Volcano plots in hydrogen electrocatalysis: uses and abuses
- Autores
- Quaino, Paola Monica; Juarez, Maria Fernanda; Santos, Elizabeth del Carmen; Schmickler, Wolfgang
- Año de publicación
- 2014
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Sabatier’s principle suggests, that for hydrogen evolution a plot of the rate constant versus the hydrogen adsorption energy should result in a volcano, and several such plots have been presented in the literature. A thorough examination of the data shows, that there is no volcano once the oxide-covered metals are left out. We examine the factors that govern the reaction rate in the light of our own theory and conclude, that Sabatier’s principle is only one of several factors that determine the rate. With the exception of nickel and cobalt, the reaction rate does not decrease for highly exothermic hydrogen adsorption as predicted, because the reaction passes through more suitable intermediate states. The case of nickel is given special attention; since it is a 3d metal, its orbitals are compact and the overlap with hydrogen is too low to make it a good catalyst.
Fil: Quaino, Paola Monica. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Fil: Juarez, Maria Fernanda. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Institute of Theoretical Chemistry; Alemania. Universitat Ulm; Alemania
Fil: Santos, Elizabeth del Carmen. Institute of Theoretical Chemistry; Alemania. Universitat Ulm; Alemania. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina
Fil: Schmickler, Wolfgang. Institute of Theoretical Chemistry; Alemania. Universitat Ulm; Alemania - Materia
-
Electrocatalysis
Hydrogen evolution
Sabatier's principle
Volcano curve - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/31169
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Volcano plots in hydrogen electrocatalysis: uses and abusesQuaino, Paola MonicaJuarez, Maria FernandaSantos, Elizabeth del CarmenSchmickler, WolfgangElectrocatalysisHydrogen evolutionSabatier's principleVolcano curvehttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Sabatier’s principle suggests, that for hydrogen evolution a plot of the rate constant versus the hydrogen adsorption energy should result in a volcano, and several such plots have been presented in the literature. A thorough examination of the data shows, that there is no volcano once the oxide-covered metals are left out. We examine the factors that govern the reaction rate in the light of our own theory and conclude, that Sabatier’s principle is only one of several factors that determine the rate. With the exception of nickel and cobalt, the reaction rate does not decrease for highly exothermic hydrogen adsorption as predicted, because the reaction passes through more suitable intermediate states. The case of nickel is given special attention; since it is a 3d metal, its orbitals are compact and the overlap with hydrogen is too low to make it a good catalyst.Fil: Quaino, Paola Monica. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; ArgentinaFil: Juarez, Maria Fernanda. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Institute of Theoretical Chemistry; Alemania. Universitat Ulm; AlemaniaFil: Santos, Elizabeth del Carmen. Institute of Theoretical Chemistry; Alemania. Universitat Ulm; Alemania. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; ArgentinaFil: Schmickler, Wolfgang. Institute of Theoretical Chemistry; Alemania. Universitat Ulm; AlemaniaBeilstein-Institut2014-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/31169Schmickler, Wolfgang; Santos, Elizabeth del Carmen; Juarez, Maria Fernanda; Quaino, Paola Monica; Volcano plots in hydrogen electrocatalysis: uses and abuses; Beilstein-Institut; Beilstein Journal of Nanotechnology; 5; 6-2014; 846-8542190-4286CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.beilstein-journals.org/bjnano/articles/5/96info:eu-repo/semantics/altIdentifier/doi/10.3762/bjnano.5.96info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:10:05Zoai:ri.conicet.gov.ar:11336/31169instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:10:05.383CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Volcano plots in hydrogen electrocatalysis: uses and abuses |
title |
Volcano plots in hydrogen electrocatalysis: uses and abuses |
spellingShingle |
Volcano plots in hydrogen electrocatalysis: uses and abuses Quaino, Paola Monica Electrocatalysis Hydrogen evolution Sabatier's principle Volcano curve |
