Photophysical properties of Re(I)(CO)3(phen) pendants grafted to a poly-4-vinylpyridine backbone: A correlation between photophysical properties and morphological changes of the ba...

Autores
Saavedra Moncada, Alejandra; Garcia Einschlag, Fernando Sebastian; Prieto, Eduardo Daniel; Ruiz, Gustavo Teodosio; Lappin, Alexander G.; Ferraudi, Guillermo J.; Wolcan, Ezequiel
Año de publicación
2016
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Photochemical and photophysical properties of a polymer, Re-P4VP, consisting of single bondRe(I)(CO)3(phen) pendants grafted to a poly-4-vinylpyridine backbone, P4VP, were interpreted on the bases of morphological transformations. These transformations are responsible of a significant increase of the MLCTRe(I)→phen excited state luminescence lifetime when the polymer concentration is increased. Also a nearly 8-fold increase in the luminescence quantum yield resulted from the protonation of Re-P4VP with consequent changes of the excited state decay kinetics. Results of TEM and AFM morphological studies on P4VP and Re-P4VP in the presence of HClO4 acid, i.e., to form Re-P4VPHnn+, revealed that they have concentration dependent morphologies. From low to large concentrations of the Re-P4VP polymer, the morphology of Re-P4VP varies from a nonhomogeneous distribution of spherical nanoaggregates coexisting with micrometer size fibers to an homogeneous distribution of spherical nanoaggregates with diameters around 25 nm. The Re-P4VP morphology is also altered when the polymer pyridines are protonated. Protonation of diluted solutions of Re-P4VP polymers decrease the sizes of the nanoaggregates and small objects with diameters smaller than 10 nm appear.
Fil: Saavedra Moncada, Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Garcia Einschlag, Fernando Sebastian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Prieto, Eduardo Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Ruiz, Gustavo Teodosio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Lappin, Alexander G.. University of Notre Dame; Estados Unidos
Fil: Ferraudi, Guillermo J.. University of Notre Dame; Estados Unidos
Fil: Wolcan, Ezequiel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Materia
-Re(Co)3(Phen) Pendants
Photophysics
Poly(4-Vinylpyridine)
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/48733
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/48733
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Photophysical properties of Re(I)(CO)3(phen) pendants grafted to a poly-4-vinylpyridine backbone: A correlation between photophysical properties and morphological changes of the backboneSaavedra Moncada, AlejandraGarcia Einschlag, Fernando SebastianPrieto, Eduardo DanielRuiz, Gustavo TeodosioLappin, Alexander G.Ferraudi, Guillermo J.Wolcan, Ezequiel-Re(Co)3(Phen) PendantsPhotophysicsPoly(4-Vinylpyridine)https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Photochemical and photophysical properties of a polymer, Re-P4VP, consisting of single bondRe(I)(CO)3(phen) pendants grafted to a poly-4-vinylpyridine backbone, P4VP, were interpreted on the bases of morphological transformations. These transformations are responsible of a significant increase of the MLCTRe(I)→phen excited state luminescence lifetime when the polymer concentration is increased. Also a nearly 8-fold increase in the luminescence quantum yield resulted from the protonation of Re-P4VP with consequent changes of the excited state decay kinetics. Results of TEM and AFM morphological studies on P4VP and Re-P4VP in the presence of HClO4 acid, i.e., to form Re-P4VPHnn+, revealed that they have concentration dependent morphologies. From low to large concentrations of the Re-P4VP polymer, the morphology of Re-P4VP varies from a nonhomogeneous distribution of spherical nanoaggregates coexisting with micrometer size fibers to an homogeneous distribution of spherical