Hydrogen oxidation reaction: Evidences of different electrocatalytic activity between α and β Pd-H
- Autores
- Rau, Maria Sol; Quaino, Paola Monica; Gennero, Maria Rosa; Chialvo, Abel Cesar
- Año de publicación
- 2008
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The hydrogen oxidation reaction (hor) was studied in steady state conditions on a palladium thin film electrode supported on a gold rotating disc. The electrode surface was characterized by cyclic voltammetry and SEM observation. The hydrogen absorption process was analysed by open circuit potential decay in an acid solution saturated with hydrogen and the kinetic measurements were carried out potentiostatically in the same solution. The results obtained show a marked change on the dependence of the current density on overpotential due to the transition between the α and β phases of the Pd-H system. These results were correlated with appropriate kinetic expressions and the corresponding electrocatalytic activity of both phases was estimated.
Fil: Rau, Maria Sol. Universidad Nacional del Litoral; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Quaino, Paola Monica. Universidad Nacional del Litoral; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Gennero, Maria Rosa. Universidad Nacional del Litoral. Instituto de Química Aplicada del Litoral. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Química Aplicada del Litoral.; Argentina
Fil: Chialvo, Abel Cesar. Universidad Nacional del Litoral. Instituto de Química Aplicada del Litoral. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Química Aplicada del Litoral.; Argentina - Materia
-
ELECTROCATALYTIC ACTIVITY
HYDROGEN OXIDATION REACTION
PALLADIUM THIN FILM - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
- Repositorio
.jpg)
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/114118
Ver los metadatos del registro completo
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Hydrogen oxidation reaction: Evidences of different electrocatalytic activity between α and β Pd-HRau, Maria SolQuaino, Paola MonicaGennero, Maria RosaChialvo, Abel CesarELECTROCATALYTIC ACTIVITYHYDROGEN OXIDATION REACTIONPALLADIUM THIN FILMhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The hydrogen oxidation reaction (hor) was studied in steady state conditions on a palladium thin film electrode supported on a gold rotating disc. The electrode surface was characterized by cyclic voltammetry and SEM observation. The hydrogen absorption process was analysed by open circuit potential decay in an acid solution saturated with hydrogen and the kinetic measurements were carried out potentiostatically in the same solution. The results obtained show a marked change on the dependence of the current density on overpotential due to the transition between the α and β phases of the Pd-H system. These results were correlated with appropriate kinetic expressions and the corresponding electrocatalytic activity of both phases was estimated.Fil: Rau, Maria Sol. Universidad Nacional del Litoral; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Quaino, Paola Monica. Universidad Nacional del Litoral; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Gennero, Maria Rosa. Universidad Nacional del Litoral. Instituto de Química Aplicada del Litoral. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Química Aplicada del Litoral.; ArgentinaFil: Chialvo, Abel Cesar. Universidad Nacional del Litoral. Instituto de Química Aplicada del Litoral. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Química Aplicada del Litoral.; ArgentinaElsevier Science Inc2008-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/114118Rau, Maria Sol; Quaino, Paola Monica; Gennero, Maria Rosa; Chialvo, Abel Cesar; Hydrogen oxidation reaction: Evidences of different electrocatalytic activity between α and β Pd-H; Elsevier Science Inc; Electrochemistry Communications; 10; 2; 1-2008; 208-2121388-2481CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.elecom.2007.11.031info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:52:17Zoai:ri.conicet.gov.ar:11336/114118instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:52:17.753CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
| dc.title.none.fl_str_mv |
Hydrogen oxidation reaction: Evidences of different electrocatalytic activity between α and β Pd-H |
| title |
Hydrogen oxidation reaction: Evidences of different electrocatalytic activity between α and β Pd-H |
| spellingShingle |
Hydrogen oxidation reaction: Evidences of different electrocatalytic activity between α and β Pd-H Rau, Maria Sol ELECTROCATALYTIC ACTIVITY HYDROGEN OXIDATION REACTION PALLADIUM THIN FILM |
| title_short |
