Turning yerba mate waste into high-performance lithium–sulfur battery cathodes

Autores
Tesio, Alvaro Yamil; de Haro Niza, Jorge; Sanchez, Laura Mabel; Rodríguez, Alejandro; Caballero, Alvaro
Año de publicación
2023
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this study, a non-activated carbon (YMCsingle bondC) derived from waste yerba mate was examined as a matrix for the development of a carbon‑sulfur composite cathode (YMC-C@S). The carbonaceous material is produced through a simple process of pyrolyzing extracted cellulose from residual yerba mate, avoiding costly and complex stages of chemical activation or additional purification. Due to its high carbon content and mesoporous structure, YMC-C can serve as an effective host for sulfur. After adding 70 % sulfur via the melt diffusion method, the YMC-C@S composite shown a remarkable initial capacity of 1678 mAh gS−1 as a cathode material, along with high reversible capacity at a low charge/discharge rate. Additionally, even when subjected to an increased C-rate during long cycling, discharge capacities at 1C of 777 mAh gS−1 and 674 mAh gS−1 after 165 cycles demonstrate good rate capability. When the cycling protocol is optimized, the YMC-C@S composite exhibits very low loss of capacity per cycle, even when using fast charge stages. The efficacy of YMC-C as an efficient cathode material in LSB is confirmed by the positive results of a self-discharge test conducted over a period of 7.5 months.
Fil: Tesio, Alvaro Yamil. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy. - Universidad Nacional de Jujuy. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy. - Gobierno de la Provincia de Jujuy. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy; Argentina
Fil: de Haro Niza, Jorge. Universidad de Córdoba; España
Fil: Sanchez, Laura Mabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Rodríguez, Alejandro. Universidad de Córdoba; España
Fil: Caballero, Alvaro. Universidad de Córdoba; España
Materia
BIOMASS
BIO-WASTE
VALORIZATION
ENERGY STORAGE
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/230298
Acceder
id CONICETDig_d56aeb6a7b0e2acd42b9a346ccf5a181
oai_identifier_str oai:ri.conicet.gov.ar:11336/230298
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Turning yerba mate waste into high-performance lithium–sulfur battery cathodesTesio, Alvaro Yamilde Haro Niza, JorgeSanchez, Laura MabelRodríguez, AlejandroCaballero, AlvaroBIOMASSBIO-WASTEVALORIZATIONENERGY STORAGEhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1In this study, a non-activated carbon (YMCsingle bondC) derived from waste yerba mate was examined as a matrix for the development of a carbon‑sulfur composite cathode (YMC-C@S). The carbonaceous material is produced through a simple process of pyrolyzing extracted cellulose from residual yerba mate, avoiding costly and complex stages of chemical activation or additional purification. Due to its high carbon content and mesoporous structure, YMC-C can serve as an effective host for sulfur. After adding 70 % sulfur via the melt diffusion method, the YMC-C@S composite shown a remarkable initial capacity of 1678 mAh gS−1 as a cathode material, along with high reversible capacity at a low charge/discharge rate. Additionally, even when subjected to an increased C-rate during long cycling, discharge capacities at 1C of 777 mAh gS−1 and 674 mAh gS−1 after 165 cycles demonstrate good rate capability. When the cycling protocol is optimized, the YMC-C@S composite exhibits very low loss of capacity per cycle, even when using fast charge stages. The efficacy of YMC-C as an efficient cathode material in LSB is confirmed by the positive results of a self-discharge test conducted over a period of 7.5 months.Fil: Tesio, Alvaro Yamil. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy. - Universidad Nacional de Jujuy. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy. - Gobierno de la Provincia de Jujuy. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy; ArgentinaFil: de Haro Niza, Jorge. Universidad de Córdoba; EspañaFil: Sanchez, Laura Mabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Rodríguez, Alejandro. Universidad de Córdoba; EspañaFil: Caballero, Alvaro. Universidad de Córdoba; EspañaElsevier2023-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/230298Tesio, Alvaro Yamil; de Haro Niza, Jorge; Sanchez, Laura Mabel; Rodríguez, Alejandro; Caballero, Alvaro; Turning yerba mate waste into high-performance lithium–sulfur battery cathodes; Elsevier; Journal of Energy Storage; 67; 9-2023; 1-102352-152XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S2352152X23010241info:eu-repo/semantics/altIdentifier/doi/10.1016/j.est.2023.107627info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:48:06Zoai:ri.conicet.gov.ar:11336/230298instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:48:06.436CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Turning yerba mate waste into high-performance lithium–sulfur battery cathodes
title Turning yerba mate waste into high-performance lithium–sulfur battery cathodes
