Iron-alumina synergy in the heterogeneous Fenton-type peroxidation of phenol solutions

Autores
Di Luca, Carla; Ivorra, Fernando Daniel; Massa, Paola Andrea; Fenoglio, Rosa Juana
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Highly dispersed Fe2O3/Al2O3 catalysts (0.5–4 wt% Fe) were prepared by incipient wetness impregnation of iron citrate over a mesoporous alumina host. Their structural and textural properties were determined by N2 adsorption–desorption at −196 °C, XRD, TEM, SEM–EDAX, Raman and XPS. The structure of the catalytic materials resulted similar to the γ-Al2O3 support, exhibiting high dispersion levels of the iron oxide active phase with a narrow pore size distribution in the range of 2–7 nm and high surface areas. The capability of these systems as efficient and active Fenton-like catalysts, were further tested for the catalytic oxidation of concentrated phenol solutions (5 g/L) with H2O2 at 70 °C in a batch reactor. The effects of iron concentration, catalyst concentration and the nature of the support were evaluated, under adjusted sub-stoichiometric oxidant concentration. Besides the positive impact of increasing the iron loading, a synergistic effect between Fe and Al species would be possibly responsible of the improvements observed using higher iron dispersions and/or support concentrations. The catalytic performance of these alumina-based catalysts resulted very promissory as they yielded: total phenol abatement, high mineralization levels (up to a maximum of 80%) and high oxidant consumption efficiencies (between 80% and 96%).
Fil: Di Luca, Carla. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Ivorra, Fernando Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Massa, Paola Andrea. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Fenoglio, Rosa Juana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Materia
Fe–Al2o3
Mesoporous Alumina
Cwhpo
Phenol
Heterogeneous Fenton-Like Systems
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/30040
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/30040
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Iron-alumina synergy in the heterogeneous Fenton-type peroxidation of phenol solutionsDi Luca, CarlaIvorra, Fernando DanielMassa, Paola AndreaFenoglio, Rosa JuanaFe–Al2o3Mesoporous AluminaCwhpoPhenolHeterogeneous Fenton-Like Systemshttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Highly dispersed Fe2O3/Al2O3 catalysts (0.5–4 wt% Fe) were prepared by incipient wetness impregnation of iron citrate over a mesoporous alumina host. Their structural and textural properties were determined by N2 adsorption–desorption at −196 °C, XRD, TEM, SEM–EDAX, Raman and XPS. The structure of the catalytic materials resulted similar to the γ-Al2O3 support, exhibiting high dispersion levels of the iron oxide active phase with a narrow pore size distribution in the range of 2–7 nm and high surface areas. The capability of these systems as efficient and active Fenton-like catalysts, were further tested for the catalytic oxidation of concentrated phenol solutions (5 g/L) with H2O2 at 70 °C in a batch reactor. The effects of iron concentration, catalyst concentration and the nature of the support were evaluated, under adjusted sub-stoichiometric oxidant concentration. Besides the positive impact of increasing the iron loading, a synergistic effect between Fe and Al species would be possibly responsible of the improvements observed using higher iron dispersions and/or support concentrations. The catalytic performance of these alumina-based catalysts resulted very promissory as they yielded: total phenol abatement, high mineralization levels (up to a maximum of 80%) and high oxidant consumption efficiencies (between 80% and 96%).Fil: Di Luca, Carla. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Ivorra, Fernando Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Massa, Paola Andrea. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Fenoglio, Rosa Juana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaElsevier2015-01-27info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/30040Di Luca, Carla; Ivorra, Fernando Daniel; Massa, Paola Andrea; Fenoglio, Rosa Juana; Iron-alumina synergy in the heterogeneous Fenton-type peroxidation of phenol solutions; Elsevier; Chemical Engineering Journal; 268; 27-1-2015; 280-2891385-8947CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1385894715001035info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cej.2015.01.074info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T14:37:34Zoai:ri.conicet.gov.ar:11336/30040instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 14:37:34.459CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Iron-alumina synergy in the heterogeneous Fenton-type peroxidation of phenol solutions
title Iron-alumina synergy in the heterogeneous Fenton-type peroxidation of phenol solutions
spellingShingle Iron-alumina synergy in the heterogeneous Fenton-type peroxidation of phenol solutions
Di Luca, Carla
Fe–Al2o3
Mesoporous Alumina
