Topaz magmatic crystallization in rhyolites of the Central Andes (Chivinar volcanic complex, NW Argentina): Constraints from texture, mineralogy and rock chemistry

Autores
Gioncada, Anna; Orlandi, Paolo; Vezzoli, Luigina; Omarini, Ricardo Hector; Mazzuoli, Roberto; Lopez Azarevich, Vanina; Sureda, Ricardo Jose; Azarevich, Miguel Basilio; Acocella, Valerio; Ruch, Joel
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Topaz-bearing rhyolite lavas were erupted as domes and cryptodomes during the early history of the Late Miocene Chivinar volcano, in Central Andes. These are the only topaz rhyolite lavas recognized in Central Andes. Textural, mineralogical and geochemical data on the Chivinar rhyolites suggest that topaz crystallized from strongly residual, fluorine-rich, peraluminous silicate melts of topazite composition before the complete solidification of the lava domes. Crystallization of the rhyolitic magma began with sodic plagioclase and alkali feldspar phenocrysts in the magma chamber, followed by groundmass quartz + alkali feldspar + minor sodic plagioclase during dome emplacement, and terminated with quartz + topaz + vapour bubbles forming small scattered miaroles. Fluorine partitioning into the fluid phase occurred only in the final stage of groundmass crystallization. The magmatic origin of topaz indicates the presence of a fluorine-rich highly differentiated magma in the early history of the Chivinar volcano and suggests the possibility of rare metals mineralizations related to the cooling and solidification of a silicic magma chamber. A late fluid circulation phase, pre-dating the andesitic phase of the Chivinar volcano, affected part of the topaz rhyolite lavas. The presence of Nb, Ta and Mn minerals as primary accessories in the rhyolites and as secondary minerals in veins suggests a connection of the fluid circulation phase with the silicic magmatic system. Although at the edge of the active volcanic arc, the Chivinar topaz rhyolites are in correspondence of the transtensive Calama–Olacapato–El Toro fault system, suggesting preferred extensional conditions for the formation of magmatic topaz in convergent settings, consistently with evidence from other known cases worldwide.
Fil: Gioncada, Anna. Università degli Studi di Pisa; Italia
Fil: Orlandi, Paolo. Università degli Studi di Pisa; Italia
Fil: Vezzoli, Luigina. Università dell'Insubria; Italia
Fil: Omarini, Ricardo Hector. Universidad Nacional de Salta. Facultad de Ciencias Naturales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Mazzuoli, Roberto. Università degli Studi di Pisa; Italia
Fil: Lopez Azarevich, Vanina. Universidad Nacional de Salta. Facultad de Ciencias Naturales; Argentina
Fil: Sureda, Ricardo Jose. Universidad Nacional de Salta. Facultad de Ciencias Naturales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Azarevich, Miguel Basilio. Universidad Nacional de Salta. Facultad de Ciencias Naturales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Acocella, Valerio. Università Roma Tre; Italia
Fil: Ruch, Joel. Università Roma Tre; Italia
Materia
Topaz-Bearing Rhyolite
Fluorine
Magmatic Volatiles
Miarolitic Texture
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/31239

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network_name_str CONICET Digital (CONICET)
spelling Topaz magmatic crystallization in rhyolites of the Central Andes (Chivinar volcanic complex, NW Argentina): Constraints from texture, mineralogy and rock chemistryGioncada, AnnaOrlandi, PaoloVezzoli, LuiginaOmarini, Ricardo HectorMazzuoli, RobertoLopez Azarevich, VaninaSureda, Ricardo JoseAzarevich, Miguel BasilioAcocella, ValerioRuch, JoelTopaz-Bearing RhyoliteFluorineMagmatic VolatilesMiarolitic Texturehttps://purl.org/becyt/ford/1.5https://purl.org/becyt/ford/1Topaz-bearing rhyolite lavas were erupted as domes and cryptodomes during the early history of the Late Miocene Chivinar volcano, in Central Andes. These are the only topaz rhyolite lavas recognized in Central Andes. Textural, mineralogical and geochemical data on the Chivinar rhyolites suggest that topaz crystallized from strongly residual, fluorine-rich, peraluminous silicate melts of topazite composition before the complete solidification of the lava domes. Crystallization of the rhyolitic magma began with sodic plagioclase and alkali feldspar phenocrysts in the magma chamber, followed by groundmass quartz + alkali feldspar + minor sodic plagioclase during dome emplacement, and terminated with quartz + topaz + vapour bubbles forming small scattered miaroles. Fluorine partitioning into the fluid phase occurred only in the final stage of groundmass crystallization. The magmatic origin of topaz indicates the presence of a fluorine-rich highly differentiated magma in the early history of the Chivinar volcano and suggests the possibility of rare metals mineralizations related to the cooling and solidification of a silicic magma chamber. A late fluid circulation phase, pre-dating the andesitic phase of the Chivinar volcano, affected part of the topaz rhyolite lavas. The presence of Nb, Ta and Mn minerals as primary accessories in the rhyolites and as secondary minerals in veins suggests a connection of the fluid circulation phase with the silicic magmatic system. Although at the edge of the active volcanic arc, the Chivinar topaz rhyolites are in correspondence of the transtensive Calama–Olacapato–El Toro fault system, suggesting preferred extensional conditions for the formation of magmatic topaz in convergent settings, consistently with evidence from other known cases worldwide.Fil: Gioncada, Anna. Università degli Studi di Pisa; ItaliaFil: Orlandi, Paolo. Università degli Studi di Pisa; ItaliaFil: Vezzoli, Luigina. Università