Hydrogeochemistry of trace and rare earth elements in the Caviahue-Copahue Volcanic Complex

Autores
Llano, Joaquin; Calabrese, Sergio; Lamberti, María Clara Isabel; Li Vigni, Lorenza; Brugnone, Filippo; Sierra, Daniela; García, Sebastián; Carbajal, Fabricio Joaquin; Brusca, Lorenzo; D'alessandro, Walter; Agusto, Mariano Roberto
Año de publicación
2023
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The Caviahue-Copahue Volcanic Complex is one of the most studied active volcanic systems in the South American Andean range, and yet little research has focused on trace and rare-earth elements of waters, especially during an eruptive cycle. In this study, we sampled and investigated natural waters from 23 sites (involving the crater lake, hot springs, streams, rivers, and bubbling pools) in two campaigns in 2017 and 2018, using physicochemical parameters, major, trace and rare-earth elements concentrations. With this novel dataset, it was possible to identify, characterize and compare three groups of waters with distinctive hydrofacies. Indeed, the normalization of water compositions against host rock concentrations showed a particular trace element pattern for each group of waters. Although the absolute concentrations of the elements in each sampling site changed from 2017 to 2018, the normalized patterns did not. Boron, As, Cd, Tl, Se, and Te, commonly recognized as volatile, are the main trace elements that magmatic gases supply to the system headwaters, whereas elements such as Ca, K, and Ba are affected by precipitation of secondary minerals (gypsum, anhydrite, barite, jarosite, and alunite). Furthermore, the main river draining the summit volcano shows a steep decrease in As, Cr, and V concentrations correlated to the precipitation of Fe and Al hydroxysulfates (schwertmannite and basaluminite, respectively). Moreover, it is the first time that a comparison between the different water groups is made using the patterns of the rare-earth elements, allowing us to identify and separate depletion patterns due to dilution processes from those due to precipitation processes.
Fil: Llano, Joaquin. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Estudios Andinos "Don Pablo Groeber". Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Estudios Andinos "Don Pablo Groeber"; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Ciencias Geológicas. Grupo de Estudio y Seguimiento de Volcanes Activos; Argentina
Fil: Calabrese, Sergio. Istituto Nazionale di Geofisica e Vulcanologia; Italia
Fil: Lamberti, María Clara Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Estudios Andinos "Don Pablo Groeber". Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Estudios Andinos "Don Pablo Groeber"; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Ciencias Geológicas. Grupo de Estudio y Seguimiento de Volcanes Activos; Argentina
Fil: Li Vigni, Lorenza. Università degli Studi di Palermo; Italia
Fil: Brugnone, Filippo. Università degli Studi di Palermo; Italia
Fil: Sierra, Daniela. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Estudios Andinos "Don Pablo Groeber". Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Estudios Andinos "Don Pablo Groeber"; Argentina
Fil: García, Sebastián. Secretaría de Industria y Minería. Servicio Geológico Minero Argentino; Argentina
Fil: Carbajal, Fabricio Joaquin. Secretaría de Industria y Minería. Servicio Geológico Minero Argentino; Argentina
Fil: Brusca, Lorenzo. Istituto Nazionale di Geofisica e Vulcanologia; Italia
Fil: D'alessandro, Walter. Istituto Nazionale di Geofisica e Vulcanologia; Italia
Fil: Agusto, Mariano Roberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Estudios Andinos "Don Pablo Groeber". Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Estudios Andinos "Don Pablo Groeber"; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Ciencias Geológicas. Grupo de Estudio y Seguimiento de Volcanes Activos; Argentina
Materia
COPAHUE VOLCANO
GEOTHERMAL
HYDROLOGICAL SYSTEM
RARE-EARTH ELEMENTS
TRACE ELEMENTS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/226704
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/226704
