Catalytic palladium-based and iron-based membrane reactors: Novel strategies of synthesis

Autores
Pinos-Vélez, Verónica; Di Luca, Carla; Crivoi, Dana G.; Medina, Francisco; Dafinov, Anton
Año de publicación
2019
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Several procedures were employed in the preparation of different Pd- and Fe-based catalytic membrane reactors (CMRs) via the normal wet impregnation method, reverse filtration of a microemulsion, sputtering method, and the precipitation of a Fe complex. Depending on the chosen procedure, the metal active phase can be found on the exterior and/or interior part of the CMR or even in its pores in concentrations between 0.05 and 2 wt %. Moreover, we have managed to implement a unique systematic process to grow hydrotalcite in the pores of a Pd-CMR. To exemplify the activity of these new CMRs, we have tested them in the peroxidation of phenol and in situ epoxidation of trans-chalcone.
Fil: Pinos-Vélez, Verónica. Universitat Rovira I Virgili; España
Fil: Di Luca, Carla. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Crivoi, Dana G.. Universitat Rovira I Virgili; España
Fil: Medina, Francisco. Universitat Rovira I Virgili; España
Fil: Dafinov, Anton. Universitat Rovira I Virgili; España
Materia
Catalytic membrane reactors
Synthesisi strategies
CWPO
Palladium and iron
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/121291
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Catalytic palladium-based and iron-based membrane reactors: Novel strategies of synthesisPinos-Vélez, VerónicaDi Luca, CarlaCrivoi, Dana G.Medina, FranciscoDafinov, AntonCatalytic membrane reactorsSynthesisi strategiesCWPOPalladium and ironhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Several procedures were employed in the preparation of different Pd- and Fe-based catalytic membrane reactors (CMRs) via the normal wet impregnation method, reverse filtration of a microemulsion, sputtering method, and the precipitation of a Fe complex. Depending on the chosen procedure, the metal active phase can be found on the exterior and/or interior part of the CMR or even in its pores in concentrations between 0.05 and 2 wt %. Moreover, we have managed to implement a unique systematic process to grow hydrotalcite in the pores of a Pd-CMR. To exemplify the activity of these new CMRs, we have tested them in the peroxidation of phenol and in situ epoxidation of trans-chalcone.Fil: Pinos-Vélez, Verónica. Universitat Rovira I Virgili; EspañaFil: Di Luca, Carla. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Crivoi, Dana G.. Universitat Rovira I Virgili; EspañaFil: Medina, Francisco. Universitat Rovira I Virgili; EspañaFil: Dafinov, Anton. Universitat Rovira I Virgili; EspañaAmerican Chemical Society2019-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/121291Pinos-Vélez, Verónica; Di Luca, Carla; Crivoi, Dana G.; Medina, Francisco; Dafinov, Anton; Catalytic palladium-based and iron-based membrane reactors: Novel strategies of synthesis; American Chemical Society; ACS Omega; 4; 22; 11-2019; 19818-198282470-1343CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acsomega.9b02706info:eu-repo/semantics/altIdentifier/doi/10.1021/acsomega.9b02706info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-11-12T09:45:31Zoai:ri.conicet.gov.ar:11336/121291instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-11-12 09:45:31.746CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Catalytic palladium-based and iron-based membrane reactors: Novel strategies of synthesis
title Catalytic palladium-based and iron-based membrane reactors: Novel strategies of synthesis
spellingShingle Catalytic palladium-based and iron-based membrane reactors: Novel strategies of synthesis
Pinos-Vélez, Verónica
Catalytic membrane reactors
Synthesisi strategies
CWPO
Palladium and iron
title_short Catalytic palladium-based and iron-based membrane reactors: Novel strategies of synthesis
title_full Catalytic palladium-based and iron-based membrane reactors: Novel strategies of synthesis
title_fullStr Catalytic palladium-based and iron-based membrane reactors: Novel strategies of synthesis
title_full_unstemmed Catalytic palladium-based and iron-based membrane reactors: Novel strategies of synthesis
title_sort Catalytic palladium-based and iron-based membrane reactors: Novel strategies of synthesis
dc.creator.none.fl_str_mv Pinos-Vélez, Verónica
Di Luca, Carla
Crivoi, Dana G.
Medina, Francisco
Dafinov, Anton
author Pinos-Vélez, Verónica
author_facet Pinos-Vélez, Verónica
Di Luca, Carla
Crivoi, Dana G.
Medina, Francisco
Dafinov, Anton
author_role author
author2 Di Luca, Carla
Crivoi, Dana G.
Medina, Francisco
Dafinov, Anton
author2_role author
author
author
author
dc.subject.none.fl_str_mv Catalytic membrane reactors
Synthesisi strategies
CWPO
Palladium and iron
topic Catalytic membrane reactors
Synthesisi strategies
CWPO
Palladium and iron
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Several procedures were employed in the preparation of different Pd- and Fe-based catalytic membrane reactors (CMRs) via the normal wet impregnation method, reverse filtration of a microemulsion, sputtering method, and the precipitation of a Fe complex. Depending on the chosen procedure, the metal active phase can be found on the exterior and/or interior part of the CMR or even in its pores in concentrations between 0.05 and 2 wt %. Moreover, we have managed to implement a unique systematic process to grow hydrotalcite in the pores of a Pd-CMR. To exemplify the activity of these new CMRs, we have tested them in the peroxidation of phenol and in situ epoxidation of trans-chalcone.
Fil: Pinos-Vélez, Verónica. Universitat Rovira I Virgili; España
Fil: Di Luca, Carla. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Crivoi, Dana G.. Universitat Rovira I Virgili; España
Fil: Medina, Francisco. Universitat Rovira I Virgili; España
Fil: Dafinov, Anton. Universitat Rovira I Virgili; España
description Several procedures were employed in the preparation of different Pd- and Fe-based catalytic membrane reactors (CMRs) via the normal wet impregnation method, reverse filtration of a microemulsion, sputtering method, and the precipitation of a Fe complex. Depending on the chosen procedure, the metal active phase can be found on the exterior and/or interior part of the CMR or even in its pores in concentrations between 0.05 and 2 wt %. Moreover, we have managed to implement a unique systematic process to grow hydrotalcite in the pores of a Pd-CMR. To exemplify the activity of these new CMRs, we have tested them in the peroxidation of phenol and in situ epoxidation of trans-chalcone.
publishDate 2019
dc.date.none.fl_str_mv 2019-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/121291
Pinos-Vélez, Verónica; Di Luca, Carla; Crivoi, Dana G.; Medina, Francisco; Dafinov, Anton; Catalytic palladium-based and iron-based membrane reactors: Novel strategies of synthesis; American Chemical Society; ACS Omega; 4; 22; 11-2019; 19818-19828
2470-1343
CONICET Digital
CONICET
url http://hdl.handle.net/11336/121291
identifier_str_mv Pinos-Vélez, Verónica; Di Luca, Carla; Crivoi, Dana G.; Medina, Francisco; Dafinov, Anton; Catalytic palladium-based and iron-based membrane reactors: Novel strategies of synthesis; American Chemical Society; ACS Omega; 4; 22; 11-2019; 19818-19828
2470-1343
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acsomega.9b02706
info:eu-repo/semantics/altIdentifier/doi/10.1021/acsomega.9b02706
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1848597831179304960
score 12.976206

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