Generation of a low temperature NO linkage isomer in a transition metal complex of group 9: K[IrCl5NO]
- Autores
- Guida, Jorge Alberto
- Año de publicación
- 2013
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The [IrCl5NO]−1 ion in the potassium salt can be partially transformed into a metastable state by light irradiation in the violet-near UV region at low temperature (77 K). The excitation process was followed by infrared spectroscopy, comparing the spectra before and after irradiation. A new band grew at 1812 cm−1 after irradiation with light in the 308–420 nm spectral region. The metastable state behavior is verified as this band decays upon heating the samples above 90 K or by subsequent irradiation using 450–680 nm light. The band at 1812 cm−1 was assigned to ν(NO) of metastable state 1 (or an IrON linkage isomer) for comparison with the band position reported for other transition metal nitrosyls. To our knowledge, this is the first generation of a M-ON linkage isomer reported for a nitrosyl of transition metal of group 9. Its behavior is similar to that observed in other nitrosyl complexes of group 8.
Fil: Guida, Jorge Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina - Materia
-
Metastable States
Low Temperature Infrared
Nitrosyl Complexes
Iridium Complexes
Photoexcited Complexes
Linkage Isomers - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/24135
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spelling |
Generation of a low temperature NO linkage isomer in a transition metal complex of group 9: K[IrCl5NO]Guida, Jorge AlbertoMetastable StatesLow Temperature InfraredNitrosyl ComplexesIridium ComplexesPhotoexcited ComplexesLinkage Isomershttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The [IrCl5NO]−1 ion in the potassium salt can be partially transformed into a metastable state by light irradiation in the violet-near UV region at low temperature (77 K). The excitation process was followed by infrared spectroscopy, comparing the spectra before and after irradiation. A new band grew at 1812 cm−1 after irradiation with light in the 308–420 nm spectral region. The metastable state behavior is verified as this band decays upon heating the samples above 90 K or by subsequent irradiation using 450–680 nm light. The band at 1812 cm−1 was assigned to ν(NO) of metastable state 1 (or an IrON linkage isomer) for comparison with the band position reported for other transition metal nitrosyls. To our knowledge, this is the first generation of a M-ON linkage isomer reported for a nitrosyl of transition metal of group 9. Its behavior is similar to that observed in other nitrosyl complexes of group 8.Fil: Guida, Jorge Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaElsevier Science2013-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/24135Guida, Jorge Alberto; Generation of a low temperature NO linkage isomer in a transition metal complex of group 9: K[IrCl5NO]; Elsevier Science; Inorganic Chemistry Communications; 33; 7-2013; 75-771387-7003CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.inoche.2013.03.022info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1387700313001238info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:42:41Zoai:ri.conicet.gov.ar:11336/24135instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:42:41.758CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Generation of a low temperature NO linkage isomer in a transition metal complex of group 9: K[IrCl5NO] |
title |
Generation of a low temperature NO linkage isomer in a transition metal complex of group 9: K[IrCl5NO] |
spellingShingle |
Generation of a low temperature NO linkage isomer in a transition metal complex of group 9: K[IrCl5NO] Guida, Jorge Alberto Metastable States Low Temperature Infrared Nitrosyl Complexes Iridium Complexes Photoexcited Complexes Linkage Isomers |
title_short |
Generation of a low temperature NO linkage isomer in a transition metal complex of group 9: K[IrCl5NO] |
title_full |
Generation of a low temperature NO linkage isomer in a transition metal complex of group 9: K[IrCl5NO] |
title_fullStr |
Generation of a low temperature NO linkage isomer in a transition metal complex of group 9: K[IrCl5NO] |
title_full_unstemmed |
Generation of a low temperature NO linkage isomer in a transition metal complex of group 9: K[IrCl5NO] |
title_sort |
Generation of a low temperature NO linkage isomer in a transition metal complex of group 9: K[IrCl5NO] |
dc.creator.none.fl_str_mv |
Guida, Jorge Alberto |
author |
Guida, Jorge Alberto |
author_facet |
Guida, Jorge Alberto |
author_role |
author |
dc.subject.none.fl_str_mv |
Metastable States Low Temperature Infrared Nitrosyl Complexes Iridium Complexes Photoexcited Complexes Linkage Isomers |
topic |
Metastable States Low Temperature Infrared Nitrosyl Complexes Iridium Complexes Photoexcited Complexes Linkage Isomers |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
The [IrCl5NO]−1 ion in the potassium salt can be partially transformed into a metastable state by light irradiation in the violet-near UV region at low temperature (77 K). The excitation process was followed by infrared spectroscopy, comparing the spectra before and after irradiation. A new band grew at 1812 cm−1 after irradiation with light in the 308–420 nm spectral region. The metastable state behavior is verified as this band decays upon heating the samples above 90 K or by subsequent irradiation using 450–680 nm light. The band at 1812 cm−1 was assigned to ν(NO) of metastable state 1 (or an IrON linkage isomer) for comparison with the band position reported for other transition metal nitrosyls. To our knowledge, this is the first generation of a M-ON linkage isomer reported for a nitrosyl of transition metal of group 9. Its behavior is similar to that observed in other nitrosyl complexes of group 8. Fil: Guida, Jorge Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina |
description |
The [IrCl5NO]−1 ion in the potassium salt can be partially transformed into a metastable state by light irradiation in the violet-near UV region at low temperature (77 K). The excitation process was followed by infrared spectroscopy, comparing the spectra before and after irradiation. A new band grew at 1812 cm−1 after irradiation with light in the 308–420 nm spectral region. The metastable state behavior is verified as this band decays upon heating the samples above 90 K or by subsequent irradiation using 450–680 nm light. The band at 1812 cm−1 was assigned to ν(NO) of metastable state 1 (or an IrON linkage isomer) for comparison with the band position reported for other transition metal nitrosyls. To our knowledge, this is the first generation of a M-ON linkage isomer reported for a nitrosyl of transition metal of group 9. Its behavior is similar to that observed in other nitrosyl complexes of group 8. |
publishDate |
2013 |
dc.date.none.fl_str_mv |
2013-07 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/24135 Guida, Jorge Alberto; Generation of a low temperature NO linkage isomer in a transition metal complex of group 9: K[IrCl5NO]; Elsevier Science; Inorganic Chemistry Communications; 33; 7-2013; 75-77 1387-7003 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/24135 |
identifier_str_mv |
Guida, Jorge Alberto; Generation of a low temperature NO linkage isomer in a transition metal complex of group 9: K[IrCl5NO]; Elsevier Science; Inorganic Chemistry Communications; 33; 7-2013; 75-77 1387-7003 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.inoche.2013.03.022 info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1387700313001238 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science |
publisher.none.fl_str_mv |
Elsevier Science |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844614460587638784 |
score |
13.070432 |