Formation and kinetics of transient metastable states in mixtures under coupled phase ordering and chemical demixing

Autores
Soulé, Ezequiel Rodolfo; Rey, A.D.
Año de publicación
2009
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
We present theory and simulation of simultaneous chemical demixing and phase ordering in a polymer-liquid-crystal mixture in conditions where isotropic-isotropic phase separation is metastable with respect to isotropic-nematic phase transition. It is found that mesophase formation proceeds by a transient metastable phase that surround the ordered phase, and whose lifetime is a function of the ratio of diffusional-to-orientational mobilities. It is shown that kinetic phase ordering in polymer-mesogen mixtures is analogous to kinetic crystallization in polymer solutions. © EPLA, 2009.
Fil: Soulé, Ezequiel Rodolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Rey, A.D.. McGill University; Canadá
Materia
Difussion
Phase Transition
Interface
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/66518
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Formation and kinetics of transient metastable states in mixtures under coupled phase ordering and chemical demixingSoulé, Ezequiel RodolfoRey, A.D.DifussionPhase TransitionInterfacehttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1We present theory and simulation of simultaneous chemical demixing and phase ordering in a polymer-liquid-crystal mixture in conditions where isotropic-isotropic phase separation is metastable with respect to isotropic-nematic phase transition. It is found that mesophase formation proceeds by a transient metastable phase that surround the ordered phase, and whose lifetime is a function of the ratio of diffusional-to-orientational mobilities. It is shown that kinetic phase ordering in polymer-mesogen mixtures is analogous to kinetic crystallization in polymer solutions. © EPLA, 2009.Fil: Soulé, Ezequiel Rodolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Rey, A.D.. McGill University; CanadáEurophysics Letters2009-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/66518Soulé, Ezequiel Rodolfo; Rey, A.D.; Formation and kinetics of transient metastable states in mixtures under coupled phase ordering and chemical demixing; Europhysics Letters; Europhysics Letters; 86; 4; 12-2009; 46006-460110295-5075CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1209/0295-5075/86/46006info:eu-repo/semantics/altIdentifier/url/http://iopscience.iop.org/article/10.1209/0295-5075/86/46006info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:33:07Zoai:ri.conicet.gov.ar:11336/66518instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:33:07.828CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Formation and kinetics of transient metastable states in mixtures under coupled phase ordering and chemical demixing
title Formation and kinetics of transient metastable states in mixtures under coupled phase ordering and chemical demixing
spellingShingle Formation and kinetics of transient metastable states in mixtures under coupled phase ordering and chemical demixing
Soulé, Ezequiel Rodolfo
Difussion
Phase Transition
Interface
title_short Formation and kinetics of transient metastable states in mixtures under coupled phase ordering and chemical demixing
title_full Formation and kinetics of transient metastable states in mixtures under coupled phase ordering and chemical demixing
title_fullStr Formation and kinetics of transient metastable states in mixtures under coupled phase ordering and chemical demixing
title_full_unstemmed Formation and kinetics of transient metastable states in mixtures under coupled phase ordering and chemical demixing
title_sort Formation and kinetics of transient metastable states in mixtures under coupled phase ordering and chemical demixing
dc.creator.none.fl_str_mv Soulé, Ezequiel Rodolfo
Rey, A.D.
author Soulé, Ezequiel Rodolfo
author_facet Soulé, Ezequiel Rodolfo
Rey, A.D.
author_role author
author2 Rey, A.D.
author2_role author
dc.subject.none.fl_str_mv Difussion
Phase Transition
Interface
topic Difussion
Phase Transition
Interface
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv We present theory and simulation of simultaneous chemical demixing and phase ordering in a polymer-liquid-crystal mixture in conditions where isotropic-isotropic phase separation is metastable with respect to isotropic-nematic phase transition. It is found that mesophase formation proceeds by a transient metastable phase that surround the ordered phase, and whose lifetime is a function of the ratio of diffusional-to-orientational mobilities. It is shown that kinetic phase ordering in polymer-mesogen mixtures is analogous to kinetic crystallization in polymer solutions. © EPLA, 2009.
Fil: Soulé, Ezequiel Rodolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Rey, A.D.. McGill University; Canadá
description We present theory and simulation of simultaneous chemical demixing and phase ordering in a polymer-liquid-crystal mixture in conditions where isotropic-isotropic phase separation is metastable with respect to isotropic-nematic phase transition. It is found that mesophase formation proceeds by a transient metastable phase that surround the ordered phase, and whose lifetime is a function of the ratio of diffusional-to-orientational mobilities. It is shown that kinetic phase ordering in polymer-mesogen mixtures is analogous to kinetic crystallization in polymer solutions. © EPLA, 2009.
publishDate 2009
dc.date.none.fl_str_mv 2009-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/66518
Soulé, Ezequiel Rodolfo; Rey, A.D.; Formation and kinetics of transient metastable states in mixtures under coupled phase ordering and chemical demixing; Europhysics Letters; Europhysics Letters; 86; 4; 12-2009; 46006-46011
0295-5075
CONICET Digital
CONICET
url http://hdl.handle.net/11336/66518
identifier_str_mv Soulé, Ezequiel Rodolfo; Rey, A.D.; Formation and kinetics of transient metastable states in mixtures under coupled phase ordering and chemical demixing; Europhysics Letters; Europhysics Letters; 86; 4; 12-2009; 46006-46011
0295-5075
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1209/0295-5075/86/46006
info:eu-repo/semantics/altIdentifier/url/http://iopscience.iop.org/article/10.1209/0295-5075/86/46006
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Europhysics Letters
publisher.none.fl_str_mv Europhysics Letters
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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