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Hydrogeochemistry of trace and rare earth elements in the Caviahue-Copahue Volcanic ComplexLlano, JoaquinCalabrese, SergioLamberti, María Clara IsabelLi Vigni, LorenzaBrugnone, FilippoSierra, DanielaGarcía, SebastiánCarbajal, Fabricio JoaquinBrusca, LorenzoD'alessandro, WalterAgusto, Mariano RobertoCOPAHUE VOLCANOGEOTHERMALHYDROLOGICAL SYSTEMRARE-EARTH ELEMENTSTRACE ELEMENTShttps://purl.org/becyt/ford/1.5https://purl.org/becyt/ford/1The Caviahue-Copahue Volcanic Complex is one of the most studied active volcanic systems in the South American Andean range, and yet little research has focused on trace and rare-earth elements of waters, especially during an eruptive cycle. In this study, we sampled and investigated natural waters from 23 sites (involving the crater lake, hot springs, streams, rivers, and bubbling pools) in two campaigns in 2017 and 2018, using physicochemical parameters, major, trace and rare-earth elements concentrations. With this novel dataset, it was possible to identify, characterize and compare three groups of waters with distinctive hydrofacies. Indeed, the normalization of water compositions against host rock concentrations showed a particular trace element pattern for each group of waters. Although the absolute concentrations of the elements in each sampling site changed from 2017 to 2018, the normalized patterns did not. Boron, As, Cd, Tl, Se, and Te, commonly recognized as volatile, are the main trace elements that magmatic gases supply to the system headwaters, whereas elements such as Ca, K, and Ba are affected by precipitation of secondary minerals (gypsum, anhydrite, barite, jarosite, and alunite). Furthermore, the main river draining the summit volcano shows a steep decrease in As, Cr, and V concentrations correlated to the precipitation of Fe and Al hydroxysulfates (schwertmannite and basaluminite, respectively). Moreover, it is the first time that a comparison between the different water groups is made using the patterns of the rare-earth elements, allowing us to identify and separate depletion patterns due to dilution processes from those due to precipitation processes.Fil: Llano, Joaquin. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Estudios Andinos "Don Pablo Groeber". Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Estudios Andinos "Don Pablo Groeber"; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Ciencias Geológicas. Grupo de Estudio y Seguimiento de Volcanes Activos; ArgentinaFil: Calabrese, Sergio. Istituto Nazionale di Geofisica e Vulcanologia; ItaliaFil: Lamberti, María Clara Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Estudios Andinos "Don Pablo Groeber". Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Estudios Andinos "Don Pablo Groeber"; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Ciencias Geológicas. Grupo de Estudio y Seguimiento de Volcanes Activos; ArgentinaFil: Li Vigni, Lorenza. Università degli Studi di Palermo; ItaliaFil: Brugnone, Filippo. Università degli Studi di Palermo; ItaliaFil: Sierra, Daniela. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Estudios Andinos "Don Pablo Groeber". Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Estudios Andinos "Don Pablo Groeber"; ArgentinaFil: García, Sebastián. Secretaría de Industria y Minería. Servicio Geológico Minero Argentino; ArgentinaFil: Carbajal, Fabricio Joaquin. Secretaría de Industria y Minería. Servicio Geológico Minero Argentino; ArgentinaFil: Brusca, Lorenzo. Istituto Nazionale di Geofisica e Vulcanologia; ItaliaFil: D'alessandro, Walter. Istituto Nazionale di Geofisica e Vulcanologia; ItaliaFil: Agusto, Mariano Roberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Estudios Andinos "Don Pablo Groeber". Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Estudios Andinos "Don Pablo Groeber"; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Ciencias Geológicas. Grupo de Estudio y Seguimiento de Volcanes Activos; ArgentinaElsevier Science2023-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/226704Llano, Joaquin; Calabrese, Sergio; Lamberti, María Clara Isabel; Li Vigni, Lorenza; Brugnone, Filippo; et al.; Hydrogeochemistry of trace and rare earth elements in the Caviahue-Copahue Volcanic Complex; Elsevier Science; Chemical Geology; 634; 9-2023; 1-520009-2541CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S0009254123003029info:eu-repo/semantics/altIdentifier/doi/10.1016/j.chemgeo.2023.121602info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-10T13:11:47Zoai:ri.conicet.gov.ar:11336/226704instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-10 13:11:47.629CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Hydrogeochemistry of trace and rare earth elements in the Caviahue-Copahue Volcanic Complex
