Tuning the morphological structure, light absorption, and photocatalytic activity of Bi2WO6 and Bi2WO6-BiOCl through cerium doping

Autores
Hojamberdiev, Mirabbos; Kadirova, Zukhra C.; Zahedi, Ehsan; Onna, Diego Ariel; Marchi, María Claudia; Zhu, Gangqiang; Matsushita, Nobuhiro; Hasegawa, Masashi; Aldabe, Sara Alfonsina; Okada, Elena
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Pharmaceuticals and personal care products are recognized as new classes of water pollutants that receive considerable attention because of their negative environmental impact on aquatic life and humans. Because microbiological and/or conventional secondary physicochemical treatments cannot completely remove those water pollutants, effective advanced oxidation processes using semiconductor-based photocatalysts are needed to ensure their total elimination in water. Here, we report on the tuning of the morphological structure, light absorption, and photocatalytic activity of Bi2WO6 and Bi2WO6-BiOCl through cerium doping. Non-doped and Ce-doped Bi2WO6 and Bi2WO6-BiOCl powders are synthesized by a hydrothermal method, and their adsorption ability and photocatalytic activity are evaluated for the removal of salicylic acid in the dark and under visible light irradiation, respectively. The adsorption affinities and preferential sites of salicylic acid molecules on non-doped and Ce-doped Bi2WO6, BiOCl, and Bi2WO6-BiOCl are computationally predicted using molecular dynamics simulations. When ethylene glycol is replaced by dilute HCl as a solvent in a hydrothermal system, BiOCl is also formed along with Bi2WO6, confirming the successful formation of a Bi2WO6-BiOCl composite. The flower-like hierarchical structures of Bi2WO6 and Bi2WO6-BiOCl can absorb more photon energy due to multiple scattering, charge carriers can easily transfer to the surface/interface, and mesopores can improve the transfer rate of organic molecules, contributing to the overall enhancement in photocatalytic activity. The Bi2WO6-BiOCl samples show higher photocatalytic activity than that of the Bi2WO6 samples for the degradation of salicylic acid due to the formed p–n heterojunction. The optimum concentration of Ce doping is found to be 1 mol% in the Bi2WO6 and Bi2WO6-BiOCl, promoting the effective separation and transfer of photogenerated charge carriers, resulting in high photocatalytic performance, and the sample exhibited good stability.
Fil: Hojamberdiev, Mirabbos. Tokyo Institute Of Technology; Japón
Fil: Kadirova, Zukhra C.. Uzbekistan-japan Youth Innovation Center; Uzbekistán
Fil: Zahedi, Ehsan. Islamic Azad University; Irán
Fil: Onna, Diego Ariel. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; Argentina
Fil: Marchi, María Claudia. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; Argentina
Fil: Zhu, Gangqiang. Shaanxi Normal University; China
Fil: Matsushita, Nobuhiro. Nagoya University; Japón
Fil: Hasegawa, Masashi. Tokyo Institute Of Technology; Japón
Fil: Aldabe, Sara Alfonsina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; Argentina
Fil: Okada, Elena. Tokyo Institute Of Technology; Japón
Materia
BI2WO6
BIOCL
CERIUM DOPING
PHOTOCATALYST
SALICYLIC ACID
WATER POLLUTANT
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/86140
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/86140
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Tuning the morphological structure, light absorption, and photocatalytic activity of Bi2WO6 and Bi2WO6-BiOCl through cerium dopingHojamberdiev, MirabbosKadirova, Zukhra C.Zahedi, EhsanOnna, Diego ArielMarchi, María ClaudiaZhu, GangqiangMatsushita, NobuhiroHasegawa, MasashiAldabe, Sara AlfonsinaOkada, ElenaBI2WO6BIOCLCERIUM DOPINGPHOTOCATALYSTSALICYLIC ACIDWATER POLLUTANThttps://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2https://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2Pharmaceuticals and personal care products are recognized as new classes of water pollutants that receive considerable attention because of their negative environmental impact on aquatic life and humans. Because microbiological and/or conventional secondary physicochemical treatments cannot completely remove those water pollutants, effective advanced oxidation processes using semiconductor-based photocatalysts are needed to ensure their total elimination in water. Here, we report on the tuning of the morphological structure, light absorption, and photocatalytic activity of Bi2WO6 and Bi2WO6-BiOCl through cerium doping. Non-doped and Ce-doped Bi2WO6 