Electrically conductive composites of polyurethane derived from castor oil with polypyrrole-coated peach palm fibers

Autores
Merlini, Claudia; Barra, Guilherme M. O.; Popov Pereira Da Cunha, Matthäus Davi; Ramôa, Sílvia D.A.S.; Soares, Bluma G.; Pegoretti, Alessandro
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Electrically conducting fibers were prepared through in situ oxidative polymerization of pyrrole (Py) in the presence of peach palm fibers (PPF) using iron (III) chloride hexahydrate (FeCl3·6H2O) as oxidant. The polypyrrole (PPy) coated PPF displayed a PPy layer on the fibers surface, which was responsible for an electrical conductivity of (2.2 ± 0.3) × 10−1 S cm−1, similar to the neat PPy. Electrically conductive composites were prepared by dispersing various amounts of PPy-coated PPF in a polyurethane matrix derived from castor oil. The polyurethane/PPy-coated PPF composites (PU/PPF–PPy) exhibited an electrical conductivity higher than PU/PPy blends with similar filler content. This behavior is attributed to the higher aspect ratio of PPF–PPy when compared with PPy particles, inducing a denser conductive network formation in the PU matrix. Electromagnetic interference shielding effectiveness (EMI SE) value in the X-band (8.2–12.4 GHz) found for PU/PPF–PPy composites containing 25 wt% of PPF–PPy were in the range −12 dB, which corresponds to 93.2% of attenuation, indicating that these composites are promising candidates for EMI shielding applications.
Fil: Merlini, Claudia. Universidade Federal de Santa Catarina; Brasil
Fil: Barra, Guilherme M. O.. Universidade Federal de Santa Catarina; Brasil
Fil: Popov Pereira Da Cunha, Matthäus Davi. Universidade Federal de Santa Catarina; Brasil. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Ramôa, Sílvia D.A.S.. Universidade Federal de Santa Catarina; Brasil
Fil: Soares, Bluma G.. Universidade Federal do Rio de Janeiro; Brasil
Fil: Pegoretti, Alessandro. Universita degli Studi di Trento; Italia
Materia
Peach palm fiber
Polypirrole
Polyurethane
Castor oil
Composite
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/210510
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Electrically conductive composites of polyurethane derived from castor oil with polypyrrole-coated peach palm fibersMerlini, ClaudiaBarra, Guilherme M. O.Popov Pereira Da Cunha, Matthäus DaviRamôa, Sílvia D.A.S.Soares, Bluma G.Pegoretti, AlessandroPeach palm fiberPolypirrolePolyurethaneCastor oilCompositehttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Electrically conducting fibers were prepared through in situ oxidative polymerization of pyrrole (Py) in the presence of peach palm fibers (PPF) using iron (III) chloride hexahydrate (FeCl3·6H2O) as oxidant. The polypyrrole (PPy) coated PPF displayed a PPy layer on the fibers surface, which was responsible for an electrical conductivity of (2.2 ± 0.3) × 10−1 S cm−1, similar to the neat PPy. Electrically conductive composites were prepared by dispersing various amounts of PPy-coated PPF in a polyurethane matrix derived from castor oil. The polyurethane/PPy-coated PPF composites (PU/PPF–PPy) exhibited an electrical conductivity higher than PU/PPy blends with similar filler content. This behavior is attributed to the higher aspect ratio of PPF–PPy when compared with PPy particles, inducing a denser conductive network formation in the PU matrix. Electromagnetic interference shielding effectiveness (EMI SE) value in the X-band (8.2–12.4 GHz) found for PU/PPF–PPy composites containing 25 wt% of PPF–PPy were in the range −12 dB, which corresponds to 93.2% of attenuation, indicating that these composites are promising candidates for EMI shielding applications.Fil: Merlini, Claudia. Universidade Federal de Santa Catarina; BrasilFil: Barra, Guilherme M. O.. Universidade Federal de Santa Catarina; BrasilFil: Popov Pereira Da Cunha, Matthäus Davi. Universidade Federal de Santa Catarina; Brasil. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Ramôa, Sílvia D.A.S.. Universidade Federal de Santa Catarina; BrasilFil: Soares, Bluma G.. Universidade Federal do Rio de Janeiro; BrasilFil: Pegoretti, Alessandro. Universita degli Studi di Trento; ItaliaJohn Wiley & Sons2017-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/210510Merlini, Claudia; Barra, Guilherme M. O.; Popov Pereira Da Cunha, Matthäus Davi; Ramôa, Sílvia D.A.S.; Soares, Bluma G.; et al.; Electrically conductive composites of polyurethane derived from castor oil with polypyrrole-coated peach palm fibers; John Wiley & Sons; Polymer Composites; 38; 10; 10-2017; 2146-21550272-8397CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1002/pc.23790info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:38:36Zoai:ri.conicet.gov.ar:11336/210510instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:38:37.22CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Electrically conductive composites of polyurethane derived from castor oil with polypyrrole-coated peach palm fibers
title Electrically conductive composites of polyurethane derived from castor oil with polypyrrole-coated peach palm fibers
spellingShingle Electrically conductive composites of polyurethane derived from castor oil with polypyrrole-coated peach palm fibers
Merlini, Claudia
Peach palm fiber
Polypirrole
Polyurethane
Castor oil
Composite
title_short Electrically conductive composites of polyurethane derived from castor oil with polypyrrole-coated peach palm fibers
title_full Electrically conductive composites of polyurethane derived from castor oil with polypyrrole-coated peach palm fibers
title_fullStr Electrically conductive composites of polyurethane derived from castor oil with polypyrrole-coated peach palm fibers
title_full_unstemmed Electrically conductive composites of polyurethane derived from castor oil with polypyrrole-coated peach palm fibers
title_sort Electrically conductive composites of polyurethane derived from castor oil with polypyrrole-coated peach palm fibers
dc.creator.none.fl_str_mv Merlini, Claudia
Barra, Guilherme M. O.
