Synthesis and characterization of Co3O4 nanoparticles for use as pigments in solar absorbing paints

Autores
Gardey Merino, María Celeste; Rodriguez Ibarra, Mariana Estela; Lascalea, Gustavo Enrique; Vazquez, Patricia Graciela
Año de publicación
2021
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
This aim of this research is to produce Co3O4 oxide by means of one-step solution novel combustion methods usingaspatic acid (C4H7NO4); lysine (C6H14N2O2); tris (hydroximethyl) aminomethane (NH2C (CH2OH)3) and ethylene diaminetetra-acetic acid (C10H16N2O8) as fuels. The pigments were characterized using X-ray diffraction, scanning andtransmission electron microscopy, infrared spectroscopy with Fourier transform and UV-VIS-IR Spectrophotometry.The paint based on alkyd resin was made from pigments obtained (Co3O4 oxide). In order to make a comparison of thethermal emittance of the paint, two different formulations were prepared and these coating are named "absorbent paintcoating": one that included 1% by weight of aluminum in metallic powder and another, with 1% of copper in metallicpowder, respectively. The solar absorbance for the Co3O4 powders, plus quartz cuvette, gave a value of 0.9 in all cases.An extraordinary value of absorption on the coatings between 95 and 96% was noted. These results suggested that thesynthesis of combustion in solution makes it possible to obtain a Co3O4 absorbent pigment with different fuels.These syntheses have a low environmental impact because they are one-step processes. All use low amounts of reactiveash obtained at a calcination of about 500 °C. These results suggest the possibility of utilizing this oxide in absorbentsolar paints.
Fil: Gardey Merino, María Celeste. Universidad Tecnológica Nacional. Facultad Regional Mendoza. Grupo CLIOPE. Energía, Ambiente y Desarrollo Sustentable; Argentina
Fil: Rodriguez Ibarra, Mariana Estela. Universidad Tecnológica Nacional. Facultad Regional Mendoza. Grupo CLIOPE. Energía, Ambiente y Desarrollo Sustentable; Argentina
Fil: Lascalea, Gustavo Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto Argentino de Nivología, Glaciología y Ciencias Ambientales. Provincia de Mendoza. Instituto Argentino de Nivología, Glaciología y Ciencias Ambientales. Universidad Nacional de Cuyo. Instituto Argentino de Nivología, Glaciología y Ciencias Ambientales; Argentina
Fil: Vazquez, Patricia Graciela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Materia
NANOPARTICLES
COMBUSTION SYNTHESIS
SOLAR ABSORPTION
SOLAR ABSORBING PAINTS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/170843
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/170843
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Synthesis and characterization of Co3O4 nanoparticles for use as pigments in solar absorbing paintsGardey Merino, María CelesteRodriguez Ibarra, Mariana EstelaLascalea, Gustavo EnriqueVazquez, Patricia GracielaNANOPARTICLESCOMBUSTION SYNTHESISSOLAR ABSORPTIONSOLAR ABSORBING PAINTShttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2This aim of this research is to produce Co3O4 oxide by means of one-step solution novel combustion methods usingaspatic acid (C4H7NO4); lysine (C6H14N2O2); tris (hydroximethyl) aminomethane (NH2C (CH2OH)3) and ethylene diaminetetra-acetic acid (C10H16N2O8) as fuels. The pigments were characterized using X-ray diffraction, scanning andtransmission electron microscopy, infrared spectroscopy with Fourier transform and UV-VIS-IR Spectrophotometry.The paint based on alkyd resin was made from pigments obtained (Co3O4 oxide). In order to make a comparison of thethermal emittance of the paint, two different formulations were prepared and these coating are named "absorbent paintcoating": one that included 1% by weight of aluminum in metallic powder and another, with 1% of copper in metallicpowder, respectively. The solar absorbance for the Co3O4 powders, plus quartz cuvette, gave a value of 0.9 in all cases.An extraordinary value of absorption on the coatings between 95 and 96% was noted. These results suggested that thesynthesis of combustion in solution makes it possible to obtain a Co3O4 absorbent pigment with different fuels.These syntheses have a low environmental impact because they are one-step processes. All use low amounts of reactiveash obtained at a calcination of about 500 °C. These results suggest the possibility of utilizing this oxide in absorbentsolar paints.Fil: Gardey Merino, María Celeste. Universidad Tecnológica Nacional. Facultad Regional Mendoza. Grupo CLIOPE. Energía, Ambiente y Desarrollo