Generation of a low temperature NO linkage isomer in a transition metal complex of group 9: K[IrCl5NO]

Autores
Guida, Jorge Alberto
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The [IrCl5NO]−1 ion in the potassium salt can be partially transformed into a metastable state by light irradiation in the violet-near UV region at low temperature (77 K). The excitation process was followed by infrared spectroscopy, comparing the spectra before and after irradiation. A new band grew at 1812 cm−1 after irradiation with light in the 308–420 nm spectral region. The metastable state behavior is verified as this band decays upon heating the samples above 90 K or by subsequent irradiation using 450–680 nm light. The band at 1812 cm−1 was assigned to ν(NO) of metastable state 1 (or an IrON linkage isomer) for comparison with the band position reported for other transition metal nitrosyls. To our knowledge, this is the first generation of a M-ON linkage isomer reported for a nitrosyl of transition metal of group 9. Its behavior is similar to that observed in other nitrosyl complexes of group 8.
Fil: Guida, Jorge Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Materia
Metastable States
Low Temperature Infrared
Nitrosyl Complexes
Iridium Complexes
Photoexcited Complexes
Linkage Isomers
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/24135
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/24135
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Generation of a low temperature NO linkage isomer in a transition metal complex of group 9: K[IrCl5NO]Guida, Jorge AlbertoMetastable StatesLow Temperature InfraredNitrosyl ComplexesIridium ComplexesPhotoexcited ComplexesLinkage Isomershttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The [IrCl5NO]−1 ion in the potassium salt can be partially transformed into a metastable state by light irradiation in the violet-near UV region at low temperature (77 K). The excitation process was followed by infrared spectroscopy, comparing the spectra before and after irradiation. A new band grew at 1812 cm−1 after irradiation with light in the 308–420 nm spectral region. The metastable state behavior is verified as this band decays upon heating the samples above 90 K or by subsequent irradiation using 450–680 nm light. The band at 1812 cm−1 was assigned to ν(NO) of metastable state 1 (or an IrON linkage isomer) for comparison with the band position reported for other transition metal nitrosyls. To our knowledge, this is the first generation of a M-ON linkage isomer reported for a nitrosyl of transition metal of group 9. Its behavior is similar to that observed in other nitrosyl complexes of group 8.Fil: Guida, Jorge Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaElsevier Science2013-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/24135Guida, Jorge Alberto; Generation of a low temperature NO linkage isomer in a transition metal complex of group 9: K[IrCl5NO]; Elsevier Science; Inorganic Chemistry Communications; 33; 7-2013; 75-771387-7003CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.inoche.2013.03.022info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1387700313001238info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T12:15:24Zoai:ri.conicet.gov.ar:11336/24135instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 12:15:24.497CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Generation of a low temperature NO linkage isomer in a transition metal complex of group 9: K[IrCl5NO]
title Generation of a low temperature NO linkage isomer in a transition metal complex of group 9: K[IrCl5NO]
spellingShingle Generation of a low temperature NO linkage isomer in a transition metal complex of group 9: K[IrCl5NO]
Guida, Jorge Alberto
Metastable States
Low Temperature Infrared
Nitrosyl Complexes
Iridium Complexes
Photoexcited Complexes
Linkage Isomers
title_short Generation of a low temperature NO linkage isomer in a transition metal complex of group 9: K[IrCl5NO]
title_full Generation of a low temperature NO linkage isomer in a transition metal complex of group 9: K[IrCl5NO]
title_fullStr Generation of a low temperature NO linkage isomer in a transition metal complex of group 9: K[IrCl5NO]
title_full_unstemmed Generation of a low temperature NO linkage isomer in a transition metal complex of group 9: K[IrCl5NO]
title_sort Generation of a low temperature NO linkage isomer in a transition metal complex of group 9: K[IrCl5NO]
dc.creator.none.fl_str_mv Guida, Jorge Alberto
author Guida, Jorge Alberto
author_facet Guida, Jorge Alberto
author_role author
dc.subject.none.fl_str_mv Metastable States
Low Temperature Infrared
Nitrosyl Complexes
Iridium Complexes
Photoexcited Complexes
Linkage Isomers
topic Metastable States
Low Temperature Infrared
Nitrosyl Complexes
Iridium Complexes
Photoexcited Complexes
Linkage Isomers
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The [IrCl5NO]−1 ion in the potassium salt can be partially transformed into a metastable state by light irradiation in the violet-near UV region at low temperature (77 K). The excitation process was followed by infrared spectroscopy, comparing the spectra before and after irradiation. A new band grew at 1812 cm−1 after irradiation with light in the 308–420 nm spectral region. The metastable state behavior is verified as this band decays upon heating the samples above 90 K or by subsequent irradiation using 450–680 nm light. The band at 1812 cm−1 was assigned to ν(NO) of metastable state 1 (or an IrON linkage isomer) for comparison with the band position reported for other transition metal nitrosyls. To our knowledge, this is the first generation of a M-ON linkage isomer reported for a nitrosyl of transition metal of group 9. Its behavior is similar to that observed in other nitrosyl complexes of group 8.
Fil: Guida, Jorge Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
description The [IrCl5NO]−1 ion in the potassium salt can be partially transformed into a metastable state by light irradiation in the violet-near UV region at low temperature (77 K). The excitation process was followed by infrared spectroscopy, comparing the spectra before and after irradiation. A new band grew at 1812 cm−1 after irradiation with light in the 308–420 nm spectral region. The metastable state behavior is verified as this band decays upon heating the samples above 90 K or by subsequent irradiation using 450–680 nm light. The band at 1812 cm−1 was assigned to ν(NO) of metastable state 1 (or an IrON linkage isomer) for comparison with the band position reported for other transition metal nitrosyls. To our knowledge, this is the first generation of a M-ON linkage isomer reported for a nitrosyl of transition metal of group 9. Its behavior is similar to that observed in other nitrosyl complexes of group 8.
publishDate 2013
dc.date.none.fl_str_mv 2013-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/24135
Guida, Jorge Alberto; Generation of a low temperature NO linkage isomer in a transition metal complex of group 9: K[IrCl5NO]; Elsevier Science; Inorganic Chemistry Communications; 33; 7-2013; 75-77
1387-7003
CONICET Digital
CONICET
url http://hdl.handle.net/11336/24135
identifier_str_mv Guida, Jorge Alberto; Generation of a low temperature NO linkage isomer in a transition metal complex of group 9: K[IrCl5NO]; Elsevier Science; Inorganic Chemistry Communications; 33; 7-2013; 75-77
1387-7003
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.inoche.2013.03.022
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1387700313001238
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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