Synthesis of SnO2 nanoparticles through the controlled precipitation route

Autores
Ararat Ibarguen, Carlos Eduardo; Mosquera, A.; Rodriguez Paez, Jorge Enrique; Parra, Rodrigo; Castro, Miriam Susana
Año de publicación
2007
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The controlled precipitation method allowed to the synthesis of SnO2 with advantageous specific properties, such as size and shape employing an aqueous SnCl2·2H2O solution as precursor. Through XRD analyses, the optimum pH value of the solution that yielded the desired product was found to be 6.25. After a thermal treatment at 600 °C, the final powder presented an average particle size below 50 nm with a surface area of 19 m2 g-1 and a large reactivity. The evolution of the most important functional groups during the steps involved in this synthesis route is explained in view of the results obtained with FTIR and XRD. A thorough discussion on the different intermediates involved in the whole process is presented on the basis of hydrolysis and condensation reactions. The conclusions are supported with a complete characterization through differential and gravimetric thermal analysis (DTA/TGA), electron microscopies (SEM/TEM) and surface area determinations (BET).
Fil: Ararat Ibarguen, Carlos Eduardo. Universidad del Cauca; Colombia
Fil: Mosquera, A.. Universidad del Cauca; Colombia
Fil: Rodriguez Paez, Jorge Enrique. Universidad del Cauca; Colombia
Fil: Parra, Rodrigo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Castro, Miriam Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Materia
Chemical Preparation
Controlled Precipitation
Nanoparticles
Powders
Tin Oxide
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/76076
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/76076
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Synthesis of SnO2 nanoparticles through the controlled precipitation routeArarat Ibarguen, Carlos EduardoMosquera, A.Rodriguez Paez, Jorge EnriqueParra, RodrigoCastro, Miriam SusanaChemical PreparationControlled PrecipitationNanoparticlesPowdersTin Oxidehttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1https://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2The controlled precipitation method allowed to the synthesis of SnO2 with advantageous specific properties, such as size and shape employing an aqueous SnCl2·2H2O solution as precursor. Through XRD analyses, the optimum pH value of the solution that yielded the desired product was found to be 6.25. After a thermal treatment at 600 °C, the final powder presented an average particle size below 50 nm with a surface area of 19 m2 g-1 and a large reactivity. The evolution of the most important functional groups during the steps involved in this synthesis route is explained in view of the results obtained with FTIR and XRD. A thorough discussion on the different intermediates involved in the whole process is presented on the basis of hydrolysis and condensation reactions. The conclusions are supported with a complete characterization through differential and gravimetric thermal analysis (DTA/TGA), electron microscopies (SEM/TEM) and surface area determinations (BET).Fil: Ararat Ibarguen, Carlos Eduardo. Universidad del Cauca; ColombiaFil: Mosquera, A.. Universidad del Cauca; ColombiaFil: Rodriguez Paez, Jorge Enrique. Universidad del Cauca; ColombiaFil: Parra, Rodrigo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Castro, Miriam Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaElsevier Science Sa2007-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/76076Ararat Ibarguen, Carlos Eduardo; Mosquera, A.; Rodriguez Paez, Jorge Enrique; Parra, Rodrigo; Castro, Miriam Susana; Synthesis of SnO2 nanoparticles through the controlled precipitation route; Elsevier Science Sa; Materials Chemistry and Physics; 101; 2-3; 2-2007; 433-4400254-0584CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0254058406002252?via%3Dihubinfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.matchemphys.2006.08.003info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T14:25:22Zoai:ri.conicet.gov.ar:11336/76076instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 14:25:22.588CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Synthesis of SnO2 nanoparticles through the controlled precipitation route
title Synthesis of SnO2 nanoparticles through the controlled precipitation route
spellingShingle Synthesis of SnO2 nanoparticles through the controlled precipitation route
Ararat Ibarguen, Carlos Eduardo
Chemical Preparation
Controlled Precipitation
Nanoparticles
Powders
Tin Oxide
title_short Synthesis of SnO2 nanoparticles through the controlled precipitation route
title_full Synthesis of SnO2 nanoparticles through the controlled precipitation route
title_fullStr Synthesis of SnO2 nanoparticles through the controlled precipitation route
title_full_unstemmed Synthesis of SnO2 nanoparticles through the controlled precipitation route
title_sort Synthesis of SnO2 nanoparticles through the controlled precipitation route
dc.creator.none.fl_str_mv Ararat Ibarguen, Carlos Eduardo
Mosquera, A.
