Preparation and characterization of activated CMK-1 with Zn and Ni species applied in hydrogen storage

Autores
Juarez, Juliana; Gómez Costa, Marcos Bruno; Anunziata, Oscar Alfredo
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The aim of this work is to prepare CMK‐1 modified with Zn and Ni in order to improve its capacity in hydrogen storage. The approach that we have followed includes synthesis of nanostructures with the experimental study of its adsorption capacity and storage properties. We have shown that CMK‐1 ordered porous carbon modified with metals is a promising material for hydrogen storage. The incorporation of metals was performed by wetness impregnation. The samples were characterized by X‐ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscope, transmission electron microscopy, X‐ray photoelectron spectroscopy, and Brunauer–Emmett–Teller methods. The CMK‐1 modified with Zn showed the highest H2 uptake at 77 K and at low and high pressure (1.5 and 4.4 wt.% at 1 and 10 bar, respectively). The introduction of Ni into CMK‐1 does not increase hydrogen storage capacity at low pressure. However, at a higher pressure (10 bars), Ni‐CMK‐1 displays improved results in hydrogen uptake compared with those of CMK‐1 pristine, 2.4 and 2.1 wt.%, respectively. Copyright © 2015 John Wiley & Sons, Ltd.
Fil: Juarez, Juliana. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina
Fil: Gómez Costa, Marcos Bruno. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina
Fil: Anunziata, Oscar Alfredo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina
Materia
Cmk-1
Zn-Cmk-1
Ni-Cmk-1
Hydrogen
Storage
Composite
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/44896
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/44896
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Preparation and characterization of activated CMK-1 with Zn and Ni species applied in hydrogen storageJuarez, JulianaGómez Costa, Marcos BrunoAnunziata, Oscar AlfredoCmk-1Zn-Cmk-1Ni-Cmk-1HydrogenStorageCompositehttps://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2The aim of this work is to prepare CMK‐1 modified with Zn and Ni in order to improve its capacity in hydrogen storage. The approach that we have followed includes synthesis of nanostructures with the experimental study of its adsorption capacity and storage properties. We have shown that CMK‐1 ordered porous carbon modified with metals is a promising material for hydrogen storage. The incorporation of metals was performed by wetness impregnation. The samples were characterized by X‐ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscope, transmission electron microscopy, X‐ray photoelectron spectroscopy, and Brunauer–Emmett–Teller methods. The CMK‐1 modified with Zn showed the highest H2 uptake at 77 K and at low and high pressure (1.5 and 4.4 wt.% at 1 and 10 bar, respectively). The introduction of Ni into CMK‐1 does not increase hydrogen storage capacity at low pressure. However, at a higher pressure (10 bars), Ni‐CMK‐1 displays improved results in hydrogen uptake compared with those of CMK‐1 pristine, 2.4 and 2.1 wt.%, respectively. Copyright © 2015 John Wiley & Sons, Ltd.Fil: Juarez, Juliana. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; ArgentinaFil: Gómez Costa, Marcos Bruno. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; ArgentinaFil: Anunziata, Oscar Alfredo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; ArgentinaJohn Wiley & Sons Ltd2015-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/44896Juarez, Juliana; Gómez Costa, Marcos Bruno; Anunziata, Oscar Alfredo; Preparation and characterization of activated CMK-1 with Zn and Ni species applied in hydrogen storage; John Wiley & Sons Ltd; International Journal of Energy Research; 39; 7; 6-2015; 941-9530363-907XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1002/er.3298info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/er.3298info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:11:39Zoai:ri.conicet.gov.ar:11336/44896instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:11:40.087CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Preparation and characterization of activated CMK-1 with Zn and Ni species applied in hydrogen storage
title Preparation and characterization of activated CMK-1 with Zn and Ni species applied in hydrogen storage
spellingShingle Preparation and characterization of activated CMK-1 with Zn and Ni species applied in hydrogen storage
Juarez, Juliana
Cmk-1
Zn-Cmk-1
Ni-Cmk-1
Hydrogen
Storage
Composite