nanoaggregates with diameters around 25 nm. The Re-P4VP morphology is also altered when the polymer pyridines are protonated. Protonation of diluted solutions of Re-P4VP polymers decrease the sizes of the nanoaggregates and small objects with diameters smaller than 10 nm appear.Fil: Saavedra Moncada, Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Garcia Einschlag, Fernando Sebastian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Prieto, Eduardo Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Ruiz, Gustavo Teodosio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Lappin, Alexander G.. University of Notre Dame; Estados UnidosFil: Ferraudi, Guillermo J.. University of Notre Dame; Estados UnidosFil: Wolcan, Ezequiel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaElsevier Science Sa2016-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/48733Saavedra Moncada, Alejandra; Garcia Einschlag, Fernando Sebastian; Prieto, Eduardo Daniel; Ruiz, Gustavo Teodosio; Lappin, Alexander G.; et al.; Photophysical properties of Re(I)(CO)3(phen) pendants grafted to a poly-4-vinylpyridine backbone: A correlation between photophysical properties and morphological changes of the backbone; Elsevier Science Sa; Journal of Photochemistry and Photobiology A: Chemistry; 321; 5-2016; 284-2961010-6030CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.jphotochem.2016.01.001info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1010603015301799info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:07:06Zoai:ri.conicet.gov.ar:11336/48733instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:07:07.185CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Photophysical properties of Re(I)(CO)3(phen) pendants grafted to a poly-4-vinylpyridine backbone: A correlation between photophysical properties and morphological changes of the backbone
title Photophysical properties of Re(I)(CO)3(phen) pendants grafted to a poly-4-vinylpyridine backbone: A correlation between photophysical properties and morphological changes of the backbone
spellingShingle Photophysical properties of Re(I)(CO)3(phen) pendants grafted to a poly-4-vinylpyridine backbone: A correlation between photophysical properties and morphological changes of the backbone
Saavedra Moncada, Alejandra
-Re(Co)3(Phen) Pendants
Photophysics
Poly(4-Vinylpyridine)
title_short Photophysical properties of Re(I)(CO)3(phen) pendants grafted to a poly-4-vinylpyridine backbone: A correlation between photophysical properties and morphological changes of the backbone
title_full Photophysical properties of Re(I)(CO)3(phen) pendants grafted to a poly-4-vinylpyridine backbone: A correlation between photophysical properties and morphological changes of the backbone
title_fullStr Photophysical properties of Re(I)(CO)3(phen) pendants grafted to a poly-4-vinylpyridine backbone: A correlation between photophysical properties and morphological changes of the backbone
title_full_unstemmed Photophysical properties of Re(I)(CO)3(phen) pendants grafted to a poly-4-vinylpyridine backbone: A correlation between photophysical properties and morphological changes of the backbone
title_sort Photophysical properties of Re(I)(CO)3(phen) pendants grafted to a poly-4-vinylpyridine backbone: A correlation between photophysical properties and morphological changes of the backbone
dc.creator.none.fl_str_mv Saavedra Moncada, Alejandra
Garcia Einschlag, Fernando Sebastian
Prieto, Eduardo Daniel
Ruiz, Gustavo Teodosio
Lappin, Alexander G.
Ferraudi, Guillermo J.
Wolcan, Ezequiel
author Saavedra Moncada, Alejandra
author_facet Saavedra Moncada, Alejandra
Garcia Einschlag, Fernando Sebastian
Prieto, Eduardo Daniel
Ruiz, Gustavo Teodosio
Lappin, Alexander G.
Ferraudi, Guillermo J.
Wolcan, Ezequiel
author_role author
author2 Garcia Einschlag, Fernando Sebastian
Prieto, Eduardo Daniel
Ruiz, Gustavo Teodosio
Lappin, Alexander G.
Ferraudi, Guillermo J.
