Hydrogen evolution reaction at lead/carbon porous electrodes studied by a novel electrochemical mass spectrometry set-up

Autores
Mondino, Tomas Miguel; García, Gonzalo; Pastor, Elena; Fungo, Fernando Gabriel; Planes, Gabriel Angel
Año de publicación
2022
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Lead–acid batteries are robust, low-cost, and have a large power-to-weight ratio. Recently, small amounts of carbon-based materials with a high surface area have been included in the Pb electrode as additives to improve the high-rate partial state of charge. However, carbon-based materials also enhance the hydrogen evolution reaction during the charging process at the negative active material (NAM), which is undesirable and dangerous. Therefore, in the current communication, a promising differential electrochemical mass spectrometry (DEMS) set-up suitable for studying the hydrogen evolution reaction (HER) at technical NAM electrodes in lead–acid batteries (LABs) is reported for the first time.
Fil: Mondino, Tomas Miguel. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Instituto de Investigaciones en Tecnologías Energéticas y Materiales Avanzados. - Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Tecnologías Energéticas y Materiales Avanzados; Argentina
Fil: García, Gonzalo. Universidad de La Laguna; España
Fil: Pastor, Elena. Universidad de La Laguna; España
Fil: Fungo, Fernando Gabriel. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Instituto de Investigaciones en Tecnologías Energéticas y Materiales Avanzados. - Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Tecnologías Energéticas y Materiales Avanzados; Argentina
Fil: Planes, Gabriel Angel. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Instituto de Investigaciones en Tecnologías Energéticas y Materiales Avanzados. - Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Tecnologías Energéticas y Materiales Avanzados; Argentina
Materia
ADDITIVE
DIFFERENTIAL ELECTROCHEMICAL MASS SPECTROMETRY
HYDROGEN EVOLUTION REACTION
LEAD–ACID BATTERY
LEAD–CARBON ANODE
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/223324
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Hydrogen evolution reaction at lead/carbon porous electrodes studied by a novel electrochemical mass spectrometry set-upMondino, Tomas MiguelGarcía, GonzaloPastor, ElenaFungo, Fernando GabrielPlanes, Gabriel AngelADDITIVEDIFFERENTIAL ELECTROCHEMICAL MASS SPECTROMETRYHYDROGEN EVOLUTION REACTIONLEAD–ACID BATTERYLEAD–CARBON ANODEhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Lead–acid batteries are robust, low-cost, and have a large power-to-weight ratio. Recently, small amounts of carbon-based materials with a high surface area have been included in the Pb electrode as additives to improve the high-rate partial state of charge. However, carbon-based materials also enhance the hydrogen evolution reaction during the charging process at the negative active material (NAM), which is undesirable and dangerous. Therefore, in the current communication, a promising differential electrochemical mass spectrometry (DEMS) set-up suitable for studying the hydrogen evolution reaction (HER) at technical NAM electrodes in lead–acid batteries (LABs) is reported for the first time.Fil: Mondino, Tomas Miguel. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Instituto de Investigaciones en Tecnologías Energéticas y Materiales Avanzados. - Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Tecnologías Energéticas y Materiales Avanzados; ArgentinaFil: García, Gonzalo. Universidad de La Laguna; EspañaFil: Pastor, Elena. Universidad de La Laguna; EspañaFil: Fungo, Fernando Gabriel. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Instituto de Investigaciones en Tecnologías Energéticas y Materiales Avanzados. - Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Tecnologías Energéticas y Materiales Avanzados; ArgentinaFil: Planes, Gabriel Angel. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Instituto de Investigaciones en Tecnologías Energéticas y Materiales Avanzados. - Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Tecnologías Energéticas y Materiales Avanzados; ArgentinaElsevier Science Inc.2022-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/223324Mondino, Tomas Miguel; García, Gonzalo; Pastor, Elena; Fungo, Fernando Gabriel; Planes, Gabriel Angel; Hydrogen evolution reaction at lead/carbon porous electrodes studied by a novel electrochemical mass spectrometry set-up; Elsevier Science Inc.; Electrochemistry Communications; 143; 11-2022; 107393-1079391388-2481CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.elecom.2022.107393info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-11-12T09:33:09Zoai:ri.conicet.gov.ar:11336/223324instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-11-12 09:33:10.169CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Hydrogen evolution reaction at lead/carbon porous electrodes studied by a novel electrochemical mass spectrometry set-up
title Hydrogen evolution reaction at lead/carbon porous electrodes studied by a novel electrochemical mass spectrometry set-up
