High-pressure experimental data of CO 2 + mitotane and CO 2 + ethanol + mitotane mixtures

Autores
Giufrida, W. M.; Rodriguez Reartes, Sabrina Belen; Alonso, C. G.; Zabaloy, Marcelo Santiago; Cabral, V. F.; Tavares, F. W.; Cardozo Filho, L.
Año de publicación
2011
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
This work presents new experimental phase equilibrium data for mitotane in supercritical CO 2 and mitone in supercritical CO 2 plus ethanol. The synthetic-static method in a high-pressure variable-volume view cell was used to measure the solid-fluid (SF) and the fluid-fluid (FF) equilibrium data. The phase equilibrium experiments were carried out in the temperature range from (298 to 333) K and in the pressure range from (3.44 to 21.84) MPa. The Peng-Robinson equation of state (PR-EoS) was used for describing the fluid phases, and an expression for the fugacity of pure solid mitotane was used for representing the solid phase. This made it possible to model the SF and FF equilibrium data for the CO 2 + mitotane mixtures. Fair agreement was found between experimental and calculated values.
Fil: Giufrida, W. M.. Universidade Estadual de Maringá; Brasil
Fil: Rodriguez Reartes, Sabrina Belen. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Alonso, C. G.. Universidade Estadual de Maringá; Brasil
Fil: Zabaloy, Marcelo Santiago. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Cabral, V. F.. Universidade Estadual de Maringá; Brasil
Fil: Tavares, F. W.. Universidade Federal do Rio de Janeiro; Brasil
Fil: Cardozo Filho, L.. Universidade Estadual de Maringá; Brasil
Materia
Mitotane
Co2
Ethanol
Solid-Fluid
Fluid-Fluid
Vapor-Liquid
Experimental Equilibrium Data
Peng-Robinson Equation of State
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/56156
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling High-pressure experimental data of CO 2 + mitotane and CO 2 + ethanol + mitotane mixturesGiufrida, W. M.Rodriguez Reartes, Sabrina BelenAlonso, C. G.Zabaloy, Marcelo SantiagoCabral, V. F.Tavares, F. W.Cardozo Filho, L.MitotaneCo2EthanolSolid-FluidFluid-FluidVapor-LiquidExperimental Equilibrium DataPeng-Robinson Equation of Statehttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2This work presents new experimental phase equilibrium data for mitotane in supercritical CO 2 and mitone in supercritical CO 2 plus ethanol. The synthetic-static method in a high-pressure variable-volume view cell was used to measure the solid-fluid (SF) and the fluid-fluid (FF) equilibrium data. The phase equilibrium experiments were carried out in the temperature range from (298 to 333) K and in the pressure range from (3.44 to 21.84) MPa. The Peng-Robinson equation of state (PR-EoS) was used for describing the fluid phases, and an expression for the fugacity of pure solid mitotane was used for representing the solid phase. This made it possible to model the SF and FF equilibrium data for the CO 2 + mitotane mixtures. Fair agreement was found between experimental and calculated values.Fil: Giufrida, W. M.. Universidade Estadual de Maringá; BrasilFil: Rodriguez Reartes, Sabrina Belen. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Alonso, C. G.. Universidade Estadual de Maringá; BrasilFil: Zabaloy, Marcelo Santiago. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Cabral, V. F.. Universidade Estadual de Maringá; BrasilFil: Tavares, F. W.. Universidade Federal do Rio de Janeiro; BrasilFil: Cardozo Filho, L.. Universidade Estadual de Maringá; BrasilAmerican Chemical Society2011-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/56156Giufrida, W. M.; Rodriguez Reartes, Sabrina Belen; Alonso, C. G.; Zabaloy, Marcelo Santiago; Cabral, V. F.; et al.; High-pressure experimental data of CO 2 + mitotane and CO 2 + ethanol + mitotane mixtures; American Chemical Society; Journal of Chemical and Engineering Data; 56; 12; 12-2011; 4333-43410021-9568CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/je101233kinfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/abs/10.1021/je101233kinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:56:51Zoai:ri.conicet.gov.ar:11336/56156instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:56:52.224CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv High-pressure experimental data of CO 2 + mitotane and CO 2 + ethanol + mitotane mixtures
title High-pressure experimental data of CO 2 + mitotane and CO 2 + ethanol + mitotane mixtures
spellingShingle High-pressure experimental data of CO 2 + mitotane and CO 2 + ethanol + mitotane mixtures
Giufrida, W. M.
