Carbon Dots Enabling Parts-Per-Billion Sensitive and Ultraselective Photoluminescence Lifetime-Based Sensing of Inorganic Mercury

Autores
Zdražil, Lukáš; Panáček, David; Sedajová, Veronika; Baďura, Zdeněk; Langer, Michal; Medveď, Miroslav; Paloncýová, Markéta; Scheibe, Magdalena; Kalytchuk, Sergii; Zoppellaro, Giorgio; Kment, Štěpán; Cadranel, Alejandro; Bakandritsos, Aristides; Guldi, Dirk; Otyepka, Michal; Zbořil, Radek
Año de publicación
2023
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
One of the UN Sustainable Development Goals is to ensure universal access to clean drinking water. Among the various types of water contaminants, mercury (Hg) is considered to be one of the most dangerous ones. It is mostly its immense toxicity and vast environmental impact that stand out. To tackle the issue of monitoring water quality, a nanosensor based on carbon dots (CDs) is developed, whose surface is functionalized with carboxylic groups. CDs show Hg2+ concentration-dependent photoluminescence (PL) lifetimes along with an ultrahigh sensitivity and selectivity. The selectivity of PL quenching by Hg2+ is rationalized by performing light-induced electron paramagnetic resonance (LEPR) spectroscopy showing significant perturbation of the CD photoexcited state upon Hg2+ binding. The experimental findings are supported by time-dependent density functional theory (TD-DFT) calculations. These unveiled the emergence of a low-lying charge transfer state involving a vacant 6s orbital of Hg2+ stabilized by relativistic effects.
Fil: Zdražil, Lukáš. Univerzita Palackého V Olomouci; República Checa. Universitat Erlangen-Nuremberg; Alemania
Fil: Panáček, David. Univerzita Palackého V Olomouci; República Checa
Fil: Sedajová, Veronika. Univerzita Palackého V Olomouci; República Checa
Fil: Baďura, Zdeněk. Univerzita Palackého V Olomouci; República Checa
Fil: Langer, Michal. Centrum Nowych Technologii Uniwersytetu Warszawskiego; Polonia. Univerzita Palackého V Olomouci; República Checa
Fil: Medveď, Miroslav. Univerzita Palackého V Olomouci; República Checa. Matej Bel University; Eslovaquia
Fil: Paloncýová, Markéta. Univerzita Palackého V Olomouci; República Checa
Fil: Scheibe, Magdalena. Univerzita Palackého V Olomouci; República Checa
Fil: Kalytchuk, Sergii. Univerzita Palackého V Olomouci; República Checa
Fil: Zoppellaro, Giorgio. Univerzita Palackého V Olomouci; República Checa
Fil: Kment, Štěpán. Univerzita Palackého V Olomouci; República Checa
Fil: Cadranel, Alejandro. Universitat Erlangen-Nuremberg; Alemania. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Bakandritsos, Aristides. Univerzita Palackého V Olomouci; República Checa
Fil: Guldi, Dirk. Universitat Erlangen-Nuremberg; Alemania
Fil: Otyepka, Michal. Univerzita Palackého V Olomouci; República Checa
Fil: Zbořil, Radek. Univerzita Palackého V Olomouci; República Checa
Materia
CARBON DOTS
COLLOIDAL NANOMATERIALS
MERCURY SENSING
TIME-RESOLVED PHOTOLUMINESCENCE
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/228653
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/228653
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Carbon Dots Enabling Parts-Per-Billion Sensitive and Ultraselective Photoluminescence Lifetime-Based Sensing of Inorganic MercuryZdražil, LukášPanáček, DavidSedajová, VeronikaBaďura, ZdeněkLanger, MichalMedveď, MiroslavPaloncýová, MarkétaScheibe, MagdalenaKalytchuk, SergiiZoppellaro, GiorgioKment, ŠtěpánCadranel, AlejandroBakandritsos, AristidesGuldi, DirkOtyepka, MichalZbořil, RadekCARBON DOTSCOLLOIDAL NANOMATERIALSMERCURY SENSINGTIME-RESOLVED PHOTOLUMINESCENCEhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1One of the UN Sustainable Development Goals is to ensure universal access to clean drinking water. Among the various types of water contaminants, mercury (Hg) is considered to be one of the most dangerous ones. It is mostly its immense toxicity and vast environmental impact that stand out. To tackle the issue of monitoring water quality, a nanosensor based on carbon dots (CDs) is developed, whose surface is functionalized with carboxylic groups. CDs show Hg2+ concentration-dependent photoluminescence (PL) lifetimes along with an ultrahigh sensitivity and selectivity. The selectivity of PL quenching by Hg2+ is rationalized by performing light-induced electron paramagnetic resonance (LEPR) spectroscopy showing significant perturbation of the CD photoexcited state upon Hg2+ binding. The experimental findings are supported by time-dependent density functional theory (TD-DFT) calculations. These unveiled the emergence of a low-lying charge transfer state involving a vacant 6s orbital of Hg2+ stabilized by relativistic effects.Fil: Zdražil, Lukáš. Univerzita Palackého V Olomouci; República Checa. Universitat Erlangen-Nuremberg; AlemaniaFil: Panáček, David. Univerzita Palackého V Olomouci; República ChecaFil: Sedajová, Veronika. Univerzita Palackého V Olomouci; República ChecaFil: Baďura, Zdeněk. Univerzita Palackého V Olomouci; República ChecaFil: Langer, Michal. Centrum Nowych Technologii Uniwersytetu Warszawskiego; Polonia. Univerzita Palackého V Olomouci; República ChecaFil: Medveď, Miroslav. Univerzita Palackého V Olomouci; República Checa. Matej Bel University; EslovaquiaFil: Paloncýová, Markéta. Univerzita Palackého V Olomouci; República ChecaFil: Scheibe, Magdalena. Univerzita Palackého V Olomouci; República ChecaFil: Kalytchuk, Sergii. Univerzita Palackého V Olomouci; República ChecaFil: Zoppellaro, Giorgio. Univerzita Palackého V Olomouci; República ChecaFil: Kment, Štěpán. Univerzita Palackého V Olomouci; República ChecaFil: Cadranel, Alejandro. Universitat Erlangen-Nuremberg; Alemania. