is calculated based on the rate coefficients
Fil: Gibilisco, Rodrigo Gastón. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Bejan, Iustinian. Bergische Universität Wuppertal; Alemania. “Al. I. Cuza” University; Rumania
Fil: Barnes, Ian. Bergische Universität Wuppertal; Alemania
Fil: Wiesen, Peter. Bergische Universität Wuppertal; Alemania
Fil: Teruel, Mariano Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
description Relative rate coefficients of the reactions of O3 with (Z)-3-hexen-1-ol, (E)-3-hexen-1-ol and (E)-2-hexen-1-ol have been determined in an environmental chamber with in situ FTIR detection of the reactants at 298 K and 760 Torr. The following rate coefficients (in units of 10−17 cm3 molecule−1 s−1) have been determined: (6.04 ± 0.95) for (Z)-CH2(OH)CH2CHCHCH2CH3; (5.83 ± 0.86) for (E)-CH2(OH)CH2CHCHCH2CH3; (5.98 ± 0.73) for (E)-CH2(OH)CHCH(CH2)2CH3. This is the first kinetic study for the reactions of O3 with (E)-2-hexen-1-ol and (E)-3-hexen-1-ol. Reactivity trends are developed and the atmospheric persistence of these compounds is calculated based on the rate coefficients
publishDate 2014
dc.date.none.fl_str_mv 2014-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/31431
Teruel, Mariano Andres; Wiesen, Peter; Barnes, Ian; Bejan, Iustinian; Gibilisco, Rodrigo Gastón; FTIR gas kinetic study of the reactions of ozone with a series of hexenols at atmospheric pressure and 298 K; Elsevier Science; Chemical Physics Letters; 618; 11-2014; 114-118
0009-2614
CONICET Digital
CONICET
url http://hdl.handle.net/11336/31431
identifier_str_mv Teruel, Mariano Andres; Wiesen, Peter; Barnes, Ian; Bejan, Iustinian; Gibilisco, Rodrigo Gastón; FTIR gas kinetic study of the reactions of ozone with a series of hexenols at atmospheric pressure and 298 K; Elsevier Science; Chemical Physics Letters; 618; 11-2014; 114-118
0009-2614
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cplett.2014.11.003
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0009261414009373
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842269813664120832
score 13.13397

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