Modeling of molecular weights in industrial autoclave reactors for high pressure polymerization of ethylene and ethylene-vinyl acetate

Autores
Sarmoria, Claudia; Brandolin, Adriana; López, Antonio R.; Whiteley, Ken S.; Del Amo Fernández, Bernardo
Año de publicación
2000
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
We have incorporated mass balances of monomer, radical and polymer species to a previously developed mixing model for high pressure autoclave polymerization reactors. The customary quasi steady state approximation is not used, and the method of moments is used to simplify the mass balance calculations. The resulting moment model is able to calculate conversions, average molecular weights, long chain branching and melt flow indexes at any point in the reactor. It may also calculate concentration and temperature profiles along the reactor. Results for two base cases are presented in detail. Model predictions were compared with experimental data obtained at the industrial reactor; excellent agreement was obtained. The moment balance equations are presented in a modular way so that they may be easily adapted to be used with any other mixing model for this type of reactor.
Fil: Sarmoria, Claudia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Brandolin, Adriana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: López, Antonio R.. Repsoll; España
Fil: Whiteley, Ken S.. Repsol; España
Fil: Del Amo Fernández, Bernardo. Repsol; España
Materia
Ethylene Polymerization
Autoclave Reactor
Vinyl Acetate
Mathematical Modeling
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/40138
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Modeling of molecular weights in industrial autoclave reactors for high pressure polymerization of ethylene and ethylene-vinyl acetateSarmoria, ClaudiaBrandolin, AdrianaLópez, Antonio R.Whiteley, Ken S.Del Amo Fernández, BernardoEthylene PolymerizationAutoclave ReactorVinyl AcetateMathematical Modelinghttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2We have incorporated mass balances of monomer, radical and polymer species to a previously developed mixing model for high pressure autoclave polymerization reactors. The customary quasi steady state approximation is not used, and the method of moments is used to simplify the mass balance calculations. The resulting moment model is able to calculate conversions, average molecular weights, long chain branching and melt flow indexes at any point in the reactor. It may also calculate concentration and temperature profiles along the reactor. Results for two base cases are presented in detail. Model predictions were compared with experimental data obtained at the industrial reactor; excellent agreement was obtained. The moment balance equations are presented in a modular way so that they may be easily adapted to be used with any other mixing model for this type of reactor.Fil: Sarmoria, Claudia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Brandolin, Adriana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: López, Antonio R.. Repsoll; EspañaFil: Whiteley, Ken S.. Repsol; EspañaFil: Del Amo Fernández, Bernardo. Repsol; EspañaJohn Wiley & Sons Inc2000-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/40138Sarmoria, Claudia; Brandolin, Adriana; López, Antonio R.; Whiteley, Ken S.; Del Amo Fernández, Bernardo; Modeling of molecular weights in industrial autoclave reactors for high pressure polymerization of ethylene and ethylene-vinyl acetate; John Wiley & Sons Inc; Polymer Engineering and Science; 40; 6; 6-2000; 1480-14940032-3888CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/pen.11277info:eu-repo/semantics/altIdentifier/doi/10.1002/pen.11277info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:44:26Zoai:ri.conicet.gov.ar:11336/40138instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:44:26.398CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Modeling of molecular weights in industrial autoclave reactors for high pressure polymerization of ethylene and ethylene-vinyl acetate
title Modeling of molecular weights in industrial autoclave reactors for high pressure polymerization of ethylene and ethylene-vinyl acetate
spellingShingle Modeling of molecular weights in industrial autoclave reactors for high pressure polymerization of ethylene and ethylene-vinyl acetate
Sarmoria, Claudia
Ethylene Polymerization
Autoclave Reactor
Vinyl Acetate
Mathematical Modeling
title_short Modeling of molecular weights in industrial autoclave reactors for high pressure polymerization of ethylene and ethylene-vinyl acetate
title_full Modeling of molecular weights in industrial autoclave reactors for high pressure polymerization of ethylene and ethylene-vinyl acetate
title_fullStr Modeling of molecular weights in industrial autoclave reactors for high pressure polymerization of ethylene and ethylene-vinyl acetate
title_full_unstemmed Modeling of molecular weights in industrial autoclave reactors for high pressure polymerization of ethylene and ethylene-vinyl acetate
title_sort Modeling of molecular weights in industrial autoclave reactors for high pressure polymerization of ethylene and ethylene-vinyl acetate
dc.creator.none.fl_str_mv Sarmoria, Claudia
Brandolin, Adriana
López, Antonio R.
Whiteley, Ken S.
Del Amo Fernández, Bernardo
author Sarmoria, Claudia
author_facet Sarmoria, Claudia
Brandolin, Adriana
López, Antonio R.
Whiteley, Ken S.
Del Amo Fernández, Bernardo
author_role author
author2 Brandolin, Adriana
López, Antonio R.
Whiteley, Ken S.
Del Amo Fernández, Bernardo
author2_role author
author
author
author
dc.subject.none.fl_str_mv Ethylene Polymerization
Autoclave Reactor
Vinyl Acetate
Mathematical Modeling
topic Ethylene Polymerization
Autoclave Reactor
Vinyl Acetate
Mathematical Modeling
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv We have incorporated mass balances of monomer, radical and polymer species to a previously developed mixing model for high pressure autoclave polymerization reactors. The customary quasi steady state approximation is not used, and the method of moments is used to simplify the mass balance calculations. The resulting moment model is able to calculate conversions, average molecular weights, long chain branching and melt flow indexes at any point in the reactor. It may also calculate concentration and temperature profiles along the reactor. Results for two base cases are presented in detail. Model predictions were compared with experimental data obtained at the industrial reactor; excellent agreement was obtained. The moment balance equations are presented in a modular way so that they may be easily adapted to be used with any other mixing model for this type of reactor.
Fil: Sarmoria, Claudia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Brandolin, Adriana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: López, Antonio R.. Repsoll; España
Fil: Whiteley, Ken S.. Repsol; España
Fil: Del Amo Fernández, Bernardo. Repsol; España
description We have incorporated mass balances of monomer, radical and polymer species to a previously developed mixing model for high pressure autoclave polymerization reactors. The customary quasi steady state approximation is not used, and the method of moments is used to simplify the mass balance calculations. The resulting moment model is able to calculate conversions, average molecular weights, long chain branching and melt flow indexes at any point in the reactor. It may also calculate concentration and temperature profiles along the reactor. Results for two base cases are presented in detail. Model predictions were compared with experimental data obtained at the industrial reactor; excellent agreement was obtained. The moment balance equations are presented in a modular way so that they may be easily adapