Tuning the morphological structure, light absorption, and photocatalytic activity of Bi2WO6 and Bi2WO6-BiOCl through cerium doping
- Autores
- Hojamberdiev, Mirabbos; Kadirova, Zukhra C.; Zahedi, Ehsan; Onna, Diego Ariel; Marchi, María Claudia; Zhu, Gangqiang; Matsushita, Nobuhiro; Hasegawa, Masashi; Aldabe, Sara Alfonsina; Okada, Elena
- Año de publicación
- 2018
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Pharmaceuticals and personal care products are recognized as new classes of water pollutants that receive considerable attention because of their negative environmental impact on aquatic life and humans. Because microbiological and/or conventional secondary physicochemical treatments cannot completely remove those water pollutants, effective advanced oxidation processes using semiconductor-based photocatalysts are needed to ensure their total elimination in water. Here, we report on the tuning of the morphological structure, light absorption, and photocatalytic activity of Bi2WO6 and Bi2WO6-BiOCl through cerium doping. Non-doped and Ce-doped Bi2WO6 and Bi2WO6-BiOCl powders are synthesized by a hydrothermal method, and their adsorption ability and photocatalytic activity are evaluated for the removal of salicylic acid in the dark and under visible light irradiation, respectively. The adsorption affinities and preferential sites of salicylic acid molecules on non-doped and Ce-doped Bi2WO6, BiOCl, and Bi2WO6-BiOCl are computationally predicted using molecular dynamics simulations. When ethylene glycol is replaced by dilute HCl as a solvent in a hydrothermal system, BiOCl is also formed along with Bi2WO6, confirming the successful formation of a Bi2WO6-BiOCl composite. The flower-like hierarchical structures of Bi2WO6 and Bi2WO6-BiOCl can absorb more photon energy due to multiple scattering, charge carriers can easily transfer to the surface/interface, and mesopores can improve the transfer rate of organic molecules, contributing to the overall enhancement in photocatalytic activity. The Bi2WO6-BiOCl samples show higher photocatalytic activity than that of the Bi2WO6 samples for the degradation of salicylic acid due to the formed p–n heterojunction. The optimum concentration of Ce doping is found to be 1 mol% in the Bi2WO6 and Bi2WO6-BiOCl, promoting the effective separation and transfer of photogenerated charge carriers, resulting in high photocatalytic performance, and the sample exhibited good stability.
Fil: Hojamberdiev, Mirabbos. Tokyo Institute Of Technology; Japón
Fil: Kadirova, Zukhra C.. Uzbekistan-japan Youth Innovation Center; Uzbekistán
Fil: Zahedi, Ehsan. Islamic Azad University; Irán
Fil: Onna, Diego Ariel. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; Argentina
Fil: Marchi, María Claudia. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; Argentina
Fil: Zhu, Gangqiang. Shaanxi Normal University; China
Fil: Matsushita, Nobuhiro. Nagoya University; Japón
Fil: Hasegawa, Masashi. Tokyo Institute Of Technology; Japón
Fil: Aldabe, Sara Alfonsina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; Argentina
Fil: Okada, Elena. Tokyo Institute Of Technology; Japón - Materia
-
BI2WO6
BIOCL
CERIUM DOPING
PHOTOCATALYST
SALICYLIC ACID
WATER POLLUTANT - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/86140
Ver los metadatos del registro completo
id |
CONICETDig_d08cf58ebbbf0646857c207e8eecbdf7 |
---|---|
oai_identifier_str |
oai:ri.conicet.gov.ar:11336/86140 |
network_acronym_str |
CONICETDig |
repository_id_str |
3498 |
network_name_str |
CONICET Digital (CONICET) |
spelling |
