Facilitated anion transfer reactions across oil∣water interfaces

Autores
Dassie, Sergio Alberto
Año de publicación
2010
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this paper we present the general equations for a model of anion transfer reactions across the oil{divides}water interface assisted by a neutral ligand. Our analysis mainly focuses on the effect of water autoprotolysis. The equations reported here allow us to simulate the system under a variety of possible conditions. The formation of complex with j:k anion-to-ligand stoichiometry is analyzed. Three different models are compared: buffered solutions (BASA model) and unbuffered solutions with and without considering water autoprotolysis (UBASA and UBAS model respectively). Moreover, the analytical relationships for the BASA model between half-wave potential and the initial concentration of anion and ligand are developed. © 2010 Elsevier B.V. All rights reserved.
Fil: Dassie, Sergio Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Materia
Coupled Chemical Reaction
Digital Simulation
Facilitated Anion Transfer
Liquid{Divides}Liquid Interface
Water Autoprotolysis
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/71388
Acceder
id CONICETDig_d11250ff39494568459c0fd226fd97c6
oai_identifier_str oai:ri.conicet.gov.ar:11336/71388
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Facilitated anion transfer reactions across oil∣water interfacesDassie, Sergio AlbertoCoupled Chemical ReactionDigital SimulationFacilitated Anion TransferLiquid{Divides}Liquid InterfaceWater Autoprotolysishttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1In this paper we present the general equations for a model of anion transfer reactions across the oil{divides}water interface assisted by a neutral ligand. Our analysis mainly focuses on the effect of water autoprotolysis. The equations reported here allow us to simulate the system under a variety of possible conditions. The formation of complex with j:k anion-to-ligand stoichiometry is analyzed. Three different models are compared: buffered solutions (BASA model) and unbuffered solutions with and without considering water autoprotolysis (UBASA and UBAS model respectively). Moreover, the analytical relationships for the BASA model between half-wave potential and the initial concentration of anion and ligand are developed. © 2010 Elsevier B.V. All rights reserved.Fil: Dassie, Sergio Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaElsevier Science Sa2010-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/71388Dassie, Sergio Alberto; Facilitated anion transfer reactions across oil∣water interfaces; Elsevier Science Sa; Journal of Electroanalytical Chemistry; 643; 1-2; 5-2010; 20-301572-6657CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.jelechem.2010.03.013info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:57:29Zoai:ri.conicet.gov.ar:11336/71388instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:57:29.48CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Facilitated anion transfer reactions across oil∣water interfaces
title Facilitated anion transfer reactions across oil∣water interfaces
spellingShingle Facilitated anion transfer reactions across oil∣water interfaces
Dassie, Sergio Alberto
Coupled Chemical Reaction
Digital Simulation
Facilitated Anion Transfer
Liquid{Divides}Liquid Interface
Water Autoprotolysis
title_short Facilitated anion transfer reactions across oil∣water interfaces
title_full Facilitated anion transfer reactions across oil∣water interfaces
title_fullStr Facilitated anion transfer reactions across oil∣water interfaces
title_full_unstemmed Facilitated anion transfer reactions across oil∣water interfaces
title_sort Facilitated anion transfer reactions across oil∣water interfaces
dc.creator.none.fl_str_mv Dassie, Sergio Alberto
author Dassie, Sergio Alberto
author_facet Dassie, Sergio Alberto
author_role author
dc.subject.none.fl_str_mv Coupled Chemical Reaction
Digital Simulation
Facilitated Anion Transfer
Liquid{Divides}Liquid Interface
Water Autoprotolysis
topic Coupled Chemical Reaction
Digital Simulation
Facilitated Anion Transfer
Liquid{Divides}Liquid Interface
Water Autoprotolysis
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv In this paper we present the general equations for a model of anion transfer reactions across the oil{divides}water interface assisted by a neutral ligand. Our analysis mainly focuses on the effect of water autoprotolysis. The equations reported here allow us to simulate the system under a variety of possible conditions. The formation of complex with j:k anion-to-ligand stoichiometry is analyzed. Three different models are compared: buffered solutions (BASA model) and unbuffered solutions with and without considering water autoprotolysis (UBASA and UBAS model respectively). Moreover, the analytical relationships for the BASA model between half-wave potential and the initial concentration of anion and ligand are developed. © 2010 Elsevier B.V. All rights reserved.
Fil: Dassie, Sergio Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
description In this paper we present the general equations for a model of anion transfer reactions across the oil{divides}water interface assisted by a neutral ligand. Our analysis mainly focuses on the effect of water autoprotolysis. The equations reported here allow us to simulate the system under a variety of possible conditions. The formation of complex with j:k anion-to-ligand stoichiometry is analyzed. Three different models are compared: buffered solutions (BASA model) and unbuffered solutions with and without considering water autoprotolysis (UBASA and UBAS model respectively). Moreover, the analytical relationships for the BASA model between half-wave potential and the initial concentration of anion and ligand are developed. © 2010 Elsevier B.V. All rights reserved.
publishDate 2010
dc.date.none.fl_str_mv 2010-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/71388
Dassie, Sergio Alberto; Facilitated anion transfer reactions across oil∣water interfaces; Elsevier Science Sa; Journal of Electroanalytical Chemistry; 643; 1-2; 5-2010; 20-30
1572-6657
CONICET Digital
CONICET
url http://hdl.handle.net/11336/71388
identifier_str_mv Dassie, Sergio Alberto; Facilitated anion transfer reactions across oil∣water interfaces; Elsevier Science Sa; Journal of Electroanalytical Chemistry; 643; 1-2; 5-2010; 20-30
1572-6657
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jelechem.2010.03.013
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science Sa
publisher.none.fl_str_mv Elsevier Science Sa
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844613719565271040
score 13.070432

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