dell'Insubria; ItaliaFil: Omarini, Ricardo Hector. Universidad Nacional de Salta. Facultad de Ciencias Naturales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Mazzuoli, Roberto. Università degli Studi di Pisa; ItaliaFil: Lopez Azarevich, Vanina. Universidad Nacional de Salta. Facultad de Ciencias Naturales; ArgentinaFil: Sureda, Ricardo Jose. Universidad Nacional de Salta. Facultad de Ciencias Naturales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Azarevich, Miguel Basilio. Universidad Nacional de Salta. Facultad de Ciencias Naturales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Acocella, Valerio. Università Roma Tre; ItaliaFil: Ruch, Joel. Università Roma Tre; ItaliaElsevier Science2013-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/31239Ruch, Joel; Acocella, Valerio; Azarevich, Miguel Basilio; Sureda, Ricardo Jose; Lopez Azarevich, Vanina; Mazzuoli, Roberto; et al.; Topaz magmatic crystallization in rhyolites of the Central Andes (Chivinar volcanic complex, NW Argentina): Constraints from texture, mineralogy and rock chemistry; Elsevier Science; Lithos; 184-187; 10-2013; 62-730024-4937CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.lithos.2013.10.023info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0024493713003393info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-17T10:45:59Zoai:ri.conicet.gov.ar:11336/31239instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-17 10:45:59.448CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Topaz magmatic crystallization in rhyolites of the Central Andes (Chivinar volcanic complex, NW Argentina): Constraints from texture, mineralogy and rock chemistry
title Topaz magmatic crystallization in rhyolites of the Central Andes (Chivinar volcanic complex, NW Argentina): Constraints from texture, mineralogy and rock chemistry
spellingShingle Topaz magmatic crystallization in rhyolites of the Central Andes (Chivinar volcanic complex, NW Argentina): Constraints from texture, mineralogy and rock chemistry
Gioncada, Anna
Topaz-Bearing Rhyolite
Fluorine
Magmatic Volatiles
Miarolitic Texture
title_short Topaz magmatic crystallization in rhyolites of the Central Andes (Chivinar volcanic complex, NW Argentina): Constraints from texture, mineralogy and rock chemistry
title_full Topaz magmatic crystallization in rhyolites of the Central Andes (Chivinar volcanic complex, NW Argentina): Constraints from texture, mineralogy and rock chemistry
title_fullStr Topaz magmatic crystallization in rhyolites of the Central Andes (Chivinar volcanic complex, NW Argentina): Constraints from texture, mineralogy and rock chemistry
title_full_unstemmed Topaz magmatic crystallization in rhyolites of the Central Andes (Chivinar volcanic complex, NW Argentina): Constraints from texture, mineralogy and rock chemistry
title_sort Topaz magmatic crystallization in rhyolites of the Central Andes (Chivinar volcanic complex, NW Argentina): Constraints from texture, mineralogy and rock chemistry
dc.creator.none.fl_str_mv Gioncada, Anna
Orlandi, Paolo
Vezzoli, Luigina
Omarini, Ricardo Hector
Mazzuoli, Roberto
Lopez Azarevich, Vanina
Sureda, Ricardo Jose
Azarevich, Miguel Basilio
Acocella, Valerio
Ruch, Joel
author Gioncada, Anna
author_facet Gioncada, Anna
Orlandi, Paolo
Vezzoli, Luigina
Omarini, Ricardo Hector
Mazzuoli, Roberto
Lopez Azarevich, Vanina
Sureda, Ricardo Jose
Azarevich, Miguel Basilio
Acocella, Valerio
Ruch, Joel
author_role author
author2 Orlandi, Paolo
Vezzoli, Luigina
Omarini, Ricardo Hector
Mazzuoli, Roberto
Lopez Azarevich, Vanina
Sureda, Ricardo Jose
Azarevich, Miguel Basilio
Acocella, Valerio
Ruch, Joel
author2_role author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Topaz-Bearing Rhyolite
Fluorine
Magmatic Volatiles
Miarolitic Texture
topic Topaz-Bearing Rhyolite
Fluorine
Magmatic Volatiles
Miarolitic Texture
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.5
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Topaz-bearing rhyolite lavas were erupted as domes and cryptodomes during the early history of the Late Miocene Chivinar volcano, in Central Andes. These are the only topaz rhyolite lavas recognized in Central Andes. Textural, mineralogical and geochemical data on the Chivinar rhyolites suggest that topaz crystallized from strongly residual, fluorine-rich, peraluminous silicate melts of topazite composition before the complete solidification of the lava domes. Crystallization of the rhyolitic magma began with sodic plagioclase and alkali feldspar phenocrysts in the magma chamber, followed by groundmass quartz + alkali feldspar + minor sodic plagioclase during dome emplacement, and terminated with quartz + topaz + vapour bubbles forming small scattered miaroles. Fluorine partitioning into the fluid phase occurred only in the final stage of groundmass crystallization. The magmatic origin of topaz indicates the presence of a fluorine-rich highly differentiated magma in the early history of the Chivinar volcano and suggests the possibility of rare metals mineralizations related to the cooling and solidification of a silicic magma chamber. A late fluid circulation phase, pre-dating the andesitic phase of the Chivinar volcano, affected part of the topaz rhyolite lavas. The presence of Nb, Ta and Mn minerals as primary accessories in the rhyolites and as secondary minerals in veins suggests a connection of the fluid circulation phase with the silicic magmatic system. Although at the edge of the active volcanic arc, the Chivinar topaz rhyolites are in correspondence of the transtensive Calama–Olacapato–El Toro fault system, suggesting preferred extensional conditions for the formation of magmatic topaz in convergent settings, consistently with evidence from other known cases worldwide.