title_short |
Volcano plots in hydrogen electrocatalysis: uses and abuses |
title_full |
Volcano plots in hydrogen electrocatalysis: uses and abuses |
title_fullStr |
Volcano plots in hydrogen electrocatalysis: uses and abuses |
title_full_unstemmed |
Volcano plots in hydrogen electrocatalysis: uses and abuses |
title_sort |
Volcano plots in hydrogen electrocatalysis: uses and abuses |
dc.creator.none.fl_str_mv |
Quaino, Paola Monica Juarez, Maria Fernanda Santos, Elizabeth del Carmen Schmickler, Wolfgang |
author |
Quaino, Paola Monica |
author_facet |
Quaino, Paola Monica Juarez, Maria Fernanda Santos, Elizabeth del Carmen Schmickler, Wolfgang |
author_role |
author |
author2 |
Juarez, Maria Fernanda Santos, Elizabeth del Carmen Schmickler, Wolfgang |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
Electrocatalysis Hydrogen evolution Sabatier's principle Volcano curve |
topic |
Electrocatalysis Hydrogen evolution Sabatier's principle Volcano curve |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
Sabatier’s principle suggests, that for hydrogen evolution a plot of the rate constant versus the hydrogen adsorption energy should result in a volcano, and several such plots have been presented in the literature. A thorough examination of the data shows, that there is no volcano once the oxide-covered metals are left out. We examine the factors that govern the reaction rate in the light of our own theory and conclude, that Sabatier’s principle is only one of several factors that determine the rate. With the exception of nickel and cobalt, the reaction rate does not decrease for highly exothermic hydrogen adsorption as predicted, because the reaction passes through more suitable intermediate states. The case of nickel is given special attention; since it is a 3d metal, its orbitals are compact and the overlap with hydrogen is too low to make it a good catalyst. Fil: Quaino, Paola Monica. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina Fil: Juarez, Maria Fernanda. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Institute of Theoretical Chemistry; Alemania. Universitat Ulm; Alemania Fil: Santos, Elizabeth del Carmen. Institute of Theoretical Chemistry; Alemania. Universitat Ulm; Alemania. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina Fil: Schmickler, Wolfgang. Institute of Theoretical Chemistry; Alemania. Universitat Ulm; Alemania |
description |
Sabatier’s principle suggests, that for hydrogen evolution a plot of the rate constant versus the hydrogen adsorption energy should result in a volcano, and several such plots have been presented in the literature. A thorough examination of the data shows, that there is no volcano once the oxide-covered metals are left out. We examine the factors that govern the reaction rate in the light of our own theory and conclude, that Sabatier’s principle is only one of several factors that determine the rate. With the exception of nickel and cobalt, the reaction rate does not decrease for highly exothermic hydrogen adsorption as predicted, because the reaction passes through more suitable intermediate states. The case of nickel is given special attention; since it is a 3d metal, its orbitals are compact and the overlap with hydrogen is too low to make it a good catalyst. |
publishDate |
2014 |
dc.date.none.fl_str_mv |
2014-06 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/31169 Schmickler, Wolfgang; Santos, Elizabeth del Carmen; Juarez, Maria Fernanda; Quaino, Paola Monica; Volcano plots in hydrogen electrocatalysis: uses and abuses; Beilstein-Institut; Beilstein Journal of Nanotechnology; 5; 6-2014; 846-854 2190-4286 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/31169 |
identifier_str_mv |
Schmickler, Wolfgang; Santos, Elizabeth del Carmen; Juarez, Maria Fernanda; Quaino, Paola Monica; Volcano plots in hydrogen electrocatalysis: uses and abuses; Beilstein-Institut; Beilstein Journal of Nanotechnology; 5; 6-2014; 846-854 2190-4286 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://www.beilstein-journals.org/bjnano/articles/5/96 info:eu-repo/semantics/altIdentifier/doi/10.3762/bjnano.5.96 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Beilstein-Institut |
publisher.none.fl_str_mv |
Beilstein-Institut |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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13.13397 |