Gas transport in surface modified LDPE films with acrylic acid as grafting agent

Autores
Costamagna, Vanina; Strumia, Miriam Cristina; López González, Mar; Riande, Evaristo
Año de publicación
2006
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The modification of polyethylene by the grafting of poly(acrylic acid) onto the surface of one of the faces of low-density polyethylene films with UV radiation is reported. The transport of oxygen, nitrogen, carbon monoxide, carbon dioxide, methane, ethane, ethylene, propane, and argon across surface-modified films containing 3.7% poly(acrylic acid) has been investigated at several temperatures. The layer of poly(acrylic acid) grafted onto the surface of one of the faces of the films reduces the permeability coefficient of the gases by a factor of about 1/6. The sharp drop in the gas permeability as a result of the poly(acrylic acid) layer may arise either from the formation of ordered structures of the grafted chains or from the development of highly crosslinked structures. The values of the polymer–gas enthalpic interaction parameter for the modified film are higher than those for the unmodified one.
Fil: Costamagna, Vanina. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química Orgánica; Argentina
Fil: Strumia, Miriam Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto Multidisciplinario de Biología Vegetal. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Instituto Multidisciplinario de Biología Vegetal; Argentina. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química Orgánica; Argentina
Fil: López González, Mar. Consejo Superior de Investigaciones Científicas. Instituto de Ciencia y Tecnología de Polímeros; España
Fil: Riande, Evaristo. Consejo Superior de Investigaciones Científicas. Instituto de Ciencia y Tecnología de Polímeros; España
Materia
Diffusion
Gas Transport
Permeability
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/29235
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/29235
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Gas transport in surface modified LDPE films with acrylic acid as grafting agentCostamagna, VaninaStrumia, Miriam CristinaLópez González, MarRiande, EvaristoDiffusionGas TransportPermeabilityhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The modification of polyethylene by the grafting of poly(acrylic acid) onto the surface of one of the faces of low-density polyethylene films with UV radiation is reported. The transport of oxygen, nitrogen, carbon monoxide, carbon dioxide, methane, ethane, ethylene, propane, and argon across surface-modified films containing 3.7% poly(acrylic acid) has been investigated at several temperatures. The layer of poly(acrylic acid) grafted onto the surface of one of the faces of the films reduces the permeability coefficient of the gases by a factor of about 1/6. The sharp drop in the gas permeability as a result of the poly(acrylic acid) layer may arise either from the formation of ordered structures of the grafted chains or from the development of highly crosslinked structures. The values of the polymer–gas enthalpic interaction parameter for the modified film are higher than those for the unmodified one.Fil: Costamagna, Vanina. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química Orgánica; ArgentinaFil: Strumia, Miriam Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto Multidisciplinario de Biología Vegetal. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Instituto Multidisciplinario de Biología Vegetal; Argentina. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química Orgánica; ArgentinaFil: López González, Mar. Consejo Superior de Investigaciones Científicas. Instituto de Ciencia y Tecnología de Polímeros; EspañaFil: Riande, Evaristo. Consejo Superior de Investigaciones Científicas. Instituto de Ciencia y Tecnología de Polímeros; EspañaWiley Blackwell Publishing, Inc2006-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/29235Costamagna, Vanina; Strumia, Miriam Cristina; López González, Mar; Riande, Evaristo; Gas transport in surface modified LDPE films with acrylic acid as grafting agent; Wiley Blackwell Publishing, Inc; Journal Polymer Science. Part B: Polymer Physics; 44; 19; 12-2006; 2828-28400887-62661099-0488CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/polb.20945/abstractinfo:eu-repo/semantics/altIdentifier/doi/10.1002/polb.20945info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:44:47Zoai:ri.conicet.gov.ar:11336/29235instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:44:48.075CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Gas transport in surface modified LDPE films with acrylic acid as grafting agent
title Gas transport in surface modified LDPE films with acrylic acid as grafting agent
