Microwave-assisted tandem catalyst-free production of 2-methyl furoate from furfural

Autores
Guerrero, Maira Antonela; Sathicq, Angel Gabriel; Lick, Ileana Daniela; Casella, Mónica Laura; Legnoverde, María Soledad; Romanelli, Gustavo Pablo
Año de publicación
2024
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The valorization of building blocks present in vegetal biomass using eco-efficient processes is an excellent alternative to reduce the demand for fossil fuels. Furfural is an encouraging renewable biomass-based platform chemical that can be transformed into several value-added chemicals.The transformation of furfural into methyl furoate through a tandem process that involves oxidation followed by esterification with methanol is widely studied since the selectivity towards the product is strongly dependent on numerous factors: reaction conditions, oxidant, and catalysts.Depending on them, more than ten different products can be obtained, making the process of no importance given the difficulty of separating each of these products. In this communication we study the reaction selectivity in a very simple procedure that is catalyst-free, using a clean oxidant and mild reaction conditions. Particularly as an alternative source of heat, and with the aim of reducing reaction times, said transformation was assisted by microwaves. In order to optimize the process, the reaction time and temperature, type of oxidant, amount of oxidant and molar ratio of reagents were studied. In this work, 100% conversion with 69% selectivity was achieved in 2 h at 120 °C using 1:3:20 M ratio of furfural, oxidant, and alcohol. The methodology represents a powerful alternative for the preparation of furoates through a low-cost and environmentally friendly process that does not use a catalyst.
Fil: Guerrero, Maira Antonela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Sathicq, Angel Gabriel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Lick, Ileana Daniela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Casella, Mónica Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Legnoverde, María Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Romanelli, Gustavo Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Materia
Methyl furoate
Tandem reaction
Biomass building-block
Catalyst-free
Microwave
Green chemistry
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/261286
Acceder
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network_acronym_str CONICETDig
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network_name_str CONICET Digital (CONICET)
spelling Microwave-assisted tandem catalyst-free production of 2-methyl furoate from furfuralGuerrero, Maira AntonelaSathicq, Angel GabrielLick, Ileana DanielaCasella, Mónica LauraLegnoverde, María SoledadRomanelli, Gustavo PabloMethyl furoateTandem reactionBiomass building-blockCatalyst-freeMicrowaveGreen chemistryhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1https://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The valorization of building blocks present in vegetal biomass using eco-efficient processes is an excellent alternative to reduce the demand for fossil fuels. Furfural is an encouraging renewable biomass-based platform chemical that can be transformed into several value-added chemicals.The transformation of furfural into methyl furoate through a tandem process that involves oxidation followed by esterification with methanol is widely studied since the selectivity towards the product is strongly dependent on numerous factors: reaction conditions, oxidant, and catalysts.Depending on them, more than ten different products can be obtained, making the process of no importance given the difficulty of separating each of these products. In this communication we study the reaction selectivity in a very simple procedure that is catalyst-free, using a clean oxidant and mild reaction conditions. Particularly as an alternative source of heat, and with the aim of reducing reaction times, said transformation was assisted by microwaves. In order to optimize the process, the reaction time and temperature, type of oxidant, amount of oxidant and molar ratio of reagents were studied. In this work, 100% conversion with 69% selectivity was achieved in 2 h at 120 °C using 1:3:20 M ratio of furfural, oxidant, and alcohol. The methodology represents a powerful alternative for the preparation of furoates through a low-cost and environmentally friendly process that does not use a catalyst.Fil: Guerrero, Maira Antonela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Sathicq, Angel Gabriel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Lick, Ileana Daniela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Casella, Mónica Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Legnoverde, María Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Romanelli, Gustavo Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaElsevier2024-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/261286Guerrero, Maira Antonela; Sathicq, Angel Gabriel; Lick, Ileana Daniela; Casella, Mónica Laura; Legnoverde, María Soledad; et al.; Microwave-assisted tandem catalyst-free production of 2-methyl furoate from furfural; Elsevier; Sustainable Chemistry and Pharmacy; 41; 10-2024; 1-122352-5541CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S235255412400278Xinfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.scp.2024.101703info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T15:24:48Zoai:ri.conicet.gov.ar:11336/261286instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 15:24:48.774CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Microwave-assisted tandem catalyst-free production of 2-methyl furoate from furfural
title Microwave-assisted tandem catalyst-free production of 2-methyl furoate from furfural
spellingShingle Microwave-assisted tandem catalyst-free production of 2-methyl furoate from furfural