Sustentable; ArgentinaFil: Rodriguez Ibarra, Mariana Estela. Universidad Tecnológica Nacional. Facultad Regional Mendoza. Grupo CLIOPE. Energía, Ambiente y Desarrollo Sustentable; ArgentinaFil: Lascalea, Gustavo Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto Argentino de Nivología, Glaciología y Ciencias Ambientales. Provincia de Mendoza. Instituto Argentino de Nivología, Glaciología y Ciencias Ambientales. Universidad Nacional de Cuyo. Instituto Argentino de Nivología, Glaciología y Ciencias Ambientales; ArgentinaFil: Vazquez, Patricia Graciela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaCollege of Engineering Mangalore2021-06-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/170843Gardey Merino, María Celeste; Rodriguez Ibarra, Mariana Estela; Lascalea, Gustavo Enrique; Vazquez, Patricia Graciela; Synthesis and characterization of Co3O4 nanoparticles for use as pigments in solar absorbing paints; College of Engineering Mangalore; GSC Advanced Engineering and Technology; 1; 2; 1-6-2021; 7-20CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://gsconlinepress.com/journals/gscaet/content/synthesis-and-characterization-co3o4-nanoparticles-use-pigments-solar-absorbing-paintsinfo:eu-repo/semantics/altIdentifier/doi/10.30574/gscaet.2021.1.2.0033info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:35:29Zoai:ri.conicet.gov.ar:11336/170843instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:35:30.031CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Synthesis and characterization of Co3O4 nanoparticles for use as pigments in solar absorbing paints
title Synthesis and characterization of Co3O4 nanoparticles for use as pigments in solar absorbing paints
spellingShingle Synthesis and characterization of Co3O4 nanoparticles for use as pigments in solar absorbing paints
Gardey Merino, María Celeste
NANOPARTICLES
COMBUSTION SYNTHESIS
SOLAR ABSORPTION
SOLAR ABSORBING PAINTS
title_short Synthesis and characterization of Co3O4 nanoparticles for use as pigments in solar absorbing paints
title_full Synthesis and characterization of Co3O4 nanoparticles for use as pigments in solar absorbing paints
title_fullStr Synthesis and characterization of Co3O4 nanoparticles for use as pigments in solar absorbing paints
title_full_unstemmed Synthesis and characterization of Co3O4 nanoparticles for use as pigments in solar absorbing paints
title_sort Synthesis and characterization of Co3O4 nanoparticles for use as pigments in solar absorbing paints
dc.creator.none.fl_str_mv Gardey Merino, María Celeste
Rodriguez Ibarra, Mariana Estela
Lascalea, Gustavo Enrique
Vazquez, Patricia Graciela
author Gardey Merino, María Celeste
author_facet Gardey Merino, María Celeste
Rodriguez Ibarra, Mariana Estela
Lascalea, Gustavo Enrique
Vazquez, Patricia Graciela
author_role author
author2 Rodriguez Ibarra, Mariana Estela
Lascalea, Gustavo Enrique
Vazquez, Patricia Graciela
author2_role author
author
author
dc.subject.none.fl_str_mv NANOPARTICLES
COMBUSTION SYNTHESIS
SOLAR ABSORPTION
SOLAR ABSORBING PAINTS
topic NANOPARTICLES
COMBUSTION SYNTHESIS
SOLAR ABSORPTION
SOLAR ABSORBING PAINTS
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv This aim of this research is to produce Co3O4 oxide by means of one-step solution novel combustion methods usingaspatic acid (C4H7NO4); lysine (C6H14N2O2); tris (hydroximethyl) aminomethane (NH2C (CH2OH)3) and ethylene diaminetetra-acetic acid (C10H16N2O8) as fuels. The pigments were characterized using X-ray diffraction, scanning andtransmission electron microscopy, infrared spectroscopy with Fourier transform and UV-VIS-IR Spectrophotometry.The paint based on alkyd resin was made from pigments obtained (Co3O4 oxide). In order to make a comparison of thethermal emittance of the paint, two different formulations were prepared and these coating are named "absorbent paintcoating": one that included 1% by weight of aluminum in metallic powder and another, with 1% of copper in metallicpowder, respectively. The solar absorbance for the Co3O4 powders, plus quartz cuvette, gave a value of 0.9 in all cases.An extraordinary value of absorption on the coatings between 95 and 96% was noted. These results suggested that thesynthesis of combustion in solution makes it possible to obtain a Co3O4 absorbent pigment with different fuels.These syntheses have a low environmental impact because they are one-step processes. All use low amounts of reactiveash obtained at a calcination of about 500 °C. These results suggest the possibility of utilizing this oxide in absorbentsolar paints.