Mitotane
Co2
Ethanol
Solid-Fluid
Fluid-Fluid
Vapor-Liquid
Experimental Equilibrium Data
Peng-Robinson Equation of State
title_short High-pressure experimental data of CO 2 + mitotane and CO 2 + ethanol + mitotane mixtures
title_full High-pressure experimental data of CO 2 + mitotane and CO 2 + ethanol + mitotane mixtures
title_fullStr High-pressure experimental data of CO 2 + mitotane and CO 2 + ethanol + mitotane mixtures
title_full_unstemmed High-pressure experimental data of CO 2 + mitotane and CO 2 + ethanol + mitotane mixtures
title_sort High-pressure experimental data of CO 2 + mitotane and CO 2 + ethanol + mitotane mixtures
dc.creator.none.fl_str_mv Giufrida, W. M.
Rodriguez Reartes, Sabrina Belen
Alonso, C. G.
Zabaloy, Marcelo Santiago
Cabral, V. F.
Tavares, F. W.
Cardozo Filho, L.
author Giufrida, W. M.
author_facet Giufrida, W. M.
Rodriguez Reartes, Sabrina Belen
Alonso, C. G.
Zabaloy, Marcelo Santiago
Cabral, V. F.
Tavares, F. W.
Cardozo Filho, L.
author_role author
author2 Rodriguez Reartes, Sabrina Belen
Alonso, C. G.
Zabaloy, Marcelo Santiago
Cabral, V. F.
Tavares, F. W.
Cardozo Filho, L.
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Mitotane
Co2
Ethanol
Solid-Fluid
Fluid-Fluid
Vapor-Liquid
Experimental Equilibrium Data
Peng-Robinson Equation of State
topic Mitotane
Co2
Ethanol
Solid-Fluid
Fluid-Fluid
Vapor-Liquid
Experimental Equilibrium Data
Peng-Robinson Equation of State
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv This work presents new experimental phase equilibrium data for mitotane in supercritical CO 2 and mitone in supercritical CO 2 plus ethanol. The synthetic-static method in a high-pressure variable-volume view cell was used to measure the solid-fluid (SF) and the fluid-fluid (FF) equilibrium data. The phase equilibrium experiments were carried out in the temperature range from (298 to 333) K and in the pressure range from (3.44 to 21.84) MPa. The Peng-Robinson equation of state (PR-EoS) was used for describing the fluid phases, and an expression for the fugacity of pure solid mitotane was used for representing the solid phase. This made it possible to model the SF and FF equilibrium data for the CO 2 + mitotane mixtures. Fair agreement was found between experimental and calculated values.
Fil: Giufrida, W. M.. Universidade Estadual de Maringá; Brasil
Fil: Rodriguez Reartes, Sabrina Belen. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Alonso, C. G.. Universidade Estadual de Maringá; Brasil
Fil: Zabaloy, Marcelo Santiago. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Cabral, V. F.. Universidade Estadual de Maringá; Brasil
Fil: Tavares, F. W.. Universidade Federal do Rio de Janeiro; Brasil
Fil: Cardozo Filho, L.. Universidade Estadual de Maringá; Brasil
description This work presents new experimental phase equilibrium data for mitotane in supercritical CO 2 and mitone in supercritical CO 2 plus ethanol. The synthetic-static method in a high-pressure variable-volume view cell was used to measure the solid-fluid (SF) and the fluid-fluid (FF) equilibrium data. The phase equilibrium experiments were carried out in the temperature range from (298 to 333) K and in the pressure range from (3.44 to 21.84) MPa. The Peng-Robinson equation of state (PR-EoS) was used for describing the fluid phases, and an expression for the fugacity of pure solid mitotane was used for representing the solid phase. This made it possible to model the SF and FF equilibrium data for the CO 2 + mitotane mixtures. Fair agreement was found between experimental and calculated values.
publishDate 2011
dc.date.none.fl_str_mv 2011-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/56156
Giufrida, W. M.; Rodriguez Reartes, Sabrina Belen; Alonso, C. G.; Zabaloy, Marcelo Santiago; Cabral, V. F.; et al.; High-pressure experimental data of CO 2 + mitotane and CO 2 + ethanol + mitotane mixtures; American Chemical Society; Journal of Chemical and Engineering Data; 56; 12; 12-2011; 4333-4341
0021-9568
CONICET Digital
CONICET
url http://hdl.handle.net/11336/56156
identifier_str_mv Giufrida, W. M.; Rodriguez Reartes, Sabrina Belen; Alonso, C. G.; Zabaloy, Marcelo Santiago; Cabral, V. F.; et al.; High-pressure experimental data of CO 2 + mitotane and CO 2 + ethanol + mitotane mixtures; American Chemical Society; Journal of Chemical and Engineering Data; 56; 12; 12-2011; 4333-4341
0021-9568
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/je101233k
info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/abs/10.1021/je101233k
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842269429116698624
score 13.13397

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