Gas transport in surface modified LDPE films with acrylic acid as grafting agent
- Autores
- Costamagna, Vanina; Strumia, Miriam Cristina; López González, Mar; Riande, Evaristo
- Año de publicación
- 2006
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The modification of polyethylene by the grafting of poly(acrylic acid) onto the surface of one of the faces of low-density polyethylene films with UV radiation is reported. The transport of oxygen, nitrogen, carbon monoxide, carbon dioxide, methane, ethane, ethylene, propane, and argon across surface-modified films containing 3.7% poly(acrylic acid) has been investigated at several temperatures. The layer of poly(acrylic acid) grafted onto the surface of one of the faces of the films reduces the permeability coefficient of the gases by a factor of about 1/6. The sharp drop in the gas permeability as a result of the poly(acrylic acid) layer may arise either from the formation of ordered structures of the grafted chains or from the development of highly crosslinked structures. The values of the polymer–gas enthalpic interaction parameter for the modified film are higher than those for the unmodified one.
Fil: Costamagna, Vanina. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química Orgánica; Argentina
Fil: Strumia, Miriam Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto Multidisciplinario de Biología Vegetal. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Instituto Multidisciplinario de Biología Vegetal; Argentina. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química Orgánica; Argentina
Fil: López González, Mar. Consejo Superior de Investigaciones Científicas. Instituto de Ciencia y Tecnología de Polímeros; España
Fil: Riande, Evaristo. Consejo Superior de Investigaciones Científicas. Instituto de Ciencia y Tecnología de Polímeros; España - Materia
-
Diffusion
Gas Transport
Permeability - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/29235
Ver los metadatos del registro completo
id |
CONICETDig_cb1f2c8cae8b643ac886c6e508145199 |
---|---|
oai_identifier_str |
oai:ri.conicet.gov.ar:11336/29235 |
network_acronym_str |
CONICETDig |
repository_id_str |
3498 |
network_name_str |
CONICET Digital (CONICET) |
spelling |
Gas transport in surface modified LDPE films with acrylic acid as grafting agentCostamagna, VaninaStrumia, Miriam CristinaLópez González, MarRiande, EvaristoDiffusionGas TransportPermeabilityhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The modification of polyethylene by the grafting of poly(acrylic acid) onto the surface of one of the faces of low-density polyethylene films with UV radiation is reported. The transport of oxygen, nitrogen, carbon monoxide, carbon dioxide, methane, ethane, ethylene, propane, and argon across surface-modified films containing 3.7% poly(acrylic acid) has been investigated at several temperatures. The layer of poly(acrylic acid) grafted onto the surface of one of the faces of the films reduces the permeability coefficient of the gases by a factor of about 1/6. The sharp drop in the gas permeability as a result of the poly(acrylic acid) layer may arise either from the formation of ordered structures of the grafted chains or from the development of highly crosslinked structures. The values of the polymer–gas enthalpic interaction parameter for the modified film are higher than those for the unmodified one.Fil: Costamagna, Vanina. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química Orgánica; ArgentinaFil: Strumia, Miriam Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto Multidisciplinario de Biología Vegetal. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Instituto Multidisciplinario de Biología Vegetal; Argentina. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química Orgánica; ArgentinaFil: López González, Mar. Consejo Superior de Investigaciones Científicas. Instituto de Ciencia y Tecnología de Polímeros; EspañaFil: Riande, Evaristo. Consejo Superior de Investigaciones Científicas. Instituto de Ciencia y Tecnología de Polímeros; EspañaWiley Blackwell Publishing, Inc2006-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/29235Costamagna, Vanina; Strumia, Miriam Cristina; López González, Mar; Riande, Evaristo; Gas transport in surface modified LDPE films with acrylic acid as grafting agent; Wiley Blackwell Publishing, Inc; Journal Polymer Science. Part B: Polymer Physics; 44; 19; 12-2006; 2828-28400887-62661099-0488CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/polb.20945/abstractinfo:eu-repo/semantics/altIdentifier/doi/10.1002/polb.20945info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:50:11Zoai:ri.conicet.gov.ar:11336/29235instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:50:11.977CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Gas transport in surface modified LDPE films with acrylic acid as grafting agent |
title |
Gas transport in surface modified LDPE films with acrylic acid as grafting agent |
spellingShingle |
Gas transport in surface modified LDPE films with acrylic acid as grafting agent Costamagna, Vanina Diffusion Gas Transport Permeability |
title_short |
Gas transport in surface modified LDPE films with acrylic acid as grafting agent |
title_full |
Gas transport in surface modified LDPE films with acrylic acid as grafting agent |
title_fullStr |
Gas transport in surface modified LDPE films with acrylic acid as grafting agent |
title_full_unstemmed |
Gas transport in surface modified LDPE films with acrylic acid as grafting agent |
title_sort |
Gas transport in surface modified LDPE films with acrylic acid as grafting agent |
dc.creator.none.fl_str_mv |
Costamagna, Vanina Strumia, Miriam Cristina López González, Mar Riande, Evaristo |
author |
Costamagna, Vanina |
author_facet |
Costamagna, Vanina Strumia, Miriam Cristina López González, Mar Riande, Evaristo |
author_role |
author |
author2 |
Strumia, Miriam Cristina López González, Mar Riande, Evaristo |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
Diffusion Gas Transport Permeability |
topic |
Diffusion Gas Transport Permeability |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
The modification of polyethylene by the grafting of poly(acrylic acid) onto the surface of one of the faces of low-density polyethylene films with UV radiation is reported. The transport of oxygen, nitrogen, carbon monoxide, carbon dioxide, methane, ethane, ethylene, propane, and argon across surface-modified films containing 3.7% poly(acrylic acid) has been investigated at several temperatures. The layer of poly(acrylic acid) grafted onto the surface of one of the faces of the films reduces the permeability coefficient of the gases by a factor of about 1/6. The sharp drop in the gas permeability as a result of the poly(acrylic acid) layer may arise either from the formation of ordered structures of the grafted chains or from the development of highly crosslinked structures. The values of the polymer–gas enthalpic interaction parameter for the modified film are higher than those for the unmodified one. Fil: Costamagna, Vanina. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química Orgánica; Argentina Fil: Strumia, Miriam Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto Multidisciplinario de Biología Vegetal. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Instituto Multidisciplinario de Biología Vegetal; Argentina. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química Orgánica; Argentina Fil: López González, Mar. Consejo Superior de Investigaciones Científicas. Instituto de Ciencia y Tecnología de Polímeros; España Fil: Riande, Evaristo. Consejo Superior de Investigaciones Científicas. Instituto de Ciencia y Tecnología de Polímeros; España |
description |
The modification of polyethylene by the grafting of poly(acrylic acid) onto the surface of one of the faces of low-density polyethylene films with UV radiation is reported. The transport of oxygen, nitrogen, carbon monoxide, carbon dioxide, methane, ethane, ethylene, propane, and argon across surface-modified films containing 3.7% poly(acrylic acid) has been investigated at several temperatures. The layer of poly(acrylic acid) grafted onto the surface of one of the faces of the films reduces the permeability coefficient of the gases by a factor of about 1/6. The sharp drop in the gas permeability as a result of the poly(acrylic acid) layer may arise either from the formation of ordered structures of the grafted chains or from the development of highly crosslinked structures. The values of the polymer–gas enthalpic interaction parameter for the modified film are higher than those for the unmodified one. |
publishDate |
2006 |
dc.date.none.fl_str_mv |
2006-12 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/29235 Costamagna, Vanina; Strumia, Miriam Cristina; López González, Mar; Riande, Evaristo; Gas transport in surface modified LDPE films with acrylic acid as grafting agent; Wiley Blackwell Publishing, Inc; Journal Polymer Science. Part B: Polymer Physics; 44; 19; 12-2006; 2828-2840 0887-6266 1099-0488 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/29235 |
identifier_str_mv |
Costamagna, Vanina; Strumia, Miriam Cristina; López González, Mar; Riande, Evaristo; Gas transport in surface modified LDPE films with acrylic acid as grafting agent; Wiley Blackwell Publishing, Inc; Journal Polymer Science. Part B: Polymer Physics; 44; 19; 12-2006; 2828-2840 0887-6266 1099-0488 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/polb.20945/abstract info:eu-repo/semantics/altIdentifier/doi/10.1002/polb.20945 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Wiley Blackwell Publishing, Inc |
publisher.none.fl_str_mv |
Wiley Blackwell Publishing, Inc |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
_version_ |
1842269018674692096 |
score |
13.13397 |