and Bi2WO6-BiOCl powders are synthesized by a hydrothermal method, and their adsorption ability and photocatalytic activity are evaluated for the removal of salicylic acid in the dark and under visible light irradiation, respectively. The adsorption affinities and preferential sites of salicylic acid molecules on non-doped and Ce-doped Bi2WO6, BiOCl, and Bi2WO6-BiOCl are computationally predicted using molecular dynamics simulations. When ethylene glycol is replaced by dilute HCl as a solvent in a hydrothermal system, BiOCl is also formed along with Bi2WO6, confirming the successful formation of a Bi2WO6-BiOCl composite. The flower-like hierarchical structures of Bi2WO6 and Bi2WO6-BiOCl can absorb more photon energy due to multiple scattering, charge carriers can easily transfer to the surface/interface, and mesopores can improve the transfer rate of organic molecules, contributing to the overall enhancement in photocatalytic activity. The Bi2WO6-BiOCl samples show higher photocatalytic activity than that of the Bi2WO6 samples for the degradation of salicylic acid due to the formed p–n heterojunction. The optimum concentration of Ce doping is found to be 1 mol% in the Bi2WO6 and Bi2WO6-BiOCl, promoting the effective separation and transfer of photogenerated charge carriers, resulting in high photocatalytic performance, and the sample exhibited good stability.Fil: Hojamberdiev, Mirabbos. Tokyo Institute Of Technology; JapónFil: Kadirova, Zukhra C.. Uzbekistan-japan Youth Innovation Center; UzbekistánFil: Zahedi, Ehsan. Islamic Azad University; IránFil: Onna, Diego Ariel. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; ArgentinaFil: Marchi, María Claudia. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; ArgentinaFil: Zhu, Gangqiang. Shaanxi Normal University; ChinaFil: Matsushita, Nobuhiro. Nagoya University; JapónFil: Hasegawa, Masashi. Tokyo Institute Of Technology; JapónFil: Aldabe, Sara Alfonsina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; ArgentinaFil: Okada, Elena. Tokyo Institute Of Technology; JapónElsevier2018-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/86140Hojamberdiev, Mirabbos; Kadirova, Zukhra C.; Zahedi, Ehsan; Onna, Diego Ariel; Marchi, María Claudia; et al.; Tuning the morphological structure, light absorption, and photocatalytic activity of Bi2WO6 and Bi2WO6-BiOCl through cerium doping; Elsevier; Arabian Journal of Chemistry; 11; 7-2018; 1-141878-5352CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S187853521830162Xinfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.arabjc.2018.07.014info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:22:59Zoai:ri.conicet.gov.ar:11336/86140instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:22:59.981CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Tuning the morphological structure, light absorption, and photocatalytic activity of Bi2WO6 and Bi2WO6-BiOCl through cerium doping
title Tuning the morphological structure, light absorption, and photocatalytic activity of Bi2WO6 and Bi2WO6-BiOCl through cerium doping
spellingShingle Tuning the morphological structure, light absorption, and photocatalytic activity of Bi2WO6 and Bi2WO6-BiOCl through cerium doping
Hojamberdiev, Mirabbos
BI2WO6
BIOCL
CERIUM DOPING
PHOTOCATALYST
SALICYLIC ACID
WATER POLLUTANT
title_short Tuning the morphological structure, light absorption, and photocatalytic activity of Bi2WO6 and Bi2WO6-BiOCl through cerium doping
title_full Tuning the morphological structure, light absorption, and photocatalytic activity of Bi2WO6 and Bi2WO6-BiOCl through cerium doping
title_fullStr Tuning the morphological structure, light absorption, and photocatalytic activity of Bi2WO6 and Bi2WO6-BiOCl through cerium doping
title_full_unstemmed Tuning the morphological structure, light absorption, and photocatalytic activity of Bi2WO6 and Bi2WO6-BiOCl through cerium doping
title_sort Tuning the morphological structure, light absorption, and photocatalytic activity of Bi2WO6 and Bi2WO6-BiOCl through cerium doping
dc.creator.none.fl_str_mv Hojamberdiev, Mirabbos
Kadirova, Zukhra C.
Zahedi, Ehsan
Onna, Diego Ariel
Marchi, María Claudia
Zhu, Gangqiang
Matsushita, Nobuhiro
Hasegawa, Masashi
Aldabe, Sara Alfonsina
Okada, Elena
author Hojamberdiev, Mirabbos
author_facet Hojamberdiev, Mirabbos
Kadirova, Zukhra C.
Zahedi, Ehsan
Onna, Diego Ariel
Marchi, María Claudia
Zhu, Gangqiang
Matsushita, Nobuhiro
Hasegawa, Masashi
Aldabe, Sara Alfonsina
Okada, Elena
author_role author
author2 Kadirova, Zukhra C.