Hydrogen oxidation reaction: Evidences of different electrocatalytic activity between α and β Pd-H |
| title_full |
Hydrogen oxidation reaction: Evidences of different electrocatalytic activity between α and β Pd-H |
| title_fullStr |
Hydrogen oxidation reaction: Evidences of different electrocatalytic activity between α and β Pd-H |
| title_full_unstemmed |
Hydrogen oxidation reaction: Evidences of different electrocatalytic activity between α and β Pd-H |
| title_sort |
Hydrogen oxidation reaction: Evidences of different electrocatalytic activity between α and β Pd-H |
| dc.creator.none.fl_str_mv |
Rau, Maria Sol Quaino, Paola Monica Gennero, Maria Rosa Chialvo, Abel Cesar |
| author |
Rau, Maria Sol |
| author_facet |
Rau, Maria Sol Quaino, Paola Monica Gennero, Maria Rosa Chialvo, Abel Cesar |
| author_role |
author |
| author2 |
Quaino, Paola Monica Gennero, Maria Rosa Chialvo, Abel Cesar |
| author2_role |
author author author |
| dc.subject.none.fl_str_mv |
ELECTROCATALYTIC ACTIVITY HYDROGEN OXIDATION REACTION PALLADIUM THIN FILM |
| topic |
ELECTROCATALYTIC ACTIVITY HYDROGEN OXIDATION REACTION PALLADIUM THIN FILM |
| purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
| dc.description.none.fl_txt_mv |
The hydrogen oxidation reaction (hor) was studied in steady state conditions on a palladium thin film electrode supported on a gold rotating disc. The electrode surface was characterized by cyclic voltammetry and SEM observation. The hydrogen absorption process was analysed by open circuit potential decay in an acid solution saturated with hydrogen and the kinetic measurements were carried out potentiostatically in the same solution. The results obtained show a marked change on the dependence of the current density on overpotential due to the transition between the α and β phases of the Pd-H system. These results were correlated with appropriate kinetic expressions and the corresponding electrocatalytic activity of both phases was estimated. Fil: Rau, Maria Sol. Universidad Nacional del Litoral; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Fil: Quaino, Paola Monica. Universidad Nacional del Litoral; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Fil: Gennero, Maria Rosa. Universidad Nacional del Litoral. Instituto de Química Aplicada del Litoral. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Química Aplicada del Litoral.; Argentina Fil: Chialvo, Abel Cesar. Universidad Nacional del Litoral. Instituto de Química Aplicada del Litoral. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Química Aplicada del Litoral.; Argentina |
| description |
The hydrogen oxidation reaction (hor) was studied in steady state conditions on a palladium thin film electrode supported on a gold rotating disc. The electrode surface was characterized by cyclic voltammetry and SEM observation. The hydrogen absorption process was analysed by open circuit potential decay in an acid solution saturated with hydrogen and the kinetic measurements were carried out potentiostatically in the same solution. The results obtained show a marked change on the dependence of the current density on overpotential due to the transition between the α and β phases of the Pd-H system. These results were correlated with appropriate kinetic expressions and the corresponding electrocatalytic activity of both phases was estimated. |
| publishDate |
2008 |
| dc.date.none.fl_str_mv |
2008-01 |
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info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
| format |
article |
| status_str |
publishedVersion |
| dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/114118 Rau, Maria Sol; Quaino, Paola Monica; Gennero, Maria Rosa; Chialvo, Abel Cesar; Hydrogen oxidation reaction: Evidences of different electrocatalytic activity between α and β Pd-H; Elsevier Science Inc; Electrochemistry Communications; 10; 2; 1-2008; 208-212 1388-2481 CONICET Digital CONICET |
| url |
http://hdl.handle.net/11336/114118 |
| identifier_str_mv |
Rau, Maria Sol; Quaino, Paola Monica; Gennero, Maria Rosa; Chialvo, Abel Cesar; Hydrogen oxidation reaction: Evidences of different electrocatalytic activity between α and β Pd-H; Elsevier Science Inc; Electrochemistry Communications; 10; 2; 1-2008; 208-212 1388-2481 CONICET Digital CONICET |
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eng |
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eng |
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info:eu-repo/semantics/altIdentifier/doi/10.1016/j.elecom.2007.11.031 |
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openAccess |
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Elsevier Science Inc |
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