Fil: Gioncada, Anna. Università degli Studi di Pisa; Italia
Fil: Orlandi, Paolo. Università degli Studi di Pisa; Italia
Fil: Vezzoli, Luigina. Università dell'Insubria; Italia
Fil: Omarini, Ricardo Hector. Universidad Nacional de Salta. Facultad de Ciencias Naturales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Mazzuoli, Roberto. Università degli Studi di Pisa; Italia
Fil: Lopez Azarevich, Vanina. Universidad Nacional de Salta. Facultad de Ciencias Naturales; Argentina
Fil: Sureda, Ricardo Jose. Universidad Nacional de Salta. Facultad de Ciencias Naturales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Azarevich, Miguel Basilio. Universidad Nacional de Salta. Facultad de Ciencias Naturales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Acocella, Valerio. Università Roma Tre; Italia
Fil: Ruch, Joel. Università Roma Tre; Italia
description Topaz-bearing rhyolite lavas were erupted as domes and cryptodomes during the early history of the Late Miocene Chivinar volcano, in Central Andes. These are the only topaz rhyolite lavas recognized in Central Andes. Textural, mineralogical and geochemical data on the Chivinar rhyolites suggest that topaz crystallized from strongly residual, fluorine-rich, peraluminous silicate melts of topazite composition before the complete solidification of the lava domes. Crystallization of the rhyolitic magma began with sodic plagioclase and alkali feldspar phenocrysts in the magma chamber, followed by groundmass quartz + alkali feldspar + minor sodic plagioclase during dome emplacement, and terminated with quartz + topaz + vapour bubbles forming small scattered miaroles. Fluorine partitioning into the fluid phase occurred only in the final stage of groundmass crystallization. The magmatic origin of topaz indicates the presence of a fluorine-rich highly differentiated magma in the early history of the Chivinar volcano and suggests the possibility of rare metals mineralizations related to the cooling and solidification of a silicic magma chamber. A late fluid circulation phase, pre-dating the andesitic phase of the Chivinar volcano, affected part of the topaz rhyolite lavas. The presence of Nb, Ta and Mn minerals as primary accessories in the rhyolites and as secondary minerals in veins suggests a connection of the fluid circulation phase with the silicic magmatic system. Although at the edge of the active volcanic arc, the Chivinar topaz rhyolites are in correspondence of the transtensive Calama–Olacapato–El Toro fault system, suggesting preferred extensional conditions for the formation of magmatic topaz in convergent settings, consistently with evidence from other known cases worldwide.
publishDate 2013
dc.date.none.fl_str_mv 2013-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/31239
Ruch, Joel; Acocella, Valerio; Azarevich, Miguel Basilio; Sureda, Ricardo Jose; Lopez Azarevich, Vanina; Mazzuoli, Roberto; et al.; Topaz magmatic crystallization in rhyolites of the Central Andes (Chivinar volcanic complex, NW Argentina): Constraints from texture, mineralogy and rock chemistry; Elsevier Science; Lithos; 184-187; 10-2013; 62-73
0024-4937
CONICET Digital
CONICET
url http://hdl.handle.net/11336/31239
identifier_str_mv Ruch, Joel; Acocella, Valerio; Azarevich, Miguel Basilio; Sureda, Ricardo Jose; Lopez Azarevich, Vanina; Mazzuoli, Roberto; et al.; Topaz magmatic crystallization in rhyolites of the Central Andes (Chivinar volcanic complex, NW Argentina): Constraints from texture, mineralogy and rock chemistry; Elsevier Science; Lithos; 184-187; 10-2013; 62-73
0024-4937
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.lithos.2013.10.023
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0024493713003393
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
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instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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