Rheological study of the curing kinetics of epoxy-phenol novolac resin

Autores
Auad, María L.; Nutt, Steven R.; Stefani, Pablo Marcelo; Aranguren, Mirta Ines
Año de publicación
2006
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The curing reaction of an epoxy-phenolic resin under different conditions was monitored using rheological measurements. The evolution of viscoelastic properties, such as storage modulus, G′, and loss modulus, G″, was recorded. Several experiments were performed to confidently compare the rheological data obtained under varied curing conditions of temperature, catalyst concentration, and reactive ratios. The values of G′ measured at the end of the reactions (at maximum conversion) were independent of the frequency and temperature of the tests in the range of high temperatures investigated. The overall curing process was described by a second-order phenomenological rheokinetic equation based on the model of Kamal. The effects of the epoxy-to-phenolic ratio as well as the curing temperature and the catalyst concentration were also investigated.
Fil: Auad, María L.. Auburn University; Estados Unidos
Fil: Nutt, Steven R.. University Of Southern California; Estados Unidos
Fil: Stefani, Pablo Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Aranguren, Mirta Ines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Materia
Epoxy-Phenolic
Kamal Model
Rheokinetic
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/78712
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/78712
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Rheological study of the curing kinetics of epoxy-phenol novolac resinAuad, María L.Nutt, Steven R.Stefani, Pablo MarceloAranguren, Mirta InesEpoxy-PhenolicKamal ModelRheokinetichttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1https://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2The curing reaction of an epoxy-phenolic resin under different conditions was monitored using rheological measurements. The evolution of viscoelastic properties, such as storage modulus, G′, and loss modulus, G″, was recorded. Several experiments were performed to confidently compare the rheological data obtained under varied curing conditions of temperature, catalyst concentration, and reactive ratios. The values of G′ measured at the end of the reactions (at maximum conversion) were independent of the frequency and temperature of the tests in the range of high temperatures investigated. The overall curing process was described by a second-order phenomenological rheokinetic equation based on the model of Kamal. The effects of the epoxy-to-phenolic ratio as well as the curing temperature and the catalyst concentration were also investigated.Fil: Auad, María L.. Auburn University; Estados UnidosFil: Nutt, Steven R.. University Of Southern California; Estados UnidosFil: Stefani, Pablo Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Aranguren, Mirta Ines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaJohn Wiley & Sons Inc2006-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/78712Auad, María L.; Nutt, Steven R.; Stefani, Pablo Marcelo; Aranguren, Mirta Ines; Rheological study of the curing kinetics of epoxy-phenol novolac resin; John Wiley & Sons Inc; Journal of Applied Polymer Science; 102; 5; 12-2006; 4430-44390021-8995CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/app.24674info:eu-repo/semantics/altIdentifier/doi/10.1002/app.24674info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:54:46Zoai:ri.conicet.gov.ar:11336/78712instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:54:46.756CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Rheological study of the curing kinetics of epoxy-phenol novolac resin
title Rheological study of the curing kinetics of epoxy-phenol novolac resin
spellingShingle Rheological study of the curing kinetics of epoxy-phenol novolac resin
Auad, María L.
Epoxy-Phenolic
Kamal Model
Rheokinetic
title_short Rheological study of the curing kinetics of epoxy-phenol novolac resin
title_full Rheological study of the curing kinetics of epoxy-phenol novolac resin
title_fullStr Rheological study of the curing kinetics of epoxy-phenol novolac resin
title_full_unstemmed Rheological study of the curing kinetics of epoxy-phenol novolac resin
title_sort Rheological study of the curing kinetics of epoxy-phenol novolac resin
dc.creator.none.fl_str_mv Auad, María L.
Nutt, Steven R.
Stefani, Pablo Marcelo
Aranguren, Mirta Ines
author Auad, María L.
author_facet Auad, María L.
Nutt, Steven R.
Stefani, Pablo Marcelo
Aranguren, Mirta Ines
author_role author
author2 Nutt, Steven R.
Stefani, Pablo Marcelo
Aranguren, Mirta Ines
author2_role author
author
author
dc.subject.none.fl_str_mv Epoxy-Phenolic
Kamal Model
Rheokinetic
topic Epoxy-Phenolic
Kamal Model
Rheokinetic
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The curing reaction of an epoxy-phenolic resin under different conditions was monitored using rheological measurements. The evolution of viscoelastic properties, such as storage modulus, G′, and loss modulus, G″, was recorded. Several experiments were performed to confidently compare the rheological data obtained under varied curing conditions of temperature, catalyst concentration, and reactive ratios. The values of G′ measured at the end of the reactions (at maximum conversion) were independent of the frequency and temperature of the tests in the range of high temperatures investigated. The overall curing process was described by a second-order phenomenological rheokinetic equation based on the model of Kamal. The effects of the epoxy-to-phenolic ratio as well as the curing temperature and the catalyst concentration were also investigated.
Fil: Auad, María L.. Auburn University; Estados Unidos
Fil: Nutt, Steven R.. University Of Southern California; Estados Unidos
Fil: Stefani, Pablo Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Aranguren, Mirta Ines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
description The curing reaction of an epoxy-phenolic resin under different conditions was monitored using rheological measurements. The evolution of viscoelastic properties, such as storage modulus, G′, and loss modulus, G″, was recorded. Several experiments were performed to confidently compare the rheological data obtained under varied curing conditions of temperature, catalyst concentration, and reactive ratios. The values of G′ measured at the end of the reactions (at maximum conversion) were independent of the frequency and temperature of the tests in the range of high temperatures investigated. The overall curing process was described by a second-order phenomenological rheokinetic equation based on the model of Kamal. The effects of the epoxy-to-phenolic ratio as well as the curing temperature and the catalyst concentration were also investigated.
publishDate 2006
dc.date.none.fl_str_mv 2006-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/78712
Auad, María L.; Nutt, Steven R.; Stefani, Pablo Marcelo; Aranguren, Mirta Ines; Rheological study of the curing kinetics of epoxy-phenol novolac resin; John Wiley & Sons Inc; Journal of Applied Polymer Science; 102; 5; 12-2006; 4430-4439
0021-8995
CONICET Digital
CONICET
url http://hdl.handle.net/11336/78712
identifier_str_mv Auad, María L.; Nutt, Steven R.; Stefani, Pablo Marcelo; Aranguren, Mirta Ines; Rheological study of the curing kinetics of epoxy-phenol novolac resin; John Wiley & Sons Inc; Journal of Applied Polymer Science; 102; 5; 12-2006; 4430-4439
0021-8995
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/app.24674
info:eu-repo/semantics/altIdentifier/doi/10.1002/app.24674
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv John Wiley & Sons Inc
publisher.none.fl_str_mv John Wiley & Sons Inc
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842269305897484288
score 13.13397

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