Effect of the electrode potential on the surface composition and crystal structure of LiMn2O4 in aqueous solutions

Autores
Marchini, Florencia; Calvo, Ernesto Julio; Williams, Federico José
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Cubic spinel LiMn2O4 has been studied for the reversible extraction of Li+ from natural brine after the application of suitable electrode potentials. In this work we report on the insertion/extraction of Li+ from natural brine of Olaroz salt flat (Jujuy, Argentina) and aqueous LiCl solutions into/from Li1-xMn2O4 (0 < x ≤ 1) to determine changes in the crystal structure and surface composition upon electrochemical polarization. In agreement with the behavior in organic electrolytes, we found that the insertion and extraction of Li+ proceeds via a two stage process and that the crystal structure undergoes two cubic phase transitions as the lattice is expanded or contracted. Contrary to the behavior in organic solvents, no decomposition layer is formed on the electrode surface and the surface composition can be controlled with the electrode potential. We also found that sodium cations present in natural brine are not inserted into the crystal lattice in the potential window explored, however they are adsorbed on the oxide surface blocking Li+ adsorption sites and decreasing the rate of Li+ exchange.
Fil: Marchini, Florencia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Calvo, Ernesto Julio. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Williams, Federico José. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Materia
BATTERY ELECTRODE
EXTRACTION
LIMN2O4
LITHIUM
XPS
XRD
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/89595
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/89595
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Effect of the electrode potential on the surface composition and crystal structure of LiMn2O4 in aqueous solutionsMarchini, FlorenciaCalvo, Ernesto JulioWilliams, Federico JoséBATTERY ELECTRODEEXTRACTIONLIMN2O4LITHIUMXPSXRDhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Cubic spinel LiMn2O4 has been studied for the reversible extraction of Li+ from natural brine after the application of suitable electrode potentials. In this work we report on the insertion/extraction of Li+ from natural brine of Olaroz salt flat (Jujuy, Argentina) and aqueous LiCl solutions into/from Li1-xMn2O4 (0 < x ≤ 1) to determine changes in the crystal structure and surface composition upon electrochemical polarization. In agreement with the behavior in organic electrolytes, we found that the insertion and extraction of Li+ proceeds via a two stage process and that the crystal structure undergoes two cubic phase transitions as the lattice is expanded or contracted. Contrary to the behavior in organic solvents, no decomposition layer is formed on the electrode surface and the surface composition can be controlled with the electrode potential. We also found that sodium cations present in natural brine are not inserted into the crystal lattice in the potential window explored, however they are adsorbed on the oxide surface blocking Li+ adsorption sites and decreasing the rate of Li+ exchange.Fil: Marchini, Florencia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: Calvo, Ernesto Julio. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: Williams, Federico José. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaPergamon-Elsevier Science Ltd2018-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/89595Marchini, Florencia; Calvo, Ernesto Julio; Williams, Federico José; Effect of the electrode potential on the surface composition and crystal structure of LiMn2O4 in aqueous solutions; Pergamon-Elsevier Science Ltd; Electrochimica Acta; 269; 4-2018; 706-7130013-4686CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0013468618304122info:eu-repo/semantics/altIdentifier/doi/10.1016/j.electacta.2018.02.108info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:37:52Zoai:ri.conicet.gov.ar:11336/89595instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:37:52.961CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Effect of the electrode potential on the surface composition and crystal structure of LiMn2O4 in aqueous solutions
title Effect of the electrode potential on the surface composition and crystal structure of LiMn2O4 in aqueous solutions
spellingShingle Effect of the electrode potential on the surface composition and crystal structure of LiMn2O4 in aqueous solutions
Marchini, Florencia
BATTERY ELECTRODE
EXTRACTION
LIMN2O4