spellingShingle Turning yerba mate waste into high-performance lithium–sulfur battery cathodes
Tesio, Alvaro Yamil
BIOMASS
BIO-WASTE
VALORIZATION
ENERGY STORAGE
title_short Turning yerba mate waste into high-performance lithium–sulfur battery cathodes
title_full Turning yerba mate waste into high-performance lithium–sulfur battery cathodes
title_fullStr Turning yerba mate waste into high-performance lithium–sulfur battery cathodes
title_full_unstemmed Turning yerba mate waste into high-performance lithium–sulfur battery cathodes
title_sort Turning yerba mate waste into high-performance lithium–sulfur battery cathodes
dc.creator.none.fl_str_mv Tesio, Alvaro Yamil
de Haro Niza, Jorge
Sanchez, Laura Mabel
Rodríguez, Alejandro
Caballero, Alvaro
author Tesio, Alvaro Yamil
author_facet Tesio, Alvaro Yamil
de Haro Niza, Jorge
Sanchez, Laura Mabel
Rodríguez, Alejandro
Caballero, Alvaro
author_role author
author2 de Haro Niza, Jorge
Sanchez, Laura Mabel
Rodríguez, Alejandro
Caballero, Alvaro
author2_role author
author
author
author
dc.subject.none.fl_str_mv BIOMASS
BIO-WASTE
VALORIZATION
ENERGY STORAGE
topic BIOMASS
BIO-WASTE
VALORIZATION
ENERGY STORAGE
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv In this study, a non-activated carbon (YMCsingle bondC) derived from waste yerba mate was examined as a matrix for the development of a carbon‑sulfur composite cathode (YMC-C@S). The carbonaceous material is produced through a simple process of pyrolyzing extracted cellulose from residual yerba mate, avoiding costly and complex stages of chemical activation or additional purification. Due to its high carbon content and mesoporous structure, YMC-C can serve as an effective host for sulfur. After adding 70 % sulfur via the melt diffusion method, the YMC-C@S composite shown a remarkable initial capacity of 1678 mAh gS−1 as a cathode material, along with high reversible capacity at a low charge/discharge rate. Additionally, even when subjected to an increased C-rate during long cycling, discharge capacities at 1C of 777 mAh gS−1 and 674 mAh gS−1 after 165 cycles demonstrate good rate capability. When the cycling protocol is optimized, the YMC-C@S composite exhibits very low loss of capacity per cycle, even when using fast charge stages. The efficacy of YMC-C as an efficient cathode material in LSB is confirmed by the positive results of a self-discharge test conducted over a period of 7.5 months.
Fil: Tesio, Alvaro Yamil. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy. - Universidad Nacional de Jujuy. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy. - Gobierno de la Provincia de Jujuy. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy; Argentina
Fil: de Haro Niza, Jorge. Universidad de Córdoba; España
Fil: Sanchez, Laura Mabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Rodríguez, Alejandro. Universidad de Córdoba; España
Fil: Caballero, Alvaro. Universidad de Córdoba; España
description In this study, a non-activated carbon (YMCsingle bondC) derived from waste yerba mate was examined as a matrix for the development of a carbon‑sulfur composite cathode (YMC-C@S). The carbonaceous material is produced through a simple process of pyrolyzing extracted cellulose from residual yerba mate, avoiding costly and complex stages of chemical activation or additional purification. Due to its high carbon content and mesoporous structure, YMC-C can serve as an effective host for sulfur. After adding 70 % sulfur via the melt diffusion method, the YMC-C@S composite shown a remarkable initial capacity of 1678 mAh gS−1 as a cathode material, along with high reversible capacity at a low charge/discharge rate. Additionally, even when subjected to an increased C-rate during long cycling, discharge capacities at 1C of 777 mAh gS−1 and 674 mAh gS−1 after 165 cycles demonstrate good rate capability. When the cycling protocol is optimized, the YMC-C@S composite exhibits very low loss of capacity per cycle, even when using fast charge stages. The efficacy of YMC-C as an efficient cathode material in LSB is confirmed by the positive results of a self-discharge test conducted over a period of 7.5 months.
publishDate 2023
dc.date.none.fl_str_mv 2023-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/230298
Tesio, Alvaro Yamil; de Haro Niza, Jorge; Sanchez, Laura Mabel; Rodríguez, Alejandro; Caballero, Alvaro; Turning yerba mate waste into high-performance lithium–sulfur battery cathodes; Elsevier; Journal of Energy Storage; 67; 9-2023; 1-10
2352-152X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/230298
identifier_str_mv Tesio, Alvaro Yamil; de Haro Niza, Jorge; Sanchez, Laura Mabel; Rodríguez, Alejandro; Caballero, Alvaro; Turning yerba mate waste into high-performance lithium–sulfur battery cathodes; Elsevier; Journal of Energy Storage; 67; 9-2023; 1-10
2352-152X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S2352152X23010241
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.est.2023.107627
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844613496108482560
score 13.070432

Publicaciones similares