First example of a preferred anti configuration in RN=SX2 compounds: N-fluoroformyliminotrifluoromethylsulfur fluoride, FC(O)N=S(F)CF3

Autores
Romano, Rosana Mariel; Della Védova, Carlos Omar; Mora Valdez, M. I.; Cutin, Edgardo Hugo
Año de publicación
2000
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The vibrational spectra, including Raman spectra at different temperatures and resonance Raman spectra, and theoretical calculations of N‐fluoroformyliminotrifluoromethylsulfur fluoride, FC(O)N= S(F)CF3, were obtained and interpreted. They point to the existence of a predominant anti–syn form and in equilibrium at lower concentration a syn–syn form (the first related to the nitrogen lone pair with respect to the sulfur lone pair and the second is related to the C= O double bond with respect to the N= S double bond). The general result indicates that it is the first anti configuration reported for this type of molecule implying for the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms.
Fil: Romano, Rosana Mariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica ; Argentina
Fil: Della Védova, Carlos Omar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica ; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Servicios a la Industria y al Sistema Científico; Argentina
Fil: Mora Valdez, M. I.. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química Física; Argentina
Fil: Cutin, Edgardo Hugo. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química Física; Argentina
Materia
Raman Spectra
Temperature
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/53263
Acceder
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network_name_str CONICET Digital (CONICET)
spelling First example of a preferred anti configuration in RN=SX2 compounds: N-fluoroformyliminotrifluoromethylsulfur fluoride, FC(O)N=S(F)CF3Romano, Rosana MarielDella Védova, Carlos OmarMora Valdez, M. I.Cutin, Edgardo HugoRaman SpectraTemperaturehttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The vibrational spectra, including Raman spectra at different temperatures and resonance Raman spectra, and theoretical calculations of N‐fluoroformyliminotrifluoromethylsulfur fluoride, FC(O)N= S(F)CF3, were obtained and interpreted. They point to the existence of a predominant anti–syn form and in equilibrium at lower concentration a syn–syn form (the first related to the nitrogen lone pair with respect to the sulfur lone pair and the second is related to the C= O double bond with respect to the N= S double bond). The general result indicates that it is the first anti configuration reported for this type of molecule implying for the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms.Fil: Romano, Rosana Mariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica ; ArgentinaFil: Della Védova, Carlos Omar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica ; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Servicios a la Industria y al Sistema Científico; ArgentinaFil: Mora Valdez, M. I.. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química Física; ArgentinaFil: Cutin, Edgardo Hugo. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química Física; ArgentinaJohn Wiley & Sons Ltd2000-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/53263Romano, Rosana Mariel; Della Védova, Carlos Omar; Mora Valdez, M. I.; Cutin, Edgardo Hugo; First example of a preferred anti configuration in RN=SX2 compounds: N-fluoroformyliminotrifluoromethylsulfur fluoride, FC(O)N=S(F)CF3; John Wiley & Sons Ltd; Journal Of Raman Spectroscopy; 31; 10; 10-2000; 881-8850377-0486CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1002/1097-4555(200010)31:10%3C881::AID-JRS588%3E3.0.CO;2-Tinfo:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/1097-4555%28200010%2931%3A10%3C881%3A%3AAID-JRS588%3E3.0.CO%3B2-Tinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:33:28Zoai:ri.conicet.gov.ar:11336/53263instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:33:29.128CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv First example of a preferred anti configuration in RN=SX2 compounds: N-fluoroformyliminotrifluoromethylsulfur fluoride, FC(O)N=S(F)CF3
title First example of a preferred anti configuration in RN=SX2 compounds: N-fluoroformyliminotrifluoromethylsulfur fluoride, FC(O)N=S(F)CF3
spellingShingle First example of a preferred anti configuration in RN=SX2 compounds: N-fluoroformyliminotrifluoromethylsulfur fluoride, FC(O)N=S(F)CF3
Romano, Rosana Mariel
Raman Spectra
Temperature
title_short First example of a preferred anti configuration in RN=SX2 compounds: N-fluoroformyliminotrifluoromethylsulfur fluoride, FC(O)N=S(F)CF3
title_full First example of a preferred anti configuration in RN=SX2 compounds: N-fluoroformyliminotrifluoromethylsulfur fluoride, FC(O)N=S(F)CF3
title_fullStr First example of a preferred anti configuration in RN=SX2 compounds: N-fluoroformyliminotrifluoromethylsulfur fluoride, FC(O)N=S(F)CF3
title_full_unstemmed First example of a preferred anti configuration in RN=SX2 compounds: N-fluoroformyliminotrifluoromethylsulfur fluoride, FC(O)N=S(F)CF3
title_sort First example of a preferred anti configuration in RN=SX2 compounds: N-fluoroformyliminotrifluoromethylsulfur fluoride, FC(O)N=S(F)CF3
dc.creator.none.fl_str_mv Romano, Rosana Mariel
Della Védova, Carlos Omar
Mora Valdez, M. I.
