Trace metal pyritization variability in response to mangrove soil aerobic and anaerobic oxidation processes

Autores
Machado, W.; Borrelli, Natalia Lorena; Ferreira, T. O.; Marques, A. G. B.; Osterrieth, Margarita Luisa; Guizan, C.
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The degree of iron pyritization (DOP) and degree of trace metal pyritization (DTMP) were evaluated in mangrove soil profiles from an estuarine area located in Rio de Janeiro (SE Brazil). The soil pH was negatively correlated with redox potential (Eh) and positively correlated with DOP and DTMP of some elements (Mn, Cu and Pb), suggesting that pyrite oxidation generated acidity and can affect the importance of pyrite as a trace metal-binding phase, mainly in response to spatial variability in tidal flooding. Besides these aerobic oxidation effects, results from a sequential extraction analyses of reactive phases evidenced that Mn oxidized phase consumption in reaction with pyrite can be also important to determine the pyritization of trace elements. Cumulative effects of these aerobic and anaerobic oxidation processes were evidenced as factors affecting the capacity of mangrove soils to act as a sink for trace metals through pyritization processes.
Fil: Machado, W.. Universidade Federal Fluminense; Brasil
Fil: Borrelli, Natalia Lorena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones Marinas y Costeras. Universidad Nacional de Mar del Plata. Facultad de Ciencia Exactas y Naturales. Instituto de Investigaciones Marinas y Costeras; Argentina. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Instituto de Geología de Costas y del Cuaternario. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Instituto de Geología de Costas y del Cuaternario; Argentina
Fil: Ferreira, T. O.. Universidade de Sao Paulo; Brasil
Fil: Marques, A. G. B.. Universidade de Sao Paulo; Brasil
Fil: Osterrieth, Margarita Luisa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones Marinas y Costeras. Universidad Nacional de Mar del Plata. Facultad de Ciencia Exactas y Naturales. Instituto de Investigaciones Marinas y Costeras; Argentina. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Instituto de Geología de Costas y del Cuaternario. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Instituto de Geología de Costas y del Cuaternario; Argentina
Fil: Guizan, C.. Universidade Federal Fluminense; Brasil
Materia
Metals
Pyritization
Sequential Extraction
Redox Processes
Pyrite Oxidation
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/34436
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/34436
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Trace metal pyritization variability in response to mangrove soil aerobic and anaerobic oxidation processesMachado, W.Borrelli, Natalia LorenaFerreira, T. O.Marques, A. G. B.Osterrieth, Margarita LuisaGuizan, C.MetalsPyritizationSequential ExtractionRedox ProcessesPyrite Oxidationhttps://purl.org/becyt/ford/1.5https://purl.org/becyt/ford/1The degree of iron pyritization (DOP) and degree of trace metal pyritization (DTMP) were evaluated in mangrove soil profiles from an estuarine area located in Rio de Janeiro (SE Brazil). The soil pH was negatively correlated with redox potential (Eh) and positively correlated with DOP and DTMP of some elements (Mn, Cu and Pb), suggesting that pyrite oxidation generated acidity and can affect the importance of pyrite as a trace metal-binding phase, mainly in response to spatial variability in tidal flooding. Besides these aerobic oxidation effects, results from a sequential extraction analyses of reactive phases evidenced that Mn oxidized phase consumption in reaction with pyrite can be also important to determine the pyritization of trace elements. Cumulative effects of these aerobic and anaerobic oxidation processes were evidenced as factors affecting the capacity of mangrove soils to act as a sink for trace metals through pyritization processes.Fil: Machado, W.. Universidade Federal Fluminense; BrasilFil: Borrelli, Natalia Lorena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones Marinas y Costeras. Universidad Nacional de Mar del Plata. Facultad de Ciencia Exactas y Naturales. Instituto de Investigaciones Marinas y Costeras; Argentina. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Instituto de Geología de Costas y del Cuaternario. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Instituto de Geología de Costas y del Cuaternario; ArgentinaFil: Ferreira, T. O.. Universidade de Sao Paulo; BrasilFil: Marques, A. G. B.. Universidade de Sao Paulo; BrasilFil: Osterrieth, Margarita Luisa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones Marinas y Costeras. Universidad Nacional de Mar del Plata. Facultad de Ciencia Exactas y Naturales. Instituto de Investigaciones Marinas y Costeras; Argentina. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Instituto de Geología de Costas y del Cuaternario. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Instituto de Geología de Costas y del Cuaternario; ArgentinaFil: Guizan, C.. Universidade Federal Fluminense; BrasilPergamon-Elsevier Science Ltd.2014-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/34436Machado, W.; Borrelli, Natalia Lorena; Ferreira, T. O.; Marques, A. G. B.; Osterrieth, Margarita Luisa; et al.; Trace metal pyritization variability in response to mangrove soil aerobic and anaerobic oxidation processes; Pergamon-Elsevier Science Ltd.; Marine Pollution Bulletin; 79; 1-2; 1-2014; 365-3700025-326XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.marpolbul.2013.11.016info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0025326X13007170info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:18:51Zoai:ri.conicet.gov.ar:11336/34436instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:18:51.5CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Trace metal pyritization variability in response to mangrove soil aerobic and anaerobic oxidation processes
title Trace metal pyritization variability in response to mangrove soil aerobic and anaerobic oxidation processes
spellingShingle Trace metal pyritization variability in response to mangrove soil aerobic and anaerobic oxidation processes
Machado, W.