title Hydrogeochemistry of trace and rare earth elements in the Caviahue-Copahue Volcanic Complex
spellingShingle Hydrogeochemistry of trace and rare earth elements in the Caviahue-Copahue Volcanic Complex
Llano, Joaquin
COPAHUE VOLCANO
GEOTHERMAL
HYDROLOGICAL SYSTEM
RARE-EARTH ELEMENTS
TRACE ELEMENTS
title_short Hydrogeochemistry of trace and rare earth elements in the Caviahue-Copahue Volcanic Complex
title_full Hydrogeochemistry of trace and rare earth elements in the Caviahue-Copahue Volcanic Complex
title_fullStr Hydrogeochemistry of trace and rare earth elements in the Caviahue-Copahue Volcanic Complex
title_full_unstemmed Hydrogeochemistry of trace and rare earth elements in the Caviahue-Copahue Volcanic Complex
title_sort Hydrogeochemistry of trace and rare earth elements in the Caviahue-Copahue Volcanic Complex
dc.creator.none.fl_str_mv Llano, Joaquin
Calabrese, Sergio
Lamberti, María Clara Isabel
Li Vigni, Lorenza
Brugnone, Filippo
Sierra, Daniela
García, Sebastián
Carbajal, Fabricio Joaquin
Brusca, Lorenzo
D'alessandro, Walter
Agusto, Mariano Roberto
author Llano, Joaquin
author_facet Llano, Joaquin
Calabrese, Sergio
Lamberti, María Clara Isabel
Li Vigni, Lorenza
Brugnone, Filippo
Sierra, Daniela
García, Sebastián
Carbajal, Fabricio Joaquin
Brusca, Lorenzo
D'alessandro, Walter
Agusto, Mariano Roberto
author_role author
author2 Calabrese, Sergio
Lamberti, María Clara Isabel
Li Vigni, Lorenza
Brugnone, Filippo
Sierra, Daniela
García, Sebastián
Carbajal, Fabricio Joaquin
Brusca, Lorenzo
D'alessandro, Walter
Agusto, Mariano Roberto
author2_role author
author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv COPAHUE VOLCANO
GEOTHERMAL
HYDROLOGICAL SYSTEM
RARE-EARTH ELEMENTS
TRACE ELEMENTS
topic COPAHUE VOLCANO
GEOTHERMAL
HYDROLOGICAL SYSTEM
RARE-EARTH ELEMENTS
TRACE ELEMENTS
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.5
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The Caviahue-Copahue Volcanic Complex is one of the most studied active volcanic systems in the South American Andean range, and yet little research has focused on trace and rare-earth elements of waters, especially during an eruptive cycle. In this study, we sampled and investigated natural waters from 23 sites (involving the crater lake, hot springs, streams, rivers, and bubbling pools) in two campaigns in 2017 and 2018, using physicochemical parameters, major, trace and rare-earth elements concentrations. With this novel dataset, it was possible to identify, characterize and compare three groups of waters with distinctive hydrofacies. Indeed, the normalization of water compositions against host rock concentrations showed a particular trace element pattern for each group of waters. Although the absolute concentrations of the elements in each sampling site changed from 2017 to 2018, the normalized patterns did not. Boron, As, Cd, Tl, Se, and Te, commonly recognized as volatile, are the main trace elements that magmatic gases supply to the system headwaters, whereas elements such as Ca, K, and Ba are affected by precipitation of secondary minerals (gypsum, anhydrite, barite, jarosite, and alunite). Furthermore, the main river draining the summit volcano shows a steep decrease in As, Cr, and V concentrations correlated to the precipitation of Fe and Al hydroxysulfates (schwertmannite and basaluminite, respectively). Moreover, it is the first time that a comparison between the different water groups is made using the patterns of the rare-earth elements, allowing us to identify and separate depletion patterns due to dilution processes from those due to precipitation processes.