LITHIUM
XPS
XRD
title_short Effect of the electrode potential on the surface composition and crystal structure of LiMn2O4 in aqueous solutions
title_full Effect of the electrode potential on the surface composition and crystal structure of LiMn2O4 in aqueous solutions
title_fullStr Effect of the electrode potential on the surface composition and crystal structure of LiMn2O4 in aqueous solutions
title_full_unstemmed Effect of the electrode potential on the surface composition and crystal structure of LiMn2O4 in aqueous solutions
title_sort Effect of the electrode potential on the surface composition and crystal structure of LiMn2O4 in aqueous solutions
dc.creator.none.fl_str_mv Marchini, Florencia
Calvo, Ernesto Julio
Williams, Federico José
author Marchini, Florencia
author_facet Marchini, Florencia
Calvo, Ernesto Julio
Williams, Federico José
author_role author
author2 Calvo, Ernesto Julio
Williams, Federico José
author2_role author
author
dc.subject.none.fl_str_mv BATTERY ELECTRODE
EXTRACTION
LIMN2O4
LITHIUM
XPS
XRD
topic BATTERY ELECTRODE
EXTRACTION
LIMN2O4
LITHIUM
XPS
XRD
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Cubic spinel LiMn2O4 has been studied for the reversible extraction of Li+ from natural brine after the application of suitable electrode potentials. In this work we report on the insertion/extraction of Li+ from natural brine of Olaroz salt flat (Jujuy, Argentina) and aqueous LiCl solutions into/from Li1-xMn2O4 (0 < x ≤ 1) to determine changes in the crystal structure and surface composition upon electrochemical polarization. In agreement with the behavior in organic electrolytes, we found that the insertion and extraction of Li+ proceeds via a two stage process and that the crystal structure undergoes two cubic phase transitions as the lattice is expanded or contracted. Contrary to the behavior in organic solvents, no decomposition layer is formed on the electrode surface and the surface composition can be controlled with the electrode potential. We also found that sodium cations present in natural brine are not inserted into the crystal lattice in the potential window explored, however they are adsorbed on the oxide surface blocking Li+ adsorption sites and decreasing the rate of Li+ exchange.
Fil: Marchini, Florencia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Calvo, Ernesto Julio. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Williams, Federico José. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
description Cubic spinel LiMn2O4 has been studied for the reversible extraction of Li+ from natural brine after the application of suitable electrode potentials. In this work we report on the insertion/extraction of Li+ from natural brine of Olaroz salt flat (Jujuy, Argentina) and aqueous LiCl solutions into/from Li1-xMn2O4 (0 < x ≤ 1) to determine changes in the crystal structure and surface composition upon electrochemical polarization. In agreement with the behavior in organic electrolytes, we found that the insertion and extraction of Li+ proceeds via a two stage process and that the crystal structure undergoes two cubic phase transitions as the lattice is expanded or contracted. Contrary to the behavior in organic solvents, no decomposition layer is formed on the electrode surface and the surface composition can be controlled with the electrode potential. We also found that sodium cations present in natural brine are not inserted into the crystal lattice in the potential window explored, however they are adsorbed on the oxide surface blocking Li+ adsorption sites and decreasing the rate of Li+ exchange.
publishDate 2018
dc.date.none.fl_str_mv 2018-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/89595
Marchini, Florencia; Calvo, Ernesto Julio; Williams, Federico José; Effect of the electrode potential on the surface composition and crystal structure of LiMn2O4 in aqueous solutions; Pergamon-Elsevier Science Ltd; Electrochimica Acta; 269; 4-2018; 706-713
0013-4686
CONICET Digital
CONICET
url http://hdl.handle.net/11336/89595
identifier_str_mv Marchini, Florencia; Calvo, Ernesto Julio; Williams, Federico José; Effect of the electrode potential on the surface composition and crystal structure of LiMn2O4 in aqueous solutions; Pergamon-Elsevier Science Ltd; Electrochimica Acta; 269; 4-2018; 706-713
0013-4686
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0013468618304122
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.electacta.2018.02.108
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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