Rodriguez Paez, Jorge Enrique
Parra, Rodrigo
Castro, Miriam Susana
author Ararat Ibarguen, Carlos Eduardo
author_facet Ararat Ibarguen, Carlos Eduardo
Mosquera, A.
Rodriguez Paez, Jorge Enrique
Parra, Rodrigo
Castro, Miriam Susana
author_role author
author2 Mosquera, A.
Rodriguez Paez, Jorge Enrique
Parra, Rodrigo
Castro, Miriam Susana
author2_role author
author
author
author
dc.subject.none.fl_str_mv Chemical Preparation
Controlled Precipitation
Nanoparticles
Powders
Tin Oxide
topic Chemical Preparation
Controlled Precipitation
Nanoparticles
Powders
Tin Oxide
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The controlled precipitation method allowed to the synthesis of SnO2 with advantageous specific properties, such as size and shape employing an aqueous SnCl2·2H2O solution as precursor. Through XRD analyses, the optimum pH value of the solution that yielded the desired product was found to be 6.25. After a thermal treatment at 600 °C, the final powder presented an average particle size below 50 nm with a surface area of 19 m2 g-1 and a large reactivity. The evolution of the most important functional groups during the steps involved in this synthesis route is explained in view of the results obtained with FTIR and XRD. A thorough discussion on the different intermediates involved in the whole process is presented on the basis of hydrolysis and condensation reactions. The conclusions are supported with a complete characterization through differential and gravimetric thermal analysis (DTA/TGA), electron microscopies (SEM/TEM) and surface area determinations (BET).
Fil: Ararat Ibarguen, Carlos Eduardo. Universidad del Cauca; Colombia
Fil: Mosquera, A.. Universidad del Cauca; Colombia
Fil: Rodriguez Paez, Jorge Enrique. Universidad del Cauca; Colombia
Fil: Parra, Rodrigo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Castro, Miriam Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
description The controlled precipitation method allowed to the synthesis of SnO2 with advantageous specific properties, such as size and shape employing an aqueous SnCl2·2H2O solution as precursor. Through XRD analyses, the optimum pH value of the solution that yielded the desired product was found to be 6.25. After a thermal treatment at 600 °C, the final powder presented an average particle size below 50 nm with a surface area of 19 m2 g-1 and a large reactivity. The evolution of the most important functional groups during the steps involved in this synthesis route is explained in view of the results obtained with FTIR and XRD. A thorough discussion on the different intermediates involved in the whole process is presented on the basis of hydrolysis and condensation reactions. The conclusions are supported with a complete characterization through differential and gravimetric thermal analysis (DTA/TGA), electron microscopies (SEM/TEM) and surface area determinations (BET).
publishDate 2007
dc.date.none.fl_str_mv 2007-02
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/76076
Ararat Ibarguen, Carlos Eduardo; Mosquera, A.; Rodriguez Paez, Jorge Enrique; Parra, Rodrigo; Castro, Miriam Susana; Synthesis of SnO2 nanoparticles through the controlled precipitation route; Elsevier Science Sa; Materials Chemistry and Physics; 101; 2-3; 2-2007; 433-440
0254-0584
CONICET Digital
CONICET
url http://hdl.handle.net/11336/76076
identifier_str_mv Ararat Ibarguen, Carlos Eduardo; Mosquera, A.; Rodriguez Paez, Jorge Enrique; Parra, Rodrigo; Castro, Miriam Susana; Synthesis of SnO2 nanoparticles through the controlled precipitation route; Elsevier Science Sa; Materials Chemistry and Physics; 101; 2-3; 2-2007; 433-440
0254-0584
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0254058406002252?via%3Dihub
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.matchemphys.2006.08.003
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science Sa
publisher.none.fl_str_mv Elsevier Science Sa
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846082687400411136
score 13.22299

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