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Bakandritsos, Aristides. Univerzita Palackého V Olomouci; República ChecaFil: Guldi, Dirk. Universitat Erlangen-Nuremberg; AlemaniaFil: Otyepka, Michal. Univerzita Palackého V Olomouci; República ChecaFil: Zbořil, Radek. Univerzita Palackého V Olomouci; República ChecaJohn Wiley & Sons Ltd2023-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/228653Zdražil, Lukáš; Panáček, David; Sedajová, Veronika; Baďura, Zdeněk; Langer, Michal; et al.; Carbon Dots Enabling Parts-Per-Billion Sensitive and Ultraselective Photoluminescence Lifetime-Based Sensing of Inorganic Mercury; John Wiley & Sons Ltd; Advanced Optical Materials; 11; 21; 7-2023; 1-82195-1071CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1002/adom.202300750info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/10.1002/adom.202300750info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:40:33Zoai:ri.conicet.gov.ar:11336/228653instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:40:33.75CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Carbon Dots Enabling Parts-Per-Billion Sensitive and Ultraselective Photoluminescence Lifetime-Based Sensing of Inorganic Mercury
title Carbon Dots Enabling Parts-Per-Billion Sensitive and Ultraselective Photoluminescence Lifetime-Based Sensing of Inorganic Mercury
spellingShingle Carbon Dots Enabling Parts-Per-Billion Sensitive and Ultraselective Photoluminescence Lifetime-Based Sensing of Inorganic Mercury
Zdražil, Lukáš
CARBON DOTS
COLLOIDAL NANOMATERIALS
MERCURY SENSING
TIME-RESOLVED PHOTOLUMINESCENCE
title_short Carbon Dots Enabling Parts-Per-Billion Sensitive and Ultraselective Photoluminescence Lifetime-Based Sensing of Inorganic Mercury
title_full Carbon Dots Enabling Parts-Per-Billion Sensitive and Ultraselective Photoluminescence Lifetime-Based Sensing of Inorganic Mercury
title_fullStr Carbon Dots Enabling Parts-Per-Billion Sensitive and Ultraselective Photoluminescence Lifetime-Based Sensing of Inorganic Mercury
title_full_unstemmed Carbon Dots Enabling Parts-Per-Billion Sensitive and Ultraselective Photoluminescence Lifetime-Based Sensing of Inorganic Mercury
title_sort Carbon Dots Enabling Parts-Per-Billion Sensitive and Ultraselective Photoluminescence Lifetime-Based Sensing of Inorganic Mercury
dc.creator.none.fl_str_mv Zdražil, Lukáš
Panáček, David
Sedajová, Veronika
Baďura, Zdeněk
Langer, Michal
Medveď, Miroslav
Paloncýová, Markéta
Scheibe, Magdalena
Kalytchuk, Sergii
Zoppellaro, Giorgio
Kment, Štěpán
Cadranel, Alejandro
Bakandritsos, Aristides
Guldi, Dirk
Otyepka, Michal
Zbořil, Radek
author Zdražil, Lukáš
author_facet Zdražil, Lukáš
Panáček, David
Sedajová, Veronika
Baďura, Zdeněk
Langer, Michal
Medveď, Miroslav
Paloncýová, Markéta
Scheibe, Magdalena
Kalytchuk, Sergii
Zoppellaro, Giorgio
Kment, Štěpán
Cadranel, Alejandro
Bakandritsos, Aristides
Guldi, Dirk
Otyepka, Michal
Zbořil, Radek
author_role author
author2 Panáček, David
Sedajová, Veronika
Baďura, Zdeněk
Langer, Michal
Medveď, Miroslav
Paloncýová, Markéta
Scheibe, Magdalena
Kalytchuk, Sergii
Zoppellaro, Giorgio
Kment, Štěpán
Cadranel, Alejandro
Bakandritsos, Aristides
Guldi, Dirk
Otyepka, Michal
Zbořil, Radek
author2_role author
author
author
author
author
author
author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv CARBON DOTS
COLLOIDAL NANOMATERIALS
MERCURY SENSING
TIME-RESOLVED PHOTOLUMINESCENCE
topic CARBON DOTS
COLLOIDAL NANOMATERIALS
MERCURY SENSING
TIME-RESOLVED PHOTOLUMINESCENCE
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv One of the UN Sustainable Development Goals is to ensure universal access to clean drinking water. Among the various types of water contaminants, mercury (Hg) is considered to be one of the most dangerous ones. It is mostly its immense toxicity and vast environmental impact that stand out. To tackle the issue of monitoring water quality, a nanosensor based on carbon dots (CDs) is developed, whose surface is functionalized with carboxylic groups. CDs show Hg2+ concentration-dependent photoluminescence (PL) lifetimes along with an ultrahigh sensitivity and selectivity. The selectivity of PL quenching by Hg2+ is rationalized by performing light-induced electron paramagnetic resonance (LEPR) spectroscopy showing significant perturbation of the CD photoexcited state upon Hg2+ binding. The experimental findings are supported by time-dependent density functional theory (TD-DFT) calculations. These unveiled the emergence of a low-lying charge transfer state involving a vacant 6s orbital of Hg2+ stabilized by relativistic effects.
