Reduction of ethanol emissions using manganese oxides supported metallic monoliths: a pilot-scale plant study

Autores
Peluso, Miguel Andrés; Sambeth, Jorge Enrique; Thomas, Horacio Jorge
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Metallic monoliths were prepared by anodized aluminum-scale pilot plant, using sulfuric acid as electrolyte. Anodisation tests were conducted at different times and different temperatures of the electrolytic bath. Aluminum monolith anodized at 40ºC for 30 min was selected for catalysts support. The monoliths were impregnated by two methods: i) impregnation in two stages using two Mn salts in an aqueous medium, and ii) impregnation using a KMnO4 solution in acetone. The last monolith presented a higher and a more homogeneous deposit of manganese oxide layer. The catalytic activity was tested in the total oxidation reaction of ethanol in a pilot-scale reactor at 50 L min-1, and ethanol concentrations of 900, 1800 and 3600 ppm. Monolith impregnated using acetone solution was more active that prepared in aqueous solution in all the experiments carried out.
Fil: Peluso, Miguel Andrés. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Sambeth, Jorge Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Thomas, Horacio Jorge. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas; Argentina. Universidad Nacional de La Plata; Argentina
Materia
Mnox;
Pilot-Scale Plant
Metallic Monoliths
Vocs
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/15747
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/15747
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Reduction of ethanol emissions using manganese oxides supported metallic monoliths: a pilot-scale plant studyPeluso, Miguel AndrésSambeth, Jorge EnriqueThomas, Horacio JorgeMnox;Pilot-Scale PlantMetallic MonolithsVocshttps://purl.org/becyt/ford/2.11https://purl.org/becyt/ford/2Metallic monoliths were prepared by anodized aluminum-scale pilot plant, using sulfuric acid as electrolyte. Anodisation tests were conducted at different times and different temperatures of the electrolytic bath. Aluminum monolith anodized at 40ºC for 30 min was selected for catalysts support. The monoliths were impregnated by two methods: i) impregnation in two stages using two Mn salts in an aqueous medium, and ii) impregnation using a KMnO4 solution in acetone. The last monolith presented a higher and a more homogeneous deposit of manganese oxide layer. The catalytic activity was tested in the total oxidation reaction of ethanol in a pilot-scale reactor at 50 L min-1, and ethanol concentrations of 900, 1800 and 3600 ppm. Monolith impregnated using acetone solution was more active that prepared in aqueous solution in all the experiments carried out.Fil: Peluso, Miguel Andrés. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Sambeth, Jorge Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Thomas, Horacio Jorge. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas; Argentina. Universidad Nacional de La Plata; ArgentinaPlanta Piloto de Ingeniería Química2013-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/15747Peluso, Miguel Andrés; Sambeth, Jorge Enrique; Thomas, Horacio Jorge; Reduction of ethanol emissions using manganese oxides supported metallic monoliths: a pilot-scale plant study; Planta Piloto de Ingeniería Química; Latin American Applied Research; 43; 4; 10-2013; 399-4040327-07931851-8796enginfo:eu-repo/semantics/altIdentifier/url/http://www.laar.uns.edu.ar/indexes/artic_v4304/Vol43_04_399.pdfinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T15:04:28Zoai:ri.conicet.gov.ar:11336/15747instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 15:04:28.484CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Reduction of ethanol emissions using manganese oxides supported metallic monoliths: a pilot-scale plant study
title Reduction of ethanol emissions using manganese oxides supported metallic monoliths: a pilot-scale plant study
spellingShingle Reduction of ethanol emissions using manganese oxides supported metallic monoliths: a pilot-scale plant study
Peluso, Miguel Andrés
Mnox;
Pilot-Scale Plant
Metallic Monoliths
Vocs
title_short Reduction of ethanol emissions using manganese oxides supported metallic monoliths: a pilot-scale plant study