Tuning the morphological structure, light absorption, and photocatalytic activity of Bi2WO6 and Bi2WO6-BiOCl through cerium dopingHojamberdiev, MirabbosKadirova, Zukhra C.Zahedi, EhsanOnna, Diego ArielMarchi, María ClaudiaZhu, GangqiangMatsushita, NobuhiroHasegawa, MasashiAldabe, Sara AlfonsinaOkada, ElenaBI2WO6BIOCLCERIUM DOPINGPHOTOCATALYSTSALICYLIC ACIDWATER POLLUTANThttps://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2https://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2Pharmaceuticals and personal care products are recognized as new classes of water pollutants that receive considerable attention because of their negative environmental impact on aquatic life and humans. Because microbiological and/or conventional secondary physicochemical treatments cannot completely remove those water pollutants, effective advanced oxidation processes using semiconductor-based photocatalysts are needed to ensure their total elimination in water. Here, we report on the tuning of the morphological structure, light absorption, and photocatalytic activity of Bi2WO6 and Bi2WO6-BiOCl through cerium doping. Non-doped and Ce-doped Bi2WO6 and Bi2WO6-BiOCl powders are synthesized by a hydrothermal method, and their adsorption ability and photocatalytic activity are evaluated for the removal of salicylic acid in the dark and under visible light irradiation, respectively. The adsorption affinities and preferential sites of salicylic acid molecules on non-doped and Ce-doped Bi2WO6, BiOCl, and Bi2WO6-BiOCl are computationally predicted using molecular dynamics simulations. When ethylene glycol is replaced by dilute HCl as a solvent in a hydrothermal system, BiOCl is also formed along with Bi2WO6, confirming the successful formation of a Bi2WO6-BiOCl composite. The flower-like hierarchical structures of Bi2WO6 and Bi2WO6-BiOCl can absorb more photon energy due to multiple scattering, charge carriers can easily transfer to the surface/interface, and mesopores can improve the transfer rate of organic molecules, contributing to the overall enhancement in photocatalytic activity. The Bi2WO6-BiOCl samples show higher photocatalytic activity than that of the Bi2WO6 samples for the degradation of salicylic acid due to the formed p–n heterojunction. The optimum concentration of Ce doping is found to be 1 mol% in the Bi2WO6 and Bi2WO6-BiOCl, promoting the effective separation and transfer of photogenerated charge carriers, resulting in high photocatalytic performance, and the sample exhibited good stability.Fil: Hojamberdiev, Mirabbos. Tokyo Institute Of Technology; JapónFil: Kadirova, Zukhra C.. Uzbekistan-japan Youth Innovation Center; UzbekistánFil: Zahedi, Ehsan. Islamic Azad University; IránFil: Onna, Diego Ariel. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; ArgentinaFil: Marchi, María Claudia. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; ArgentinaFil: Zhu, Gangqiang. Shaanxi Normal University; ChinaFil: Matsushita, Nobuhiro. Nagoya University; JapónFil: Hasegawa, Masashi. Tokyo Institute Of Technology; JapónFil: Aldabe, Sara Alfonsina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; ArgentinaFil: Okada, Elena. Tokyo Institute Of Technology; JapónElsevier2018-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/86140Hojamberdiev, Mirabbos; Kadirova, Zukhra C.; Zahedi, Ehsan; Onna, Diego Ariel; Marchi, María Claudia; et al.; Tuning the morphological structure, light absorption, and photocatalytic activity of Bi2WO6 and Bi2WO6-BiOCl through cerium doping; Elsevier; Arabian Journal of Chemistry; 11; 7-2018; 1-141878-5352CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S187853521830162Xinfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.arabjc.2018.07.014info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:53:39Zoai:ri.conicet.gov.ar:11336/86140instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:53:40.015CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Tuning the morphological structure, light absorption, and photocatalytic activity of Bi2WO6 and Bi2WO6-BiOCl through cerium doping |
title |
Tuning the morphological structure, light absorption, and photocatalytic activity of Bi2WO6 and Bi2WO6-BiOCl through cerium doping |
spellingShingle |