Wolcan, Ezequiel
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv -Re(Co)3(Phen) Pendants
Photophysics
Poly(4-Vinylpyridine)
topic -Re(Co)3(Phen) Pendants
Photophysics
Poly(4-Vinylpyridine)
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Photochemical and photophysical properties of a polymer, Re-P4VP, consisting of single bondRe(I)(CO)3(phen) pendants grafted to a poly-4-vinylpyridine backbone, P4VP, were interpreted on the bases of morphological transformations. These transformations are responsible of a significant increase of the MLCTRe(I)→phen excited state luminescence lifetime when the polymer concentration is increased. Also a nearly 8-fold increase in the luminescence quantum yield resulted from the protonation of Re-P4VP with consequent changes of the excited state decay kinetics. Results of TEM and AFM morphological studies on P4VP and Re-P4VP in the presence of HClO4 acid, i.e., to form Re-P4VPHnn+, revealed that they have concentration dependent morphologies. From low to large concentrations of the Re-P4VP polymer, the morphology of Re-P4VP varies from a nonhomogeneous distribution of spherical nanoaggregates coexisting with micrometer size fibers to an homogeneous distribution of spherical nanoaggregates with diameters around 25 nm. The Re-P4VP morphology is also altered when the polymer pyridines are protonated. Protonation of diluted solutions of Re-P4VP polymers decrease the sizes of the nanoaggregates and small objects with diameters smaller than 10 nm appear.
Fil: Saavedra Moncada, Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Garcia Einschlag, Fernando Sebastian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Prieto, Eduardo Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Ruiz, Gustavo Teodosio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Lappin, Alexander G.. University of Notre Dame; Estados Unidos
Fil: Ferraudi, Guillermo J.. University of Notre Dame; Estados Unidos
Fil: Wolcan, Ezequiel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
description Photochemical and photophysical properties of a polymer, Re-P4VP, consisting of single bondRe(I)(CO)3(phen) pendants grafted to a poly-4-vinylpyridine backbone, P4VP, were interpreted on the bases of morphological transformations. These transformations are responsible of a significant increase of the MLCTRe(I)→phen excited state luminescence lifetime when the polymer concentration is increased. Also a nearly 8-fold increase in the luminescence quantum yield resulted from the protonation of Re-P4VP with consequent changes of the excited state decay kinetics. Results of TEM and AFM morphological studies on P4VP and Re-P4VP in the presence of HClO4 acid, i.e., to form Re-P4VPHnn+, revealed that they have concentration dependent morphologies. From low to large concentrations of the Re-P4VP polymer, the morphology of Re-P4VP varies from a nonhomogeneous distribution of spherical nanoaggregates coexisting with micrometer size fibers to an homogeneous distribution of spherical nanoaggregates with diameters around 25 nm. The Re-P4VP morphology is also altered when the polymer pyridines are protonated. Protonation of diluted solutions of Re-P4VP polymers decrease the sizes of the nanoaggregates and small objects with diameters smaller than 10 nm appear.
publishDate 2016
dc.date.none.fl_str_mv 2016-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/48733
Saavedra Moncada, Alejandra; Garcia Einschlag, Fernando Sebastian; Prieto, Eduardo Daniel; Ruiz, Gustavo Teodosio; Lappin, Alexander G.; et al.; Photophysical properties of Re(I)(CO)3(phen) pendants grafted to a poly-4-vinylpyridine backbone: A correlation between photophysical properties and morphological changes of the backbone; Elsevier Science Sa; Journal of Photochemistry and Photobiology A: Chemistry; 321; 5-2016; 284-296
1010-6030
CONICET Digital
CONICET
url http://hdl.handle.net/11336/48733
identifier_str_mv Saavedra Moncada, Alejandra; Garcia Einschlag, Fernando Sebastian; Prieto, Eduardo Daniel; Ruiz, Gustavo Teodosio; Lappin, Alexander G.; et al.; Photophysical properties of Re(I)(CO)3(phen) pendants grafted to a poly-4-vinylpyridine backbone: A correlation between photophysical properties and morphological changes of the backbone; Elsevier Science Sa; Journal of Photochemistry and Photobiology A: Chemistry; 321; 5-2016; 284-296
1010-6030
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jphotochem.2016.01.001
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1010603015301799
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science Sa
publisher.none.fl_str_mv Elsevier Science Sa
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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