Linking Soil, Water, and Honey Composition To Assess the Geographical Origin of Argentinean Honey by Multielemental and Isotopic Analyses

Autores
Baroni, María Verónica; Podio, Natalia Soledad; Badini, Raúl G.; Inga, Marcela; Ostera, Hector Adolfo; Cagnoni, Mariana Celina; Gautier, Eduardo Amilcar; Peral Garcia, Pilar; Hoogewerff, Jurian; Wunderlin, Daniel Alberto
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The objective of this research was to investigate the development of a reliable fingerprint from elemental and isotopic signatures of Argentinean honey to assess its geographical provenance. Honey, soil, and water from three regions (Córdoba, Buenos Aires, and Entre Rı́os) were collected. The multielemental composition was determined by ICP-MS. δ13C was measured by isotopic ratio mass spectrometry, whereas the 87Sr/86Sr ratio was determined using thermal ionization mass spectrometry. The data were analyzed by chemometrics looking for the association between the elements, stable isotopes, and honey samples from the three studied areas. Honey samples were differentiated by classification trees and discriminant analysis using a combination of eight key variables (Rb, K/Rb, B, U, 87Sr/86Sr, Na, La, and Zn) presenting differences among the studied regions. The application of canonical correlation analysis and generalized procrustes analysis showed 91.5% consensus between soil, water, and honey samples, in addition to clear differences between studied areas. To the authors’ knowledge, this is the first report demonstrating the correspondence between soil, water, and honey samples using different statistical methods, showing that elemental and isotopic honey compositions are related to soil and water characteristics of the site of origin.
Fil: Baroni, María Verónica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Ciencia y Tecnología de Alimentos Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Ciencia y Tecnología de Alimentos Córdoba; Argentina
Fil: Podio, Natalia Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Ciencia y Tecnología de Alimentos Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Ciencia y Tecnología de Alimentos Córdoba; Argentina
Fil: Badini, Raúl G.. Provincia de Córdoba. Ministerio de Ciencia y Técnica. Centro de Excelencia en Productos y Procesos de Córdoba; Argentina
Fil: Inga, Marcela. Provincia de Córdoba. Ministerio de Ciencia y Técnica. Centro de Excelencia en Productos y Procesos de Córdoba; Argentina
Fil: Ostera, Hector Adolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Geocronología y Geología Isotopica. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Geocronología y Geología Isotópica; Argentina
Fil: Cagnoni, Mariana Celina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Geocronología y Geología Isotopica. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Geocronología y Geología Isotópica; Argentina
Fil: Gautier, Eduardo Amilcar. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina
Fil: Peral Garcia, Pilar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico CONICET- La Plata. Instituto de Genética Veterinaria ; Argentina
Fil: Hoogewerff, Jurian. University Of Otago; Canadá
Fil: Wunderlin, Daniel Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Ciencia y Tecnología de Alimentos Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Ciencia y Tecnología de Alimentos Córdoba; Argentina
Materia
Honey
Traceability
Minerals
Isotopes
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/43308
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/43308
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Linking Soil, Water, and Honey Composition To Assess the Geographical Origin of Argentinean Honey by Multielemental and Isotopic AnalysesBaroni, María VerónicaPodio, Natalia SoledadBadini, Raúl G.Inga, MarcelaOstera, Hector AdolfoCagnoni, Mariana CelinaGautier, Eduardo AmilcarPeral Garcia, PilarHoogewerff, JurianWunderlin, Daniel AlbertoHoneyTraceabilityMineralsIsotopeshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The objective of this research was to investigate the development of a reliable fingerprint from elemental and isotopic signatures of Argentinean honey to assess its geographical provenance. Honey, soil, and water from three regions (Córdoba, Buenos Aires, and Entre Rı́os) were collected. The multielemental composition was determined by ICP-MS. δ13C was measured by isotopic ratio mass spectrometry, whereas the 87Sr/86Sr ratio was determined using thermal ionization mass spectrometry. The data were analyzed by chemometrics looking for the association between the elements, stable isotopes, and honey samples from the three studied areas. Honey samples were differentiated by classification trees and discriminant analysis using a combination of eight key variables (Rb, K/Rb, B, U, 87Sr/86Sr, Na, La, and Zn) presenting differences among the studied regions. The application of canonical correlation analysis and generalized procrustes analysis showed 91.5% consensus between soil, water, and honey samples, in addition to clear differences between studied areas. To the authors’ knowledge, this is the first report demonstrating the correspondence between soil, water, and honey samples using different statistical methods, showing that elemental and isotopic honey compositions are related to soil and water characteristics of the site of origin.Fil: Baroni, María Verónica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Ciencia y Tecnología de Alimentos Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Ciencia y Tecnología de Alimentos Córdoba; ArgentinaFil: Podio, Natalia Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Ciencia y Tecnología de Alimentos Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Ciencia y Tecnología de Alimentos Córdoba; ArgentinaFil: Badini, Raúl G.. Provincia de Córdoba. Ministerio de Ciencia y Técnica. Centro de Excelencia en Productos y Procesos de Córdoba; ArgentinaFil: Inga, Marcela. Provincia de Córdoba. Ministerio de Ciencia y Técnica. Centro de Excelencia en Productos y Procesos de Córdoba; ArgentinaFil: Ostera, Hector Adolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Geocronología y Geología Isotopica. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Geocronología y Geología Isotópica; ArgentinaFil: Cagnoni, Mariana Celina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Geocronología y Geología Isotopica. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Geocronología y Geología Isotópica; ArgentinaFil: Gautier, Eduardo Amilcar. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; ArgentinaFil: Peral Garcia, Pilar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico CONICET- La Plata. Instituto de Genética Veterinaria ; ArgentinaFil: Hoogewerff, Jurian. University Of Otago; CanadáFil: Wunderlin, Daniel Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Ciencia y Tecnología de Alimentos Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Ciencia y Tecnología de Alimentos Córdoba; ArgentinaAmerican Chemical Society2015-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/43308Baroni, María Verónica; Podio, Natalia Soledad; Badini, Raúl G.; Inga, Marcela; Ostera, Hector Adolfo; et al.; Linking Soil, Water, and Honey Composition To Assess the Geographical Origin of Argentinean Honey by Multielemental and Isotopic Analyses; American Chemical Society; Journal of Agricultural and Food Chemistry; 63; 18; 5-2015; 4638-46450021-8561CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/jf5060112info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/jf5060112info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T14:52:22Zoai:ri.conicet.gov.ar:11336/43308instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 14:52:22.361CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Linking Soil, Water, and Honey Composition To Assess the Geographical Origin of Argentinean Honey by Multielemental and Isotopic Analyses
title Linking Soil, Water, and Honey Composition To Assess the Geographical Origin of Argentinean Honey by Multielemental and Isotopic Analyses
spellingShingle Linking Soil, Water, and Honey Composition To Assess the Geographical Origin of Argentinean Honey by Multielemental and Isotopic Analyses
Baroni, María Verónica
Honey
Traceability
Minerals
Isotopes
title_short Linking Soil, Water, and Honey Composition To Assess the Geographical Origin of Argentinean Honey by Multielemental and Isotopic Analyses
title_full Linking Soil, Water, and Honey Composition To Assess the Geographical Origin of Argentinean Honey by Multielemental and Isotopic Analyses
title_fullStr Linking Soil, Water, and Honey Composition To Assess the Geographical Origin of Argentinean Honey by Multielemental and Isotopic Analyses
title_full_unstemmed Linking Soil, Water, and Honey Composition To Assess the Geographical Origin of Argentinean Honey by Multielemental and Isotopic Analyses
title_sort Linking Soil, Water, and Honey Composition To Assess the Geographical Origin of Argentinean Honey by Multielemental and Isotopic Analyses
dc.creator.none.fl_str_mv Baroni, María Verónica
Podio, Natalia Soledad
Badini, Raúl G.
Inga, Marcela
Ostera, Hector Adolfo
Cagnoni, Mariana Celina
Gautier, Eduardo Amilcar
Peral Garcia, Pilar
Hoogewerff, Jurian
Wunderlin, Daniel Alberto
author Baroni, María Verónica
author_facet Baroni, María Verónica
Podio, Natalia Soledad
Badini, Raúl G.
Inga, Marcela
Ostera, Hector Adolfo
Cagnoni, Mariana Celina
Gautier, Eduardo Amilcar
Peral Garcia, Pilar
Hoogewerff, Jurian
Wunderlin, Daniel Alberto
author_role author
author2 Podio, Natalia Soledad
Badini, Raúl G.