Zahedi, Ehsan
Onna, Diego Ariel
Marchi, María Claudia
Zhu, Gangqiang
Matsushita, Nobuhiro
Hasegawa, Masashi
Aldabe, Sara Alfonsina
Okada, Elena
author2_role author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv BI2WO6
BIOCL
CERIUM DOPING
PHOTOCATALYST
SALICYLIC ACID
WATER POLLUTANT
topic BI2WO6
BIOCL
CERIUM DOPING
PHOTOCATALYST
SALICYLIC ACID
WATER POLLUTANT
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.10
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/2.10
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Pharmaceuticals and personal care products are recognized as new classes of water pollutants that receive considerable attention because of their negative environmental impact on aquatic life and humans. Because microbiological and/or conventional secondary physicochemical treatments cannot completely remove those water pollutants, effective advanced oxidation processes using semiconductor-based photocatalysts are needed to ensure their total elimination in water. Here, we report on the tuning of the morphological structure, light absorption, and photocatalytic activity of Bi2WO6 and Bi2WO6-BiOCl through cerium doping. Non-doped and Ce-doped Bi2WO6 and Bi2WO6-BiOCl powders are synthesized by a hydrothermal method, and their adsorption ability and photocatalytic activity are evaluated for the removal of salicylic acid in the dark and under visible light irradiation, respectively. The adsorption affinities and preferential sites of salicylic acid molecules on non-doped and Ce-doped Bi2WO6, BiOCl, and Bi2WO6-BiOCl are computationally predicted using molecular dynamics simulations. When ethylene glycol is replaced by dilute HCl as a solvent in a hydrothermal system, BiOCl is also formed along with Bi2WO6, confirming the successful formation of a Bi2WO6-BiOCl composite. The flower-like hierarchical structures of Bi2WO6 and Bi2WO6-BiOCl can absorb more photon energy due to multiple scattering, charge carriers can easily transfer to the surface/interface, and mesopores can improve the transfer rate of organic molecules, contributing to the overall enhancement in photocatalytic activity. The Bi2WO6-BiOCl samples show higher photocatalytic activity than that of the Bi2WO6 samples for the degradation of salicylic acid due to the formed p–n heterojunction. The optimum concentration of Ce doping is found to be 1 mol% in the Bi2WO6 and Bi2WO6-BiOCl, promoting the effective separation and transfer of photogenerated charge carriers, resulting in high photocatalytic performance, and the sample exhibited good stability.
Fil: Hojamberdiev, Mirabbos. Tokyo Institute Of Technology; Japón
Fil: Kadirova, Zukhra C.. Uzbekistan-japan Youth Innovation Center; Uzbekistán
Fil: Zahedi, Ehsan. Islamic Azad University; Irán
Fil: Onna, Diego Ariel. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; Argentina
Fil: Marchi, María Claudia. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; Argentina
Fil: Zhu, Gangqiang. Shaanxi Normal University; China
Fil: Matsushita, Nobuhiro. Nagoya University; Japón
Fil: Hasegawa, Masashi. Tokyo Institute Of Technology; Japón
Fil: Aldabe, Sara Alfonsina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; Argentina
Fil: Okada, Elena. Tokyo Institute Of Technology; Japón
description Pharmaceuticals and personal care products are recognized as new classes of water pollutants that receive considerable attention because of their negative environmental impact on aquatic life and humans. Because microbiological and/or conventional secondary physicochemical treatments cannot completely remove those water pollutants, effective advanced oxidation processes using semiconductor-based photocatalysts are needed to ensure their total elimination in water. Here, we report on the tuning of the morphological structure, light absorption, and photocatalytic activity of Bi2WO6 and Bi2WO6-BiOCl through cerium doping. Non-doped and Ce-doped Bi2WO6 and Bi2WO6-BiOCl powders are synthesized by a hydrothermal method, and their adsorption ability and photocatalytic activity are evaluated for the removal of salicylic acid in the dark and under visible light irradiation, respectively. The adsorption affinities and preferential sites of salicylic acid molecules on non-doped and Ce-doped Bi2WO6, BiOCl, and Bi2WO6-BiOCl are computationally predicted using molecular dynamics simulations. When ethylene glycol is replaced by dilute HCl as a solvent in a hydrothermal system, BiOCl is also formed along with Bi2WO6, confirming the successful formation of a Bi2WO6-BiOCl composite. The flower-like hierarchical structures of Bi2WO6 and Bi2WO6-BiOCl can absorb more photon energy due to multiple scattering, charge carriers can easily transfer to the surface/interface, and mesopores can improve the transfer rate of organic molecules, contributing to the overall enhancement in photocatalytic activity. The Bi2WO6-BiOCl samples show higher photocatalytic activity than that of the Bi2WO6 samples for the degradation of salicylic acid due to the formed p–n heterojunction. The optimum concentration of Ce doping is found to be 1 mol% in the Bi2WO6 and Bi2WO6-BiOCl, promoting the effective separation and transfer of photogenerated charge carriers, resulting in high photocatalytic performance, and the sample exhibited good stability.
publishDate 2018
dc.date.none.fl_str_mv 2018-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/86140
Hojamberdiev, Mirabbos; Kadirova, Zukhra C.; Zahedi, Ehsan; Onna, Diego Ariel; Marchi, María Claudia; et al.; Tuning the morphological structure, light absorption, and photocatalytic activity of Bi2WO6 and Bi2WO6-BiOCl through cerium doping; Elsevier; Arabian Journal of Chemistry; 11; 7-2018; 1-14
1878-5352
CONICET Digital
CONICET
url http://hdl.handle.net/11336/86140
identifier_str_mv Hojamberdiev, Mirabbos; Kadirova, Zukhra C.; Zahedi, Ehsan; Onna, Diego Ariel; Marchi, María Claudia; et al.; Tuning the morphological structure, light absorption, and photocatalytic activity of Bi2WO6 and Bi2WO6-BiOCl through cerium doping; Elsevier; Arabian Journal of Chemistry; 11; 7-2018; 1-14
1878-5352
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S187853521830162X
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.arabjc.2018.07.014
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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