Cwhpo
Phenol
Heterogeneous Fenton-Like Systems
title_short Iron-alumina synergy in the heterogeneous Fenton-type peroxidation of phenol solutions
title_full Iron-alumina synergy in the heterogeneous Fenton-type peroxidation of phenol solutions
title_fullStr Iron-alumina synergy in the heterogeneous Fenton-type peroxidation of phenol solutions
title_full_unstemmed Iron-alumina synergy in the heterogeneous Fenton-type peroxidation of phenol solutions
title_sort Iron-alumina synergy in the heterogeneous Fenton-type peroxidation of phenol solutions
dc.creator.none.fl_str_mv Di Luca, Carla
Ivorra, Fernando Daniel
Massa, Paola Andrea
Fenoglio, Rosa Juana
author Di Luca, Carla
author_facet Di Luca, Carla
Ivorra, Fernando Daniel
Massa, Paola Andrea
Fenoglio, Rosa Juana
author_role author
author2 Ivorra, Fernando Daniel
Massa, Paola Andrea
Fenoglio, Rosa Juana
author2_role author
author
author
dc.subject.none.fl_str_mv Fe–Al2o3
Mesoporous Alumina
Cwhpo
Phenol
Heterogeneous Fenton-Like Systems
topic Fe–Al2o3
Mesoporous Alumina
Cwhpo
Phenol
Heterogeneous Fenton-Like Systems
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Highly dispersed Fe2O3/Al2O3 catalysts (0.5–4 wt% Fe) were prepared by incipient wetness impregnation of iron citrate over a mesoporous alumina host. Their structural and textural properties were determined by N2 adsorption–desorption at −196 °C, XRD, TEM, SEM–EDAX, Raman and XPS. The structure of the catalytic materials resulted similar to the γ-Al2O3 support, exhibiting high dispersion levels of the iron oxide active phase with a narrow pore size distribution in the range of 2–7 nm and high surface areas. The capability of these systems as efficient and active Fenton-like catalysts, were further tested for the catalytic oxidation of concentrated phenol solutions (5 g/L) with H2O2 at 70 °C in a batch reactor. The effects of iron concentration, catalyst concentration and the nature of the support were evaluated, under adjusted sub-stoichiometric oxidant concentration. Besides the positive impact of increasing the iron loading, a synergistic effect between Fe and Al species would be possibly responsible of the improvements observed using higher iron dispersions and/or support concentrations. The catalytic performance of these alumina-based catalysts resulted very promissory as they yielded: total phenol abatement, high mineralization levels (up to a maximum of 80%) and high oxidant consumption efficiencies (between 80% and 96%).
Fil: Di Luca, Carla. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Ivorra, Fernando Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Massa, Paola Andrea. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Fenoglio, Rosa Juana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
description Highly dispersed Fe2O3/Al2O3 catalysts (0.5–4 wt% Fe) were prepared by incipient wetness impregnation of iron citrate over a mesoporous alumina host. Their structural and textural properties were determined by N2 adsorption–desorption at −196 °C, XRD, TEM, SEM–EDAX, Raman and XPS. The structure of the catalytic materials resulted similar to the γ-Al2O3 support, exhibiting high dispersion levels of the iron oxide active phase with a narrow pore size distribution in the range of 2–7 nm and high surface areas. The capability of these systems as efficient and active Fenton-like catalysts, were further tested for the catalytic oxidation of concentrated phenol solutions (5 g/L) with H2O2 at 70 °C in a batch reactor. The effects of iron concentration, catalyst concentration and the nature of the support were evaluated, under adjusted sub-stoichiometric oxidant concentration. Besides the positive impact of increasing the iron loading, a synergistic effect between Fe and Al species would be possibly responsible of the improvements observed using higher iron dispersions and/or support concentrations. The catalytic performance of these alumina-based catalysts resulted very promissory as they yielded: total phenol abatement, high mineralization levels (up to a maximum of 80%) and high oxidant consumption efficiencies (between 80% and 96%).
publishDate 2015
dc.date.none.fl_str_mv 2015-01-27
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/30040
Di Luca, Carla; Ivorra, Fernando Daniel; Massa, Paola Andrea; Fenoglio, Rosa Juana; Iron-alumina synergy in the heterogeneous Fenton-type peroxidation of phenol solutions; Elsevier; Chemical Engineering Journal; 268; 27-1-2015; 280-289
1385-8947
CONICET Digital
CONICET
url http://hdl.handle.net/11336/30040
identifier_str_mv Di Luca, Carla; Ivorra, Fernando Daniel; Massa, Paola Andrea; Fenoglio, Rosa Juana; Iron-alumina synergy in the heterogeneous Fenton-type peroxidation of phenol solutions; Elsevier; Chemical Engineering Journal; 268; 27-1-2015; 280-289
1385-8947
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1385894715001035
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cej.2015.01.074
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.22299

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