spellingShingle Gas transport in surface modified LDPE films with acrylic acid as grafting agent
Costamagna, Vanina
Diffusion
Gas Transport
Permeability
title_short Gas transport in surface modified LDPE films with acrylic acid as grafting agent
title_full Gas transport in surface modified LDPE films with acrylic acid as grafting agent
title_fullStr Gas transport in surface modified LDPE films with acrylic acid as grafting agent
title_full_unstemmed Gas transport in surface modified LDPE films with acrylic acid as grafting agent
title_sort Gas transport in surface modified LDPE films with acrylic acid as grafting agent
dc.creator.none.fl_str_mv Costamagna, Vanina
Strumia, Miriam Cristina
López González, Mar
Riande, Evaristo
author Costamagna, Vanina
author_facet Costamagna, Vanina
Strumia, Miriam Cristina
López González, Mar
Riande, Evaristo
author_role author
author2 Strumia, Miriam Cristina
López González, Mar
Riande, Evaristo
author2_role author
author
author
dc.subject.none.fl_str_mv Diffusion
Gas Transport
Permeability
topic Diffusion
Gas Transport
Permeability
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The modification of polyethylene by the grafting of poly(acrylic acid) onto the surface of one of the faces of low-density polyethylene films with UV radiation is reported. The transport of oxygen, nitrogen, carbon monoxide, carbon dioxide, methane, ethane, ethylene, propane, and argon across surface-modified films containing 3.7% poly(acrylic acid) has been investigated at several temperatures. The layer of poly(acrylic acid) grafted onto the surface of one of the faces of the films reduces the permeability coefficient of the gases by a factor of about 1/6. The sharp drop in the gas permeability as a result of the poly(acrylic acid) layer may arise either from the formation of ordered structures of the grafted chains or from the development of highly crosslinked structures. The values of the polymer–gas enthalpic interaction parameter for the modified film are higher than those for the unmodified one.
Fil: Costamagna, Vanina. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química Orgánica; Argentina
Fil: Strumia, Miriam Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto Multidisciplinario de Biología Vegetal. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Instituto Multidisciplinario de Biología Vegetal; Argentina. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química Orgánica; Argentina
Fil: López González, Mar. Consejo Superior de Investigaciones Científicas. Instituto de Ciencia y Tecnología de Polímeros; España
Fil: Riande, Evaristo. Consejo Superior de Investigaciones Científicas. Instituto de Ciencia y Tecnología de Polímeros; España
description The modification of polyethylene by the grafting of poly(acrylic acid) onto the surface of one of the faces of low-density polyethylene films with UV radiation is reported. The transport of oxygen, nitrogen, carbon monoxide, carbon dioxide, methane, ethane, ethylene, propane, and argon across surface-modified films containing 3.7% poly(acrylic acid) has been investigated at several temperatures. The layer of poly(acrylic acid) grafted onto the surface of one of the faces of the films reduces the permeability coefficient of the gases by a factor of about 1/6. The sharp drop in the gas permeability as a result of the poly(acrylic acid) layer may arise either from the formation of ordered structures of the grafted chains or from the development of highly crosslinked structures. The values of the polymer–gas enthalpic interaction parameter for the modified film are higher than those for the unmodified one.
publishDate 2006
dc.date.none.fl_str_mv 2006-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/29235
Costamagna, Vanina; Strumia, Miriam Cristina; López González, Mar; Riande, Evaristo; Gas transport in surface modified LDPE films with acrylic acid as grafting agent; Wiley Blackwell Publishing, Inc; Journal Polymer Science. Part B: Polymer Physics; 44; 19; 12-2006; 2828-2840
0887-6266
1099-0488
CONICET Digital
CONICET
url http://hdl.handle.net/11336/29235
identifier_str_mv Costamagna, Vanina; Strumia, Miriam Cristina; López González, Mar; Riande, Evaristo; Gas transport in surface modified LDPE films with acrylic acid as grafting agent; Wiley Blackwell Publishing, Inc; Journal Polymer Science. Part B: Polymer Physics; 44; 19; 12-2006; 2828-2840
0887-6266
1099-0488
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/polb.20945/abstract
info:eu-repo/semantics/altIdentifier/doi/10.1002/polb.20945
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley Blackwell Publishing, Inc
publisher.none.fl_str_mv Wiley Blackwell Publishing, Inc
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.069144

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