Guerrero, Maira Antonela
Methyl furoate
Tandem reaction
Biomass building-block
Catalyst-free
Microwave
Green chemistry
title_short Microwave-assisted tandem catalyst-free production of 2-methyl furoate from furfural
title_full Microwave-assisted tandem catalyst-free production of 2-methyl furoate from furfural
title_fullStr Microwave-assisted tandem catalyst-free production of 2-methyl furoate from furfural
title_full_unstemmed Microwave-assisted tandem catalyst-free production of 2-methyl furoate from furfural
title_sort Microwave-assisted tandem catalyst-free production of 2-methyl furoate from furfural
dc.creator.none.fl_str_mv Guerrero, Maira Antonela
Sathicq, Angel Gabriel
Lick, Ileana Daniela
Casella, Mónica Laura
Legnoverde, María Soledad
Romanelli, Gustavo Pablo
author Guerrero, Maira Antonela
author_facet Guerrero, Maira Antonela
Sathicq, Angel Gabriel
Lick, Ileana Daniela
Casella, Mónica Laura
Legnoverde, María Soledad
Romanelli, Gustavo Pablo
author_role author
author2 Sathicq, Angel Gabriel
Lick, Ileana Daniela
Casella, Mónica Laura
Legnoverde, María Soledad
Romanelli, Gustavo Pablo
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Methyl furoate
Tandem reaction
Biomass building-block
Catalyst-free
Microwave
Green chemistry
topic Methyl furoate
Tandem reaction
Biomass building-block
Catalyst-free
Microwave
Green chemistry
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The valorization of building blocks present in vegetal biomass using eco-efficient processes is an excellent alternative to reduce the demand for fossil fuels. Furfural is an encouraging renewable biomass-based platform chemical that can be transformed into several value-added chemicals.The transformation of furfural into methyl furoate through a tandem process that involves oxidation followed by esterification with methanol is widely studied since the selectivity towards the product is strongly dependent on numerous factors: reaction conditions, oxidant, and catalysts.Depending on them, more than ten different products can be obtained, making the process of no importance given the difficulty of separating each of these products. In this communication we study the reaction selectivity in a very simple procedure that is catalyst-free, using a clean oxidant and mild reaction conditions. Particularly as an alternative source of heat, and with the aim of reducing reaction times, said transformation was assisted by microwaves. In order to optimize the process, the reaction time and temperature, type of oxidant, amount of oxidant and molar ratio of reagents were studied. In this work, 100% conversion with 69% selectivity was achieved in 2 h at 120 °C using 1:3:20 M ratio of furfural, oxidant, and alcohol. The methodology represents a powerful alternative for the preparation of furoates through a low-cost and environmentally friendly process that does not use a catalyst.
Fil: Guerrero, Maira Antonela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Sathicq, Angel Gabriel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Lick, Ileana Daniela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Casella, Mónica Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Legnoverde, María Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Romanelli, Gustavo Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
description The valorization of building blocks present in vegetal biomass using eco-efficient processes is an excellent alternative to reduce the demand for fossil fuels. Furfural is an encouraging renewable biomass-based platform chemical that can be transformed into several value-added chemicals.The transformation of furfural into methyl furoate through a tandem process that involves oxidation followed by esterification with methanol is widely studied since the selectivity towards the product is strongly dependent on numerous factors: reaction conditions, oxidant, and catalysts.Depending on them, more than ten different products can be obtained, making the process of no importance given the difficulty of separating each of these products. In this communication we study the reaction selectivity in a very simple procedure that is catalyst-free, using a clean oxidant and mild reaction conditions. Particularly as an alternative source of heat, and with the aim of reducing reaction times, said transformation was assisted by microwaves. In order to optimize the process, the reaction time and temperature, type of oxidant, amount of oxidant and molar ratio of reagents were studied. In this work, 100% conversion with 69% selectivity was achieved in 2 h at 120 °C using 1:3:20 M ratio of furfural, oxidant, and alcohol. The methodology represents a powerful alternative for the preparation of furoates through a low-cost and environmentally friendly process that does not use a catalyst.
publishDate 2024
dc.date.none.fl_str_mv 2024-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/261286
Guerrero, Maira Antonela; Sathicq, Angel Gabriel; Lick, Ileana Daniela; Casella, Mónica Laura; Legnoverde, María Soledad; et al.; Microwave-assisted tandem catalyst-free production of 2-methyl furoate from furfural; Elsevier; Sustainable Chemistry and Pharmacy; 41; 10-2024; 1-12
2352-5541
CONICET Digital
CONICET
url http://hdl.handle.net/11336/261286
identifier_str_mv Guerrero, Maira Antonela; Sathicq, Angel Gabriel; Lick, Ileana Daniela; Casella, Mónica Laura; Legnoverde, María Soledad; et al.; Microwave-assisted tandem catalyst-free production of 2-methyl furoate from furfural; Elsevier; Sustainable Chemistry and Pharmacy; 41; 10-2024; 1-12
2352-5541
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S235255412400278X
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.scp.2024.101703
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
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dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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