Tuning the morphological structure, light absorption, and photocatalytic activity of Bi2WO6 and Bi2WO6-BiOCl through cerium doping Hojamberdiev, Mirabbos BI2WO6 BIOCL CERIUM DOPING PHOTOCATALYST SALICYLIC ACID WATER POLLUTANT |
title_short |
Tuning the morphological structure, light absorption, and photocatalytic activity of Bi2WO6 and Bi2WO6-BiOCl through cerium doping |
title_full |
Tuning the morphological structure, light absorption, and photocatalytic activity of Bi2WO6 and Bi2WO6-BiOCl through cerium doping |
title_fullStr |
Tuning the morphological structure, light absorption, and photocatalytic activity of Bi2WO6 and Bi2WO6-BiOCl through cerium doping |
title_full_unstemmed |
Tuning the morphological structure, light absorption, and photocatalytic activity of Bi2WO6 and Bi2WO6-BiOCl through cerium doping |
title_sort |
Tuning the morphological structure, light absorption, and photocatalytic activity of Bi2WO6 and Bi2WO6-BiOCl through cerium doping |
dc.creator.none.fl_str_mv |
Hojamberdiev, Mirabbos Kadirova, Zukhra C. Zahedi, Ehsan Onna, Diego Ariel Marchi, María Claudia Zhu, Gangqiang Matsushita, Nobuhiro Hasegawa, Masashi Aldabe, Sara Alfonsina Okada, Elena |
author |
Hojamberdiev, Mirabbos |
author_facet |
Hojamberdiev, Mirabbos Kadirova, Zukhra C. Zahedi, Ehsan Onna, Diego Ariel Marchi, María Claudia Zhu, Gangqiang Matsushita, Nobuhiro Hasegawa, Masashi Aldabe, Sara Alfonsina Okada, Elena |
author_role |
author |
author2 |
Kadirova, Zukhra C. Zahedi, Ehsan Onna, Diego Ariel Marchi, María Claudia Zhu, Gangqiang Matsushita, Nobuhiro Hasegawa, Masashi Aldabe, Sara Alfonsina Okada, Elena |
author2_role |
author author author author author author author author author |
dc.subject.none.fl_str_mv |
BI2WO6 BIOCL CERIUM DOPING PHOTOCATALYST SALICYLIC ACID WATER POLLUTANT |
topic |
BI2WO6 BIOCL CERIUM DOPING PHOTOCATALYST SALICYLIC ACID WATER POLLUTANT |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.10 https://purl.org/becyt/ford/2 https://purl.org/becyt/ford/2.10 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
Pharmaceuticals and personal care products are recognized as new classes of water pollutants that receive considerable attention because of their negative environmental impact on aquatic life and humans. Because microbiological and/or conventional secondary physicochemical treatments cannot completely remove those water pollutants, effective advanced oxidation processes using semiconductor-based photocatalysts are needed to ensure their total elimination in water. Here, we report on the tuning of the morphological structure, light absorption, and photocatalytic activity of Bi2WO6 and Bi2WO6-BiOCl through cerium doping. Non-doped and Ce-doped Bi2WO6 and Bi2WO6-BiOCl powders are synthesized by a hydrothermal method, and their adsorption ability and photocatalytic activity are evaluated for the removal of salicylic acid in the dark and under visible light irradiation, respectively. The adsorption affinities and preferential sites of salicylic acid molecules on non-doped and Ce-doped Bi2WO6, BiOCl, and Bi2WO6-BiOCl are computationally predicted using molecular dynamics simulations. When ethylene glycol is replaced by dilute HCl as a solvent in a hydrothermal system, BiOCl is also formed along with Bi2WO6, confirming the successful formation of a Bi2WO6-BiOCl composite. The flower-like hierarchical structures of Bi2WO6 and Bi2WO6-BiOCl can absorb more photon energy due to multiple scattering, charge carriers can easily transfer to the surface/interface, and mesopores can improve the transfer rate of organic molecules, contributing to the overall enhancement in photocatalytic activity. The Bi2WO6-BiOCl samples show higher photocatalytic activity than that of the Bi2WO6 samples for the degradation of salicylic acid due to the formed p–n heterojunction. The optimum concentration of Ce doping is found to be 1 mol% in the Bi2WO6 and Bi2WO6-BiOCl, promoting the effective separation and transfer of photogenerated charge carriers, resulting in high photocatalytic performance, and the sample exhibited good stability. Fil: Hojamberdiev, Mirabbos. Tokyo Institute Of Technology; Japón Fil: Kadirova, Zukhra C.. Uzbekistan-japan Youth Innovation Center; Uzbekistán Fil: Zahedi, Ehsan. Islamic Azad University; Irán Fil: Onna, Diego Ariel. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; Argentina Fil: Marchi, María Claudia. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; Argentina Fil: Zhu, Gangqiang. Shaanxi Normal University; China Fil: Matsushita, Nobuhiro. Nagoya University; Japón Fil: Hasegawa, Masashi. Tokyo Institute Of Technology; Japón Fil: Aldabe, Sara Alfonsina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; Argentina Fil: Okada, Elena. Tokyo Institute Of Technology; Japón |
description |
Pharmaceuticals and personal care products are recognized as new classes of water pollutants that receive considerable attention because of their negative environmental impact on aquatic life and humans. Because microbiological and/or conventional secondary physicochemical treatments cannot completely remove those water pollutants, effective advanced oxidation processes using semiconductor-based photocatalysts are needed to ensure their total elimination in water. Here, we report on the tuning of the morphological structure, light absorption, and photocatalytic activity of Bi2WO6 and Bi2WO6-BiOCl through cerium doping. Non-doped and Ce-doped Bi2WO6 and Bi2WO6-BiOCl powders are synthesized by a hydrothermal method, and their adsorption ability and photocatalytic activity are evaluated for the removal of salicylic acid in the dark and under visible light irradiation, respectively. The adsorption affinities and preferential sites of salicylic acid molecules on non-doped and Ce-doped Bi2WO6, BiOCl, and Bi2WO6-BiOCl are computationally predicted using molecular dynamics simulations. When ethylene glycol is replaced by dilute HCl as a solvent in a hydrothermal system, BiOCl is also formed along with Bi2WO6, confirming the successful formation of a Bi2WO6-BiOCl composite. The flower-like hierarchical structures of Bi2WO6 and Bi2WO6-BiOCl can absorb more photon energy due to multiple scattering, charge carriers can easily transfer to the surface/interface, and mesopores can improve the transfer rate of organic molecules, contributing to the overall enhancement in photocatalytic activity. The Bi2WO6-BiOCl samples show higher photocatalytic activity than that of the Bi2WO6 samples for the degradation of salicylic acid due to the formed p–n heterojunction. The optimum concentration of Ce doping is found to be 1 mol% in the Bi2WO6 and Bi2WO6-BiOCl, promoting the effective separation and transfer of photogenerated charge carriers, resulting in high photocatalytic performance, and the sample exhibited good stability. |
publishDate |
2018 |
dc.date.none.fl_str_mv |
2018-07 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/86140 Hojamberdiev, Mirabbos; Kadirova, Zukhra C.; Zahedi, Ehsan; Onna, Diego Ariel; Marchi, María Claudia; et al.; Tuning the morphological structure, light absorption, and photocatalytic activity of Bi2WO6 and Bi2WO6-BiOCl through cerium doping; Elsevier; Arabian Journal of Chemistry; 11; 7-2018; 1-14 1878-5352 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/86140 |
identifier_str_mv |
Hojamberdiev, Mirabbos; Kadirova, Zukhra C.; Zahedi, Ehsan; Onna, Diego Ariel; Marchi, María Claudia; et al.; Tuning the morphological structure, light absorption, and photocatalytic activity of Bi2WO6 and Bi2WO6-BiOCl through cerium doping; Elsevier; Arabian Journal of Chemistry; 11; 7-2018; 1-14 1878-5352 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S187853521830162X info:eu-repo/semantics/altIdentifier/doi/10.1016/j.arabjc.2018.07.014 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
_version_ |
1844613637060165632 |
score |
13.070432 |