Fil: Zdražil, Lukáš. Univerzita Palackého V Olomouci; República Checa. Universitat Erlangen-Nuremberg; Alemania
Fil: Panáček, David. Univerzita Palackého V Olomouci; República Checa
Fil: Sedajová, Veronika. Univerzita Palackého V Olomouci; República Checa
Fil: Baďura, Zdeněk. Univerzita Palackého V Olomouci; República Checa
Fil: Langer, Michal. Centrum Nowych Technologii Uniwersytetu Warszawskiego; Polonia. Univerzita Palackého V Olomouci; República Checa
Fil: Medveď, Miroslav. Univerzita Palackého V Olomouci; República Checa. Matej Bel University; Eslovaquia
Fil: Paloncýová, Markéta. Univerzita Palackého V Olomouci; República Checa
Fil: Scheibe, Magdalena. Univerzita Palackého V Olomouci; República Checa
Fil: Kalytchuk, Sergii. Univerzita Palackého V Olomouci; República Checa
Fil: Zoppellaro, Giorgio. Univerzita Palackého V Olomouci; República Checa
Fil: Kment, Štěpán. Univerzita Palackého V Olomouci; República Checa
Fil: Cadranel, Alejandro. Universitat Erlangen-Nuremberg; Alemania. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Bakandritsos, Aristides. Univerzita Palackého V Olomouci; República Checa
Fil: Guldi, Dirk. Universitat Erlangen-Nuremberg; Alemania
Fil: Otyepka, Michal. Univerzita Palackého V Olomouci; República Checa
Fil: Zbořil, Radek. Univerzita Palackého V Olomouci; República Checa
description One of the UN Sustainable Development Goals is to ensure universal access to clean drinking water. Among the various types of water contaminants, mercury (Hg) is considered to be one of the most dangerous ones. It is mostly its immense toxicity and vast environmental impact that stand out. To tackle the issue of monitoring water quality, a nanosensor based on carbon dots (CDs) is developed, whose surface is functionalized with carboxylic groups. CDs show Hg2+ concentration-dependent photoluminescence (PL) lifetimes along with an ultrahigh sensitivity and selectivity. The selectivity of PL quenching by Hg2+ is rationalized by performing light-induced electron paramagnetic resonance (LEPR) spectroscopy showing significant perturbation of the CD photoexcited state upon Hg2+ binding. The experimental findings are supported by time-dependent density functional theory (TD-DFT) calculations. These unveiled the emergence of a low-lying charge transfer state involving a vacant 6s orbital of Hg2+ stabilized by relativistic effects.
publishDate 2023
dc.date.none.fl_str_mv 2023-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/228653
Zdražil, Lukáš; Panáček, David; Sedajová, Veronika; Baďura, Zdeněk; Langer, Michal; et al.; Carbon Dots Enabling Parts-Per-Billion Sensitive and Ultraselective Photoluminescence Lifetime-Based Sensing of Inorganic Mercury; John Wiley & Sons Ltd; Advanced Optical Materials; 11; 21; 7-2023; 1-8
2195-1071
CONICET Digital
CONICET
url http://hdl.handle.net/11336/228653
identifier_str_mv Zdražil, Lukáš; Panáček, David; Sedajová, Veronika; Baďura, Zdeněk; Langer, Michal; et al.; Carbon Dots Enabling Parts-Per-Billion Sensitive and Ultraselective Photoluminescence Lifetime-Based Sensing of Inorganic Mercury; John Wiley & Sons Ltd; Advanced Optical Materials; 11; 21; 7-2023; 1-8
2195-1071
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1002/adom.202300750
info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/10.1002/adom.202300750
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv John Wiley & Sons Ltd
publisher.none.fl_str_mv John Wiley & Sons Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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