Fil: Gardey Merino, María Celeste. Universidad Tecnológica Nacional. Facultad Regional Mendoza. Grupo CLIOPE. Energía, Ambiente y Desarrollo Sustentable; Argentina
Fil: Rodriguez Ibarra, Mariana Estela. Universidad Tecnológica Nacional. Facultad Regional Mendoza. Grupo CLIOPE. Energía, Ambiente y Desarrollo Sustentable; Argentina
Fil: Lascalea, Gustavo Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto Argentino de Nivología, Glaciología y Ciencias Ambientales. Provincia de Mendoza. Instituto Argentino de Nivología, Glaciología y Ciencias Ambientales. Universidad Nacional de Cuyo. Instituto Argentino de Nivología, Glaciología y Ciencias Ambientales; Argentina
Fil: Vazquez, Patricia Graciela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
description This aim of this research is to produce Co3O4 oxide by means of one-step solution novel combustion methods usingaspatic acid (C4H7NO4); lysine (C6H14N2O2); tris (hydroximethyl) aminomethane (NH2C (CH2OH)3) and ethylene diaminetetra-acetic acid (C10H16N2O8) as fuels. The pigments were characterized using X-ray diffraction, scanning andtransmission electron microscopy, infrared spectroscopy with Fourier transform and UV-VIS-IR Spectrophotometry.The paint based on alkyd resin was made from pigments obtained (Co3O4 oxide). In order to make a comparison of thethermal emittance of the paint, two different formulations were prepared and these coating are named "absorbent paintcoating": one that included 1% by weight of aluminum in metallic powder and another, with 1% of copper in metallicpowder, respectively. The solar absorbance for the Co3O4 powders, plus quartz cuvette, gave a value of 0.9 in all cases.An extraordinary value of absorption on the coatings between 95 and 96% was noted. These results suggested that thesynthesis of combustion in solution makes it possible to obtain a Co3O4 absorbent pigment with different fuels.These syntheses have a low environmental impact because they are one-step processes. All use low amounts of reactiveash obtained at a calcination of about 500 °C. These results suggest the possibility of utilizing this oxide in absorbentsolar paints.
publishDate 2021
dc.date.none.fl_str_mv 2021-06-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/170843
Gardey Merino, María Celeste; Rodriguez Ibarra, Mariana Estela; Lascalea, Gustavo Enrique; Vazquez, Patricia Graciela; Synthesis and characterization of Co3O4 nanoparticles for use as pigments in solar absorbing paints; College of Engineering Mangalore; GSC Advanced Engineering and Technology; 1; 2; 1-6-2021; 7-20
CONICET Digital
CONICET
url http://hdl.handle.net/11336/170843
identifier_str_mv Gardey Merino, María Celeste; Rodriguez Ibarra, Mariana Estela; Lascalea, Gustavo Enrique; Vazquez, Patricia Graciela; Synthesis and characterization of Co3O4 nanoparticles for use as pigments in solar absorbing paints; College of Engineering Mangalore; GSC Advanced Engineering and Technology; 1; 2; 1-6-2021; 7-20
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://gsconlinepress.com/journals/gscaet/content/synthesis-and-characterization-co3o4-nanoparticles-use-pigments-solar-absorbing-paints
info:eu-repo/semantics/altIdentifier/doi/10.30574/gscaet.2021.1.2.0033
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv College of Engineering Mangalore
publisher.none.fl_str_mv College of Engineering Mangalore
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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