Co oxidation: effect of Ce and Au addition on MnOx catalysts
- Autores
- Peluso, Miguel Andrés; Hernández Enciso, W. Y.; Dominguez, M. I.; Thomas, Horacio Jorge; Centeno, M. A.; Sambeth, Jorge Enrique
- Año de publicación
- 2012
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The effect of cerium and/or gold addition to a manganese oxide which was greatly active in CO oxidation was studied. The catalysts obtained by this way were characterized by N2 adsorption, XRF, XRD and TPR, and their catalytic activity was measured in the CO oxidation reaction. The pure MnOx catalyst was active in the CO oxidation but the addition of 5 wt % cerium decreased their catalytic activity. Adding 2 wt % gold improved the activity of MnOx and Ce/MnOx and caused a slight decrease of the catalyst specific area and of the average oxidation state of manganese in catalysts, which was found between 3.3 and 3.6. The order of activity found on the basis of T50 for the four catalysts was: Au/MnOx > Au/Ce/MnOx > MnOx > Ce/MnOx, with T50 of 89, 95, 99 and 139 °C, respectively. The solids Au/MnOx and Au/Ce/MnOx presented a T10 of 30 and 49 °C, indicating that gold favored the conversion at room temperature. The effect of water vapor on the reaction was also analyzed, finding a decrease in the catalytic activity of all catalysts, due to the blocking of active sites in the catalyst surface.
Fil: Peluso, Miguel Andrés. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Fil: Hernández Enciso, W. Y.. Universidad de Sevilla. Consejo Superior de Investigaciones Cientificas. Instituto de Ciencia de Materiales de Sevilla; España
Fil: Dominguez, M. I.. Universidad de Sevilla. Consejo Superior de Investigaciones Cientificas. Instituto de Ienia de Materiales de Sevilla; España
Fil: Thomas, Horacio Jorge. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Fil: Centeno, M. A.. Universidad de Sevilla. Consejo Superior de Investigaciones Cientificas. Instituto de Ciencia de Materiales de Sevilla; España
Fil: Sambeth, Jorge Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina - Materia
-
Co Oxidation
Mnox
Cemnox
Au - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/5870
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Co oxidation: effect of Ce and Au addition on MnOx catalystsPeluso, Miguel AndrésHernández Enciso, W. Y.Dominguez, M. I.Thomas, Horacio JorgeCenteno, M. A.Sambeth, Jorge EnriqueCo OxidationMnoxCemnoxAuhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The effect of cerium and/or gold addition to a manganese oxide which was greatly active in CO oxidation was studied. The catalysts obtained by this way were characterized by N2 adsorption, XRF, XRD and TPR, and their catalytic activity was measured in the CO oxidation reaction. The pure MnOx catalyst was active in the CO oxidation but the addition of 5 wt % cerium decreased their catalytic activity. Adding 2 wt % gold improved the activity of MnOx and Ce/MnOx and caused a slight decrease of the catalyst specific area and of the average oxidation state of manganese in catalysts, which was found between 3.3 and 3.6. The order of activity found on the basis of T50 for the four catalysts was: Au/MnOx > Au/Ce/MnOx > MnOx > Ce/MnOx, with T50 of 89, 95, 99 and 139 °C, respectively. The solids Au/MnOx and Au/Ce/MnOx presented a T10 of 30 and 49 °C, indicating that gold favored the conversion at room temperature. The effect of water vapor on the reaction was also analyzed, finding a decrease in the catalytic activity of all catalysts, due to the blocking of active sites in the catalyst surface.Fil: Peluso, Miguel Andrés. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; ArgentinaFil: Hernández Enciso, W. Y.. Universidad de Sevilla. Consejo Superior de Investigaciones Cientificas. Instituto de Ciencia de Materiales de Sevilla; EspañaFil: Dominguez, M. I.. Universidad de Sevilla. Consejo Superior de Investigaciones Cientificas. Instituto de Ienia de Materiales de Sevilla; EspañaFil: Thomas, Horacio Jorge. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; ArgentinaFil: Centeno, M. A.. Universidad de Sevilla. Consejo Superior de Investigaciones Cientificas. Instituto de Ciencia de Materiales de Sevilla; EspañaFil: Sambeth, Jorge Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; ArgentinaPlanta Piloto de Ingeniería Química2012-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/5870Peluso, Miguel Andrés; Hernández Enciso, W. Y.; Dominguez, M. I.; Thomas, Horacio Jorge; Centeno, M. A.; et al.; Co oxidation: effect of Ce and Au addition on MnOx catalysts; Planta Piloto de Ingeniería Química; Latin American Applied Research; 42; 4; 10-2012; 351-3580327-07931851-8796enginfo:eu-repo/semantics/altIdentifier/url/http://www.laar.uns.edu.ar/indexes/artic_v4204/Vol42_04_351.pdfinfo:eu-repo/semantics/altIdentifier/url/http://ref.scielo.org/g66v8binfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:06:56Zoai:ri.conicet.gov.ar:11336/5870instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:06:56.985CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Co oxidation: effect of Ce and Au addition on MnOx catalysts |
title |
Co oxidation: effect of Ce and Au addition on MnOx catalysts |
spellingShingle |