Cutin, Edgardo Hugo
author Romano, Rosana Mariel
author_facet Romano, Rosana Mariel
Della Védova, Carlos Omar
Mora Valdez, M. I.
Cutin, Edgardo Hugo
author_role author
author2 Della Védova, Carlos Omar
Mora Valdez, M. I.
Cutin, Edgardo Hugo
author2_role author
author
author
dc.subject.none.fl_str_mv Raman Spectra
Temperature
topic Raman Spectra
Temperature
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The vibrational spectra, including Raman spectra at different temperatures and resonance Raman spectra, and theoretical calculations of N‐fluoroformyliminotrifluoromethylsulfur fluoride, FC(O)N= S(F)CF3, were obtained and interpreted. They point to the existence of a predominant anti–syn form and in equilibrium at lower concentration a syn–syn form (the first related to the nitrogen lone pair with respect to the sulfur lone pair and the second is related to the C= O double bond with respect to the N= S double bond). The general result indicates that it is the first anti configuration reported for this type of molecule implying for the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms.
Fil: Romano, Rosana Mariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica ; Argentina
Fil: Della Védova, Carlos Omar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica ; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Servicios a la Industria y al Sistema Científico; Argentina
Fil: Mora Valdez, M. I.. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química Física; Argentina
Fil: Cutin, Edgardo Hugo. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química Física; Argentina
description The vibrational spectra, including Raman spectra at different temperatures and resonance Raman spectra, and theoretical calculations of N‐fluoroformyliminotrifluoromethylsulfur fluoride, FC(O)N= S(F)CF3, were obtained and interpreted. They point to the existence of a predominant anti–syn form and in equilibrium at lower concentration a syn–syn form (the first related to the nitrogen lone pair with respect to the sulfur lone pair and the second is related to the C= O double bond with respect to the N= S double bond). The general result indicates that it is the first anti configuration reported for this type of molecule implying for the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms.
publishDate 2000
dc.date.none.fl_str_mv 2000-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/53263
Romano, Rosana Mariel; Della Védova, Carlos Omar; Mora Valdez, M. I.; Cutin, Edgardo Hugo; First example of a preferred anti configuration in RN=SX2 compounds: N-fluoroformyliminotrifluoromethylsulfur fluoride, FC(O)N=S(F)CF3; John Wiley & Sons Ltd; Journal Of Raman Spectroscopy; 31; 10; 10-2000; 881-885
0377-0486
CONICET Digital
CONICET
url http://hdl.handle.net/11336/53263
identifier_str_mv Romano, Rosana Mariel; Della Védova, Carlos Omar; Mora Valdez, M. I.; Cutin, Edgardo Hugo; First example of a preferred anti configuration in RN=SX2 compounds: N-fluoroformyliminotrifluoromethylsulfur fluoride, FC(O)N=S(F)CF3; John Wiley & Sons Ltd; Journal Of Raman Spectroscopy; 31; 10; 10-2000; 881-885
0377-0486
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1002/1097-4555(200010)31:10%3C881::AID-JRS588%3E3.0.CO;2-T
info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/1097-4555%28200010%2931%3A10%3C881%3A%3AAID-JRS588%3E3.0.CO%3B2-T
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv John Wiley & Sons Ltd
publisher.none.fl_str_mv John Wiley & Sons Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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