Inga, Marcela
Ostera, Hector Adolfo
Cagnoni, Mariana Celina
Gautier, Eduardo Amilcar
Peral Garcia, Pilar
Hoogewerff, Jurian
Wunderlin, Daniel Alberto
author2_role author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Honey
Traceability
Minerals
Isotopes
topic Honey
Traceability
Minerals
Isotopes
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The objective of this research was to investigate the development of a reliable fingerprint from elemental and isotopic signatures of Argentinean honey to assess its geographical provenance. Honey, soil, and water from three regions (Córdoba, Buenos Aires, and Entre Rı́os) were collected. The multielemental composition was determined by ICP-MS. δ13C was measured by isotopic ratio mass spectrometry, whereas the 87Sr/86Sr ratio was determined using thermal ionization mass spectrometry. The data were analyzed by chemometrics looking for the association between the elements, stable isotopes, and honey samples from the three studied areas. Honey samples were differentiated by classification trees and discriminant analysis using a combination of eight key variables (Rb, K/Rb, B, U, 87Sr/86Sr, Na, La, and Zn) presenting differences among the studied regions. The application of canonical correlation analysis and generalized procrustes analysis showed 91.5% consensus between soil, water, and honey samples, in addition to clear differences between studied areas. To the authors’ knowledge, this is the first report demonstrating the correspondence between soil, water, and honey samples using different statistical methods, showing that elemental and isotopic honey compositions are related to soil and water characteristics of the site of origin.
Fil: Baroni, María Verónica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Ciencia y Tecnología de Alimentos Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Ciencia y Tecnología de Alimentos Córdoba; Argentina
Fil: Podio, Natalia Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Ciencia y Tecnología de Alimentos Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Ciencia y Tecnología de Alimentos Córdoba; Argentina
Fil: Badini, Raúl G.. Provincia de Córdoba. Ministerio de Ciencia y Técnica. Centro de Excelencia en Productos y Procesos de Córdoba; Argentina
Fil: Inga, Marcela. Provincia de Córdoba. Ministerio de Ciencia y Técnica. Centro de Excelencia en Productos y Procesos de Córdoba; Argentina
Fil: Ostera, Hector Adolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Geocronología y Geología Isotopica. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Geocronología y Geología Isotópica; Argentina
Fil: Cagnoni, Mariana Celina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Geocronología y Geología Isotopica. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Geocronología y Geología Isotópica; Argentina
Fil: Gautier, Eduardo Amilcar. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina
Fil: Peral Garcia, Pilar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico CONICET- La Plata. Instituto de Genética Veterinaria ; Argentina
Fil: Hoogewerff, Jurian. University Of Otago; Canadá
Fil: Wunderlin, Daniel Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Ciencia y Tecnología de Alimentos Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Ciencia y Tecnología de Alimentos Córdoba; Argentina
description The objective of this research was to investigate the development of a reliable fingerprint from elemental and isotopic signatures of Argentinean honey to assess its geographical provenance. Honey, soil, and water from three regions (Córdoba, Buenos Aires, and Entre Rı́os) were collected. The multielemental composition was determined by ICP-MS. δ13C was measured by isotopic ratio mass spectrometry, whereas the 87Sr/86Sr ratio was determined using thermal ionization mass spectrometry. The data were analyzed by chemometrics looking for the association between the elements, stable isotopes, and honey samples from the three studied areas. Honey samples were differentiated by classification trees and discriminant analysis using a combination of eight key variables (Rb, K/Rb, B, U, 87Sr/86Sr, Na, La, and Zn) presenting differences among the studied regions. The application of canonical correlation analysis and generalized procrustes analysis showed 91.5% consensus between soil, water, and honey samples, in addition to clear differences between studied areas. To the authors’ knowledge, this is the first report demonstrating the correspondence between soil, water, and honey samples using different statistical methods, showing that elemental and isotopic honey compositions are related to soil and water characteristics of the site of origin.
publishDate 2015
dc.date.none.fl_str_mv 2015-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/43308
Baroni, María Verónica; Podio, Natalia Soledad; Badini, Raúl G.; Inga, Marcela; Ostera, Hector Adolfo; et al.; Linking Soil, Water, and Honey Composition To Assess the Geographical Origin of Argentinean Honey by Multielemental and Isotopic Analyses; American Chemical Society; Journal of Agricultural and Food Chemistry; 63; 18; 5-2015; 4638-4645
0021-8561
CONICET Digital
CONICET
url http://hdl.handle.net/11336/43308
identifier_str_mv Baroni, María Verónica; Podio, Natalia Soledad; Badini, Raúl G.; Inga, Marcela; Ostera, Hector Adolfo; et al.; Linking Soil, Water, and Honey Composition To Assess the Geographical Origin of Argentinean Honey by Multielemental and Isotopic Analyses; American Chemical Society; Journal of Agricultural and Food Chemistry; 63; 18; 5-2015; 4638-4645
0021-8561
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/jf5060112
info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/jf5060112
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.22299

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