spellingShingle Hydrogen evolution reaction at lead/carbon porous electrodes studied by a novel electrochemical mass spectrometry set-up
Mondino, Tomas Miguel
ADDITIVE
DIFFERENTIAL ELECTROCHEMICAL MASS SPECTROMETRY
HYDROGEN EVOLUTION REACTION
LEAD–ACID BATTERY
LEAD–CARBON ANODE
title_short Hydrogen evolution reaction at lead/carbon porous electrodes studied by a novel electrochemical mass spectrometry set-up
title_full Hydrogen evolution reaction at lead/carbon porous electrodes studied by a novel electrochemical mass spectrometry set-up
title_fullStr Hydrogen evolution reaction at lead/carbon porous electrodes studied by a novel electrochemical mass spectrometry set-up
title_full_unstemmed Hydrogen evolution reaction at lead/carbon porous electrodes studied by a novel electrochemical mass spectrometry set-up
title_sort Hydrogen evolution reaction at lead/carbon porous electrodes studied by a novel electrochemical mass spectrometry set-up
dc.creator.none.fl_str_mv Mondino, Tomas Miguel
García, Gonzalo
Pastor, Elena
Fungo, Fernando Gabriel
Planes, Gabriel Angel
author Mondino, Tomas Miguel
author_facet Mondino, Tomas Miguel
García, Gonzalo
Pastor, Elena
Fungo, Fernando Gabriel
Planes, Gabriel Angel
author_role author
author2 García, Gonzalo
Pastor, Elena
Fungo, Fernando Gabriel
Planes, Gabriel Angel
author2_role author
author
author
author
dc.subject.none.fl_str_mv ADDITIVE
DIFFERENTIAL ELECTROCHEMICAL MASS SPECTROMETRY
HYDROGEN EVOLUTION REACTION
LEAD–ACID BATTERY
LEAD–CARBON ANODE
topic ADDITIVE
DIFFERENTIAL ELECTROCHEMICAL MASS SPECTROMETRY
HYDROGEN EVOLUTION REACTION
LEAD–ACID BATTERY
LEAD–CARBON ANODE
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Lead–acid batteries are robust, low-cost, and have a large power-to-weight ratio. Recently, small amounts of carbon-based materials with a high surface area have been included in the Pb electrode as additives to improve the high-rate partial state of charge. However, carbon-based materials also enhance the hydrogen evolution reaction during the charging process at the negative active material (NAM), which is undesirable and dangerous. Therefore, in the current communication, a promising differential electrochemical mass spectrometry (DEMS) set-up suitable for studying the hydrogen evolution reaction (HER) at technical NAM electrodes in lead–acid batteries (LABs) is reported for the first time.
Fil: Mondino, Tomas Miguel. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Instituto de Investigaciones en Tecnologías Energéticas y Materiales Avanzados. - Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Tecnologías Energéticas y Materiales Avanzados; Argentina
Fil: García, Gonzalo. Universidad de La Laguna; España
Fil: Pastor, Elena. Universidad de La Laguna; España
Fil: Fungo, Fernando Gabriel. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Instituto de Investigaciones en Tecnologías Energéticas y Materiales Avanzados. - Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Tecnologías Energéticas y Materiales Avanzados; Argentina
Fil: Planes, Gabriel Angel. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Instituto de Investigaciones en Tecnologías Energéticas y Materiales Avanzados. - Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Tecnologías Energéticas y Materiales Avanzados; Argentina
description Lead–acid batteries are robust, low-cost, and have a large power-to-weight ratio. Recently, small amounts of carbon-based materials with a high surface area have been included in the Pb electrode as additives to improve the high-rate partial state of charge. However, carbon-based materials also enhance the hydrogen evolution reaction during the charging process at the negative active material (NAM), which is undesirable and dangerous. Therefore, in the current communication, a promising differential electrochemical mass spectrometry (DEMS) set-up suitable for studying the hydrogen evolution reaction (HER) at technical NAM electrodes in lead–acid batteries (LABs) is reported for the first time.
publishDate 2022
dc.date.none.fl_str_mv 2022-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/223324
Mondino, Tomas Miguel; García, Gonzalo; Pastor, Elena; Fungo, Fernando Gabriel; Planes, Gabriel Angel; Hydrogen evolution reaction at lead/carbon porous electrodes studied by a novel electrochemical mass spectrometry set-up; Elsevier Science Inc.; Electrochemistry Communications; 143; 11-2022; 107393-107939
1388-2481
CONICET Digital
CONICET
url http://hdl.handle.net/11336/223324
identifier_str_mv Mondino, Tomas Miguel; García, Gonzalo; Pastor, Elena; Fungo, Fernando Gabriel; Planes, Gabriel Angel; Hydrogen evolution reaction at lead/carbon porous electrodes studied by a novel electrochemical mass spectrometry set-up; Elsevier Science Inc.; Electrochemistry Communications; 143; 11-2022; 107393-107939
1388-2481
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.elecom.2022.107393
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science Inc.
publisher.none.fl_str_mv Elsevier Science Inc.
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1848597035753668608
score 13.24909

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