Popov Pereira Da Cunha, Matthäus Davi
Ramôa, Sílvia D.A.S.
Soares, Bluma G.
Pegoretti, Alessandro
author Merlini, Claudia
author_facet Merlini, Claudia
Barra, Guilherme M. O.
Popov Pereira Da Cunha, Matthäus Davi
Ramôa, Sílvia D.A.S.
Soares, Bluma G.
Pegoretti, Alessandro
author_role author
author2 Barra, Guilherme M. O.
Popov Pereira Da Cunha, Matthäus Davi
Ramôa, Sílvia D.A.S.
Soares, Bluma G.
Pegoretti, Alessandro
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Peach palm fiber
Polypirrole
Polyurethane
Castor oil
Composite
topic Peach palm fiber
Polypirrole
Polyurethane
Castor oil
Composite
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Electrically conducting fibers were prepared through in situ oxidative polymerization of pyrrole (Py) in the presence of peach palm fibers (PPF) using iron (III) chloride hexahydrate (FeCl3·6H2O) as oxidant. The polypyrrole (PPy) coated PPF displayed a PPy layer on the fibers surface, which was responsible for an electrical conductivity of (2.2 ± 0.3) × 10−1 S cm−1, similar to the neat PPy. Electrically conductive composites were prepared by dispersing various amounts of PPy-coated PPF in a polyurethane matrix derived from castor oil. The polyurethane/PPy-coated PPF composites (PU/PPF–PPy) exhibited an electrical conductivity higher than PU/PPy blends with similar filler content. This behavior is attributed to the higher aspect ratio of PPF–PPy when compared with PPy particles, inducing a denser conductive network formation in the PU matrix. Electromagnetic interference shielding effectiveness (EMI SE) value in the X-band (8.2–12.4 GHz) found for PU/PPF–PPy composites containing 25 wt% of PPF–PPy were in the range −12 dB, which corresponds to 93.2% of attenuation, indicating that these composites are promising candidates for EMI shielding applications.
Fil: Merlini, Claudia. Universidade Federal de Santa Catarina; Brasil
Fil: Barra, Guilherme M. O.. Universidade Federal de Santa Catarina; Brasil
Fil: Popov Pereira Da Cunha, Matthäus Davi. Universidade Federal de Santa Catarina; Brasil. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Ramôa, Sílvia D.A.S.. Universidade Federal de Santa Catarina; Brasil
Fil: Soares, Bluma G.. Universidade Federal do Rio de Janeiro; Brasil
Fil: Pegoretti, Alessandro. Universita degli Studi di Trento; Italia
description Electrically conducting fibers were prepared through in situ oxidative polymerization of pyrrole (Py) in the presence of peach palm fibers (PPF) using iron (III) chloride hexahydrate (FeCl3·6H2O) as oxidant. The polypyrrole (PPy) coated PPF displayed a PPy layer on the fibers surface, which was responsible for an electrical conductivity of (2.2 ± 0.3) × 10−1 S cm−1, similar to the neat PPy. Electrically conductive composites were prepared by dispersing various amounts of PPy-coated PPF in a polyurethane matrix derived from castor oil. The polyurethane/PPy-coated PPF composites (PU/PPF–PPy) exhibited an electrical conductivity higher than PU/PPy blends with similar filler content. This behavior is attributed to the higher aspect ratio of PPF–PPy when compared with PPy particles, inducing a denser conductive network formation in the PU matrix. Electromagnetic interference shielding effectiveness (EMI SE) value in the X-band (8.2–12.4 GHz) found for PU/PPF–PPy composites containing 25 wt% of PPF–PPy were in the range −12 dB, which corresponds to 93.2% of attenuation, indicating that these composites are promising candidates for EMI shielding applications.
publishDate 2017
dc.date.none.fl_str_mv 2017-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/210510
Merlini, Claudia; Barra, Guilherme M. O.; Popov Pereira Da Cunha, Matthäus Davi; Ramôa, Sílvia D.A.S.; Soares, Bluma G.; et al.; Electrically conductive composites of polyurethane derived from castor oil with polypyrrole-coated peach palm fibers; John Wiley & Sons; Polymer Composites; 38; 10; 10-2017; 2146-2155
0272-8397
CONICET Digital
CONICET
url http://hdl.handle.net/11336/210510
identifier_str_mv Merlini, Claudia; Barra, Guilherme M. O.; Popov Pereira Da Cunha, Matthäus Davi; Ramôa, Sílvia D.A.S.; Soares, Bluma G.; et al.; Electrically conductive composites of polyurethane derived from castor oil with polypyrrole-coated peach palm fibers; John Wiley & Sons; Polymer Composites; 38; 10; 10-2017; 2146-2155
0272-8397
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1002/pc.23790
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv John Wiley & Sons
publisher.none.fl_str_mv John Wiley & Sons
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844613221047074816
score 13.070432

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