Compatibilization and properties of EVA copolymers containing surface-functionalized cellulose microfibers
- Autores
- Pracella, Mariano; Minhaz-Ul Haque, M.; Alvarez, Vera Alejandra
- Año de publicación
- 2010
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Cellulose microfibers were modified with two different bi-functional monomers. Composites of EVA copolymer with modified and unmodified cellulose were prepared by melt mixing. The samples were analyzed by SEM, XRD, FT-IR, DSC, TGA, DMTA and tensile mechanical tests. SEM showed that the presence of reactive groups on cellulose surface enhanced the compatibility,improving the fiber/matrix interfacial adhesion.FT-IR disclosed the occurrence of chemical reactions between the functionalized cellulose and polymer chains. The incorporation of fibers affected the crystallization behaviour and crystallinity of the polymer matrix. Composites with GMA modified cellulose displayed better compatibility, higher thermal and mechanical properties.
Fil: Pracella, Mariano. Institute of Composite and Biomedical Materials; Italia
Fil: Minhaz-Ul Haque, M.. Universita Degli Studi Di Pisa; Italia
Fil: Alvarez, Vera Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina - Materia
-
Cellulose Microfibers
Eva Copolymer
Fber/Matrix Interfacial Adhesion
Chemical Modification - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/13302
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Compatibilization and properties of EVA copolymers containing surface-functionalized cellulose microfibersPracella, MarianoMinhaz-Ul Haque, M.Alvarez, Vera AlejandraCellulose MicrofibersEva CopolymerFber/Matrix Interfacial AdhesionChemical Modificationhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2https://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Cellulose microfibers were modified with two different bi-functional monomers. Composites of EVA copolymer with modified and unmodified cellulose were prepared by melt mixing. The samples were analyzed by SEM, XRD, FT-IR, DSC, TGA, DMTA and tensile mechanical tests. SEM showed that the presence of reactive groups on cellulose surface enhanced the compatibility,improving the fiber/matrix interfacial adhesion.FT-IR disclosed the occurrence of chemical reactions between the functionalized cellulose and polymer chains. The incorporation of fibers affected the crystallization behaviour and crystallinity of the polymer matrix. Composites with GMA modified cellulose displayed better compatibility, higher thermal and mechanical properties.Fil: Pracella, Mariano. Institute of Composite and Biomedical Materials; ItaliaFil: Minhaz-Ul Haque, M.. Universita Degli Studi Di Pisa; ItaliaFil: Alvarez, Vera Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaWiley Vch Verlag2010-08-16info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/13302Pracella, Mariano; Minhaz-Ul Haque, M.; Alvarez, Vera Alejandra; Compatibilization and properties of EVA copolymers containing surface-functionalized cellulose microfibers; Wiley Vch Verlag; Macromolecular Materials And Engineering (print); 295; 10; 16-8-2010; 949-9571438-7492enginfo:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/mame.201000175/abstractinfo:eu-repo/semantics/altIdentifier/doi/10.1002/mame.201000175info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:39:30Zoai:ri.conicet.gov.ar:11336/13302instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:39:31.147CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Compatibilization and properties of EVA copolymers containing surface-functionalized cellulose microfibers |
title |
Compatibilization and properties of EVA copolymers containing surface-functionalized cellulose microfibers |
spellingShingle |
Compatibilization and properties of EVA copolymers containing surface-functionalized cellulose microfibers Pracella, Mariano Cellulose Microfibers Eva Copolymer Fber/Matrix Interfacial Adhesion Chemical Modification |
title_short |
Compatibilization and properties of EVA copolymers containing surface-functionalized cellulose microfibers |
title_full |
Compatibilization and properties of EVA copolymers containing surface-functionalized cellulose microfibers |
title_fullStr |
Compatibilization and properties of EVA copolymers containing surface-functionalized cellulose microfibers |
title_full_unstemmed |
Compatibilization and properties of EVA copolymers containing surface-functionalized cellulose microfibers |
title_sort |
Compatibilization and properties of EVA copolymers containing surface-functionalized cellulose microfibers |
dc.creator.none.fl_str_mv |
Pracella, Mariano Minhaz-Ul Haque, M. Alvarez, Vera Alejandra |
author |
Pracella, Mariano |
author_facet |
Pracella, Mariano Minhaz-Ul Haque, M. Alvarez, Vera Alejandra |
author_role |
author |
author2 |
Minhaz-Ul Haque, M. Alvarez, Vera Alejandra |
author2_role |
author author |
dc.subject.none.fl_str_mv |
Cellulose Microfibers Eva Copolymer Fber/Matrix Interfacial Adhesion Chemical Modification |
topic |
Cellulose Microfibers Eva Copolymer Fber/Matrix Interfacial Adhesion Chemical Modification |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.5 https://purl.org/becyt/ford/2 https://purl.org/becyt/ford/2.5 https://purl.org/becyt/ford/2 https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
Cellulose microfibers were modified with two different bi-functional monomers. Composites of EVA copolymer with modified and unmodified cellulose were prepared by melt mixing. The samples were analyzed by SEM, XRD, FT-IR, DSC, TGA, DMTA and tensile mechanical tests. SEM showed that the presence of reactive groups on cellulose surface enhanced the compatibility,improving the fiber/matrix interfacial adhesion.FT-IR disclosed the occurrence of chemical reactions between the functionalized cellulose and polymer chains. The incorporation of fibers affected the crystallization behaviour and crystallinity of the polymer matrix. Composites with GMA modified cellulose displayed better compatibility, higher thermal and mechanical properties. Fil: Pracella, Mariano. Institute of Composite and Biomedical Materials; Italia Fil: Minhaz-Ul Haque, M.. Universita Degli Studi Di Pisa; Italia Fil: Alvarez, Vera Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina |
description |
Cellulose microfibers were modified with two different bi-functional monomers. Composites of EVA copolymer with modified and unmodified cellulose were prepared by melt mixing. The samples were analyzed by SEM, XRD, FT-IR, DSC, TGA, DMTA and tensile mechanical tests. SEM showed that the presence of reactive groups on cellulose surface enhanced the compatibility,improving the fiber/matrix interfacial adhesion.FT-IR disclosed the occurrence of chemical reactions between the functionalized cellulose and polymer chains. The incorporation of fibers affected the crystallization behaviour and crystallinity of the polymer matrix. Composites with GMA modified cellulose displayed better compatibility, higher thermal and mechanical properties. |
publishDate |
2010 |
dc.date.none.fl_str_mv |
2010-08-16 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/13302 Pracella, Mariano; Minhaz-Ul Haque, M.; Alvarez, Vera Alejandra; Compatibilization and properties of EVA copolymers containing surface-functionalized cellulose microfibers; Wiley Vch Verlag; Macromolecular Materials And Engineering (print); 295; 10; 16-8-2010; 949-957 1438-7492 |
url |
http://hdl.handle.net/11336/13302 |
identifier_str_mv |
Pracella, Mariano; Minhaz-Ul Haque, M.; Alvarez, Vera Alejandra; Compatibilization and properties of EVA copolymers containing surface-functionalized cellulose microfibers; Wiley Vch Verlag; Macromolecular Materials And Engineering (print); 295; 10; 16-8-2010; 949-957 1438-7492 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/mame.201000175/abstract info:eu-repo/semantics/altIdentifier/doi/10.1002/mame.201000175 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Wiley Vch Verlag |
publisher.none.fl_str_mv |
Wiley Vch Verlag |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844614420776353792 |
score |
13.070432 |