Co oxidation: effect of Ce and Au addition on MnOx catalysts Peluso, Miguel Andrés Co Oxidation Mnox Cemnox Au |
title_short |
Co oxidation: effect of Ce and Au addition on MnOx catalysts |
title_full |
Co oxidation: effect of Ce and Au addition on MnOx catalysts |
title_fullStr |
Co oxidation: effect of Ce and Au addition on MnOx catalysts |
title_full_unstemmed |
Co oxidation: effect of Ce and Au addition on MnOx catalysts |
title_sort |
Co oxidation: effect of Ce and Au addition on MnOx catalysts |
dc.creator.none.fl_str_mv |
Peluso, Miguel Andrés Hernández Enciso, W. Y. Dominguez, M. I. Thomas, Horacio Jorge Centeno, M. A. Sambeth, Jorge Enrique |
author |
Peluso, Miguel Andrés |
author_facet |
Peluso, Miguel Andrés Hernández Enciso, W. Y. Dominguez, M. I. Thomas, Horacio Jorge Centeno, M. A. Sambeth, Jorge Enrique |
author_role |
author |
author2 |
Hernández Enciso, W. Y. Dominguez, M. I. Thomas, Horacio Jorge Centeno, M. A. Sambeth, Jorge Enrique |
author2_role |
author author author author author |
dc.subject.none.fl_str_mv |
Co Oxidation Mnox Cemnox Au |
topic |
Co Oxidation Mnox Cemnox Au |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
The effect of cerium and/or gold addition to a manganese oxide which was greatly active in CO oxidation was studied. The catalysts obtained by this way were characterized by N2 adsorption, XRF, XRD and TPR, and their catalytic activity was measured in the CO oxidation reaction. The pure MnOx catalyst was active in the CO oxidation but the addition of 5 wt % cerium decreased their catalytic activity. Adding 2 wt % gold improved the activity of MnOx and Ce/MnOx and caused a slight decrease of the catalyst specific area and of the average oxidation state of manganese in catalysts, which was found between 3.3 and 3.6. The order of activity found on the basis of T50 for the four catalysts was: Au/MnOx > Au/Ce/MnOx > MnOx > Ce/MnOx, with T50 of 89, 95, 99 and 139 °C, respectively. The solids Au/MnOx and Au/Ce/MnOx presented a T10 of 30 and 49 °C, indicating that gold favored the conversion at room temperature. The effect of water vapor on the reaction was also analyzed, finding a decrease in the catalytic activity of all catalysts, due to the blocking of active sites in the catalyst surface. Fil: Peluso, Miguel Andrés. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina Fil: Hernández Enciso, W. Y.. Universidad de Sevilla. Consejo Superior de Investigaciones Cientificas. Instituto de Ciencia de Materiales de Sevilla; España Fil: Dominguez, M. I.. Universidad de Sevilla. Consejo Superior de Investigaciones Cientificas. Instituto de Ienia de Materiales de Sevilla; España Fil: Thomas, Horacio Jorge. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina Fil: Centeno, M. A.. Universidad de Sevilla. Consejo Superior de Investigaciones Cientificas. Instituto de Ciencia de Materiales de Sevilla; España Fil: Sambeth, Jorge Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina |
description |
The effect of cerium and/or gold addition to a manganese oxide which was greatly active in CO oxidation was studied. The catalysts obtained by this way were characterized by N2 adsorption, XRF, XRD and TPR, and their catalytic activity was measured in the CO oxidation reaction. The pure MnOx catalyst was active in the CO oxidation but the addition of 5 wt % cerium decreased their catalytic activity. Adding 2 wt % gold improved the activity of MnOx and Ce/MnOx and caused a slight decrease of the catalyst specific area and of the average oxidation state of manganese in catalysts, which was found between 3.3 and 3.6. The order of activity found on the basis of T50 for the four catalysts was: Au/MnOx > Au/Ce/MnOx > MnOx > Ce/MnOx, with T50 of 89, 95, 99 and 139 °C, respectively. The solids Au/MnOx and Au/Ce/MnOx presented a T10 of 30 and 49 °C, indicating that gold favored the conversion at room temperature. The effect of water vapor on the reaction was also analyzed, finding a decrease in the catalytic activity of all catalysts, due to the blocking of active sites in the catalyst surface. |
publishDate |
2012 |
dc.date.none.fl_str_mv |
2012-10 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/5870 Peluso, Miguel Andrés; Hernández Enciso, W. Y.; Dominguez, M. I.; Thomas, Horacio Jorge; Centeno, M. A.; et al.; Co oxidation: effect of Ce and Au addition on MnOx catalysts; Planta Piloto de Ingeniería Química; Latin American Applied Research; 42; 4; 10-2012; 351-358 0327-0793 1851-8796 |
url |
http://hdl.handle.net/11336/5870 |
identifier_str_mv |
Peluso, Miguel Andrés; Hernández Enciso, W. Y.; Dominguez, M. I.; Thomas, Horacio Jorge; Centeno, M. A.; et al.; Co oxidation: effect of Ce and Au addition on MnOx catalysts; Planta Piloto de Ingeniería Química; Latin American Applied Research; 42; 4; 10-2012; 351-358 0327-0793 1851-8796 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/http://www.laar.uns.edu.ar/indexes/artic_v4204/Vol42_04_351.pdf info:eu-repo/semantics/altIdentifier/url/http://ref.scielo.org/g66v8b |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Planta Piloto de Ingeniería Química |
publisher.none.fl_str_mv |
Planta Piloto de Ingeniería Química |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1842269982084300800 |
score |
13.13397 |