Fil: Llano, Joaquin. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Estudios Andinos "Don Pablo Groeber". Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Estudios Andinos "Don Pablo Groeber"; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Ciencias Geológicas. Grupo de Estudio y Seguimiento de Volcanes Activos; Argentina
Fil: Calabrese, Sergio. Istituto Nazionale di Geofisica e Vulcanologia; Italia
Fil: Lamberti, María Clara Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Estudios Andinos "Don Pablo Groeber". Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Estudios Andinos "Don Pablo Groeber"; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Ciencias Geológicas. Grupo de Estudio y Seguimiento de Volcanes Activos; Argentina
Fil: Li Vigni, Lorenza. Università degli Studi di Palermo; Italia
Fil: Brugnone, Filippo. Università degli Studi di Palermo; Italia
Fil: Sierra, Daniela. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Estudios Andinos "Don Pablo Groeber". Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Estudios Andinos "Don Pablo Groeber"; Argentina
Fil: García, Sebastián. Secretaría de Industria y Minería. Servicio Geológico Minero Argentino; Argentina
Fil: Carbajal, Fabricio Joaquin. Secretaría de Industria y Minería. Servicio Geológico Minero Argentino; Argentina
Fil: Brusca, Lorenzo. Istituto Nazionale di Geofisica e Vulcanologia; Italia
Fil: D'alessandro, Walter. Istituto Nazionale di Geofisica e Vulcanologia; Italia
Fil: Agusto, Mariano Roberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Estudios Andinos "Don Pablo Groeber". Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Estudios Andinos "Don Pablo Groeber"; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Ciencias Geológicas. Grupo de Estudio y Seguimiento de Volcanes Activos; Argentina
description The Caviahue-Copahue Volcanic Complex is one of the most studied active volcanic systems in the South American Andean range, and yet little research has focused on trace and rare-earth elements of waters, especially during an eruptive cycle. In this study, we sampled and investigated natural waters from 23 sites (involving the crater lake, hot springs, streams, rivers, and bubbling pools) in two campaigns in 2017 and 2018, using physicochemical parameters, major, trace and rare-earth elements concentrations. With this novel dataset, it was possible to identify, characterize and compare three groups of waters with distinctive hydrofacies. Indeed, the normalization of water compositions against host rock concentrations showed a particular trace element pattern for each group of waters. Although the absolute concentrations of the elements in each sampling site changed from 2017 to 2018, the normalized patterns did not. Boron, As, Cd, Tl, Se, and Te, commonly recognized as volatile, are the main trace elements that magmatic gases supply to the system headwaters, whereas elements such as Ca, K, and Ba are affected by precipitation of secondary minerals (gypsum, anhydrite, barite, jarosite, and alunite). Furthermore, the main river draining the summit volcano shows a steep decrease in As, Cr, and V concentrations correlated to the precipitation of Fe and Al hydroxysulfates (schwertmannite and basaluminite, respectively). Moreover, it is the first time that a comparison between the different water groups is made using the patterns of the rare-earth elements, allowing us to identify and separate depletion patterns due to dilution processes from those due to precipitation processes.
publishDate 2023
dc.date.none.fl_str_mv 2023-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/226704
Llano, Joaquin; Calabrese, Sergio; Lamberti, María Clara Isabel; Li Vigni, Lorenza; Brugnone, Filippo; et al.; Hydrogeochemistry of trace and rare earth elements in the Caviahue-Copahue Volcanic Complex; Elsevier Science; Chemical Geology; 634; 9-2023; 1-52
0009-2541
CONICET Digital
CONICET
url http://hdl.handle.net/11336/226704
identifier_str_mv Llano, Joaquin; Calabrese, Sergio; Lamberti, María Clara Isabel; Li Vigni, Lorenza; Brugnone, Filippo; et al.; Hydrogeochemistry of trace and rare earth elements in the Caviahue-Copahue Volcanic Complex; Elsevier Science; Chemical Geology; 634; 9-2023; 1-52
0009-2541
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S0009254123003029
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.chemgeo.2023.121602
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
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eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
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reponame_str CONICET Digital (CONICET)
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instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
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repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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