Stannathianes as activated polythiols for the synthesis of functionalized macrocyclic polythiolactones

Autores
Delgado Espinosa, Zuly Yuliana; Erben, Mauricio Federico
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
We synthesized novel macrocyclic dithiolactones bearing endocyclic ether, polyether and lactone groups using new stannadithianes as tin templates in the condensation reaction with acid dichlorides and demonstrated an extension of this method toward synthesizing spirotetrathiolactones of controlled size. The structures of all synthesized compounds were characterized by spectroscopic methods.
Fil: Delgado Espinosa, Zuly Yuliana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica ; Argentina
Fil: Erben, Mauricio Federico. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica ; Argentina
Materia
Template Synthesis
Stannathiane
Macrocyclic Compounds
Thiolactone
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/48435
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/48435
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Stannathianes as activated polythiols for the synthesis of functionalized macrocyclic polythiolactonesDelgado Espinosa, Zuly YulianaErben, Mauricio FedericoTemplate SynthesisStannathianeMacrocyclic CompoundsThiolactonehttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1We synthesized novel macrocyclic dithiolactones bearing endocyclic ether, polyether and lactone groups using new stannadithianes as tin templates in the condensation reaction with acid dichlorides and demonstrated an extension of this method toward synthesizing spirotetrathiolactones of controlled size. The structures of all synthesized compounds were characterized by spectroscopic methods.Fil: Delgado Espinosa, Zuly Yuliana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica ; ArgentinaFil: Erben, Mauricio Federico. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica ; ArgentinaPergamon-Elsevier Science Ltd2017-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/48435Delgado Espinosa, Zuly Yuliana; Erben, Mauricio Federico; Stannathianes as activated polythiols for the synthesis of functionalized macrocyclic polythiolactones; Pergamon-Elsevier Science Ltd; Tetrahedron Letters; 58; 15; 4-2017; 1484-14860040-4039CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.tetlet.2017.02.086info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0040403917302757info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:44:39Zoai:ri.conicet.gov.ar:11336/48435instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:44:40.096CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Stannathianes as activated polythiols for the synthesis of functionalized macrocyclic polythiolactones
title Stannathianes as activated polythiols for the synthesis of functionalized macrocyclic polythiolactones
spellingShingle Stannathianes as activated polythiols for the synthesis of functionalized macrocyclic polythiolactones
Delgado Espinosa, Zuly Yuliana
Template Synthesis
Stannathiane
Macrocyclic Compounds
Thiolactone
title_short Stannathianes as activated polythiols for the synthesis of functionalized macrocyclic polythiolactones
title_full Stannathianes as activated polythiols for the synthesis of functionalized macrocyclic polythiolactones
title_fullStr Stannathianes as activated polythiols for the synthesis of functionalized macrocyclic polythiolactones
title_full_unstemmed Stannathianes as activated polythiols for the synthesis of functionalized macrocyclic polythiolactones
title_sort Stannathianes as activated polythiols for the synthesis of functionalized macrocyclic polythiolactones
dc.creator.none.fl_str_mv Delgado Espinosa, Zuly Yuliana
Erben, Mauricio Federico
author Delgado Espinosa, Zuly Yuliana
author_facet Delgado Espinosa, Zuly Yuliana
Erben, Mauricio Federico
author_role author
author2 Erben, Mauricio Federico
author2_role author
dc.subject.none.fl_str_mv Template Synthesis
Stannathiane
Macrocyclic Compounds
Thiolactone
topic Template Synthesis
Stannathiane
Macrocyclic Compounds
Thiolactone
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv We synthesized novel macrocyclic dithiolactones bearing endocyclic ether, polyether and lactone groups using new stannadithianes as tin templates in the condensation reaction with acid dichlorides and demonstrated an extension of this method toward synthesizing spirotetrathiolactones of controlled size. The structures of all synthesized compounds were characterized by spectroscopic methods.
Fil: Delgado Espinosa, Zuly Yuliana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica ; Argentina
Fil: Erben, Mauricio Federico. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica ; Argentina
description We synthesized novel macrocyclic dithiolactones bearing endocyclic ether, polyether and lactone groups using new stannadithianes as tin templates in the condensation reaction with acid dichlorides and demonstrated an extension of this method toward synthesizing spirotetrathiolactones of controlled size. The structures of all synthesized compounds were characterized by spectroscopic methods.
publishDate 2017
dc.date.none.fl_str_mv 2017-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/48435
Delgado Espinosa, Zuly Yuliana; Erben, Mauricio Federico; Stannathianes as activated polythiols for the synthesis of functionalized macrocyclic polythiolactones; Pergamon-Elsevier Science Ltd; Tetrahedron Letters; 58; 15; 4-2017; 1484-1486
0040-4039
CONICET Digital
CONICET
url http://hdl.handle.net/11336/48435
identifier_str_mv Delgado Espinosa, Zuly Yuliana; Erben, Mauricio Federico; Stannathianes as activated polythiols for the synthesis of functionalized macrocyclic polythiolactones; Pergamon-Elsevier Science Ltd; Tetrahedron Letters; 58; 15; 4-2017; 1484-1486
0040-4039
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.tetlet.2017.02.086
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0040403917302757
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844613405266149376
score 13.070432

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