Metals
Pyritization
Sequential Extraction
Redox Processes
Pyrite Oxidation
title_short Trace metal pyritization variability in response to mangrove soil aerobic and anaerobic oxidation processes
title_full Trace metal pyritization variability in response to mangrove soil aerobic and anaerobic oxidation processes
title_fullStr Trace metal pyritization variability in response to mangrove soil aerobic and anaerobic oxidation processes
title_full_unstemmed Trace metal pyritization variability in response to mangrove soil aerobic and anaerobic oxidation processes
title_sort Trace metal pyritization variability in response to mangrove soil aerobic and anaerobic oxidation processes
dc.creator.none.fl_str_mv Machado, W.
Borrelli, Natalia Lorena
Ferreira, T. O.
Marques, A. G. B.
Osterrieth, Margarita Luisa
Guizan, C.
author Machado, W.
author_facet Machado, W.
Borrelli, Natalia Lorena
Ferreira, T. O.
Marques, A. G. B.
Osterrieth, Margarita Luisa
Guizan, C.
author_role author
author2 Borrelli, Natalia Lorena
Ferreira, T. O.
Marques, A. G. B.
Osterrieth, Margarita Luisa
Guizan, C.
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Metals
Pyritization
Sequential Extraction
Redox Processes
Pyrite Oxidation
topic Metals
Pyritization
Sequential Extraction
Redox Processes
Pyrite Oxidation
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.5
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The degree of iron pyritization (DOP) and degree of trace metal pyritization (DTMP) were evaluated in mangrove soil profiles from an estuarine area located in Rio de Janeiro (SE Brazil). The soil pH was negatively correlated with redox potential (Eh) and positively correlated with DOP and DTMP of some elements (Mn, Cu and Pb), suggesting that pyrite oxidation generated acidity and can affect the importance of pyrite as a trace metal-binding phase, mainly in response to spatial variability in tidal flooding. Besides these aerobic oxidation effects, results from a sequential extraction analyses of reactive phases evidenced that Mn oxidized phase consumption in reaction with pyrite can be also important to determine the pyritization of trace elements. Cumulative effects of these aerobic and anaerobic oxidation processes were evidenced as factors affecting the capacity of mangrove soils to act as a sink for trace metals through pyritization processes.
Fil: Machado, W.. Universidade Federal Fluminense; Brasil
Fil: Borrelli, Natalia Lorena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones Marinas y Costeras. Universidad Nacional de Mar del Plata. Facultad de Ciencia Exactas y Naturales. Instituto de Investigaciones Marinas y Costeras; Argentina. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Instituto de Geología de Costas y del Cuaternario. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Instituto de Geología de Costas y del Cuaternario; Argentina
Fil: Ferreira, T. O.. Universidade de Sao Paulo; Brasil
Fil: Marques, A. G. B.. Universidade de Sao Paulo; Brasil
Fil: Osterrieth, Margarita Luisa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones Marinas y Costeras. Universidad Nacional de Mar del Plata. Facultad de Ciencia Exactas y Naturales. Instituto de Investigaciones Marinas y Costeras; Argentina. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Instituto de Geología de Costas y del Cuaternario. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Instituto de Geología de Costas y del Cuaternario; Argentina
Fil: Guizan, C.. Universidade Federal Fluminense; Brasil
description The degree of iron pyritization (DOP) and degree of trace metal pyritization (DTMP) were evaluated in mangrove soil profiles from an estuarine area located in Rio de Janeiro (SE Brazil). The soil pH was negatively correlated with redox potential (Eh) and positively correlated with DOP and DTMP of some elements (Mn, Cu and Pb), suggesting that pyrite oxidation generated acidity and can affect the importance of pyrite as a trace metal-binding phase, mainly in response to spatial variability in tidal flooding. Besides these aerobic oxidation effects, results from a sequential extraction analyses of reactive phases evidenced that Mn oxidized phase consumption in reaction with pyrite can be also important to determine the pyritization of trace elements. Cumulative effects of these aerobic and anaerobic oxidation processes were evidenced as factors affecting the capacity of mangrove soils to act as a sink for trace metals through pyritization processes.
publishDate 2014
dc.date.none.fl_str_mv 2014-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/34436
Machado, W.; Borrelli, Natalia Lorena; Ferreira, T. O.; Marques, A. G. B.; Osterrieth, Margarita Luisa; et al.; Trace metal pyritization variability in response to mangrove soil aerobic and anaerobic oxidation processes; Pergamon-Elsevier Science Ltd.; Marine Pollution Bulletin; 79; 1-2; 1-2014; 365-370
0025-326X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/34436
identifier_str_mv Machado, W.; Borrelli, Natalia Lorena; Ferreira, T. O.; Marques, A. G. B.; Osterrieth, Margarita Luisa; et al.; Trace metal pyritization variability in response to mangrove soil aerobic and anaerobic oxidation processes; Pergamon-Elsevier Science Ltd.; Marine Pollution Bulletin; 79; 1-2; 1-2014; 365-370
0025-326X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.marpolbul.2013.11.016
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0025326X13007170
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd.
publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd.
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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