title_full Reduction of ethanol emissions using manganese oxides supported metallic monoliths: a pilot-scale plant study
title_fullStr Reduction of ethanol emissions using manganese oxides supported metallic monoliths: a pilot-scale plant study
title_full_unstemmed Reduction of ethanol emissions using manganese oxides supported metallic monoliths: a pilot-scale plant study
title_sort Reduction of ethanol emissions using manganese oxides supported metallic monoliths: a pilot-scale plant study
dc.creator.none.fl_str_mv Peluso, Miguel Andrés
Sambeth, Jorge Enrique
Thomas, Horacio Jorge
author Peluso, Miguel Andrés
author_facet Peluso, Miguel Andrés
Sambeth, Jorge Enrique
Thomas, Horacio Jorge
author_role author
author2 Sambeth, Jorge Enrique
Thomas, Horacio Jorge
author2_role author
author
dc.subject.none.fl_str_mv Mnox;
Pilot-Scale Plant
Metallic Monoliths
Vocs
topic Mnox;
Pilot-Scale Plant
Metallic Monoliths
Vocs
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.11
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Metallic monoliths were prepared by anodized aluminum-scale pilot plant, using sulfuric acid as electrolyte. Anodisation tests were conducted at different times and different temperatures of the electrolytic bath. Aluminum monolith anodized at 40ºC for 30 min was selected for catalysts support. The monoliths were impregnated by two methods: i) impregnation in two stages using two Mn salts in an aqueous medium, and ii) impregnation using a KMnO4 solution in acetone. The last monolith presented a higher and a more homogeneous deposit of manganese oxide layer. The catalytic activity was tested in the total oxidation reaction of ethanol in a pilot-scale reactor at 50 L min-1, and ethanol concentrations of 900, 1800 and 3600 ppm. Monolith impregnated using acetone solution was more active that prepared in aqueous solution in all the experiments carried out.
Fil: Peluso, Miguel Andrés. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Sambeth, Jorge Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Thomas, Horacio Jorge. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas; Argentina. Universidad Nacional de La Plata; Argentina
description Metallic monoliths were prepared by anodized aluminum-scale pilot plant, using sulfuric acid as electrolyte. Anodisation tests were conducted at different times and different temperatures of the electrolytic bath. Aluminum monolith anodized at 40ºC for 30 min was selected for catalysts support. The monoliths were impregnated by two methods: i) impregnation in two stages using two Mn salts in an aqueous medium, and ii) impregnation using a KMnO4 solution in acetone. The last monolith presented a higher and a more homogeneous deposit of manganese oxide layer. The catalytic activity was tested in the total oxidation reaction of ethanol in a pilot-scale reactor at 50 L min-1, and ethanol concentrations of 900, 1800 and 3600 ppm. Monolith impregnated using acetone solution was more active that prepared in aqueous solution in all the experiments carried out.
publishDate 2013
dc.date.none.fl_str_mv 2013-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/15747
Peluso, Miguel Andrés; Sambeth, Jorge Enrique; Thomas, Horacio Jorge; Reduction of ethanol emissions using manganese oxides supported metallic monoliths: a pilot-scale plant study; Planta Piloto de Ingeniería Química; Latin American Applied Research; 43; 4; 10-2013; 399-404
0327-0793
1851-8796
url http://hdl.handle.net/11336/15747
identifier_str_mv Peluso, Miguel Andrés; Sambeth, Jorge Enrique; Thomas, Horacio Jorge; Reduction of ethanol emissions using manganese oxides supported metallic monoliths: a pilot-scale plant study; Planta Piloto de Ingeniería Química; Latin American Applied Research; 43; 4; 10-2013; 399-404
0327-0793
1851-8796
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.laar.uns.edu.ar/indexes/artic_v4304/Vol43_04_399.pdf
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Planta Piloto de Ingeniería Química
publisher.none.fl_str_mv Planta Piloto de Ingeniería Química
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846083187972767744
score 13.22299

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