title_short Preparation and characterization of activated CMK-1 with Zn and Ni species applied in hydrogen storage
title_full Preparation and characterization of activated CMK-1 with Zn and Ni species applied in hydrogen storage
title_fullStr Preparation and characterization of activated CMK-1 with Zn and Ni species applied in hydrogen storage
title_full_unstemmed Preparation and characterization of activated CMK-1 with Zn and Ni species applied in hydrogen storage
title_sort Preparation and characterization of activated CMK-1 with Zn and Ni species applied in hydrogen storage
dc.creator.none.fl_str_mv Juarez, Juliana
Gómez Costa, Marcos Bruno
Anunziata, Oscar Alfredo
author Juarez, Juliana
author_facet Juarez, Juliana
Gómez Costa, Marcos Bruno
Anunziata, Oscar Alfredo
author_role author
author2 Gómez Costa, Marcos Bruno
Anunziata, Oscar Alfredo
author2_role author
author
dc.subject.none.fl_str_mv Cmk-1
Zn-Cmk-1
Ni-Cmk-1
Hydrogen
Storage
Composite
topic Cmk-1
Zn-Cmk-1
Ni-Cmk-1
Hydrogen
Storage
Composite
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.10
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The aim of this work is to prepare CMK‐1 modified with Zn and Ni in order to improve its capacity in hydrogen storage. The approach that we have followed includes synthesis of nanostructures with the experimental study of its adsorption capacity and storage properties. We have shown that CMK‐1 ordered porous carbon modified with metals is a promising material for hydrogen storage. The incorporation of metals was performed by wetness impregnation. The samples were characterized by X‐ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscope, transmission electron microscopy, X‐ray photoelectron spectroscopy, and Brunauer–Emmett–Teller methods. The CMK‐1 modified with Zn showed the highest H2 uptake at 77 K and at low and high pressure (1.5 and 4.4 wt.% at 1 and 10 bar, respectively). The introduction of Ni into CMK‐1 does not increase hydrogen storage capacity at low pressure. However, at a higher pressure (10 bars), Ni‐CMK‐1 displays improved results in hydrogen uptake compared with those of CMK‐1 pristine, 2.4 and 2.1 wt.%, respectively. Copyright © 2015 John Wiley & Sons, Ltd.
Fil: Juarez, Juliana. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina
Fil: Gómez Costa, Marcos Bruno. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina
Fil: Anunziata, Oscar Alfredo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina
description The aim of this work is to prepare CMK‐1 modified with Zn and Ni in order to improve its capacity in hydrogen storage. The approach that we have followed includes synthesis of nanostructures with the experimental study of its adsorption capacity and storage properties. We have shown that CMK‐1 ordered porous carbon modified with metals is a promising material for hydrogen storage. The incorporation of metals was performed by wetness impregnation. The samples were characterized by X‐ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscope, transmission electron microscopy, X‐ray photoelectron spectroscopy, and Brunauer–Emmett–Teller methods. The CMK‐1 modified with Zn showed the highest H2 uptake at 77 K and at low and high pressure (1.5 and 4.4 wt.% at 1 and 10 bar, respectively). The introduction of Ni into CMK‐1 does not increase hydrogen storage capacity at low pressure. However, at a higher pressure (10 bars), Ni‐CMK‐1 displays improved results in hydrogen uptake compared with those of CMK‐1 pristine, 2.4 and 2.1 wt.%, respectively. Copyright © 2015 John Wiley & Sons, Ltd.
publishDate 2015
dc.date.none.fl_str_mv 2015-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/44896
Juarez, Juliana; Gómez Costa, Marcos Bruno; Anunziata, Oscar Alfredo; Preparation and characterization of activated CMK-1 with Zn and Ni species applied in hydrogen storage; John Wiley & Sons Ltd; International Journal of Energy Research; 39; 7; 6-2015; 941-953
0363-907X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/44896
identifier_str_mv Juarez, Juliana; Gómez Costa, Marcos Bruno; Anunziata, Oscar Alfredo; Preparation and characterization of activated CMK-1 with Zn and Ni species applied in hydrogen storage; John Wiley & Sons Ltd; International Journal of Energy Research; 39; 7; 6-2015; 941-953
0363-907X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1002/er.3298
info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/er.3298
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv John Wiley & Sons Ltd
publisher.none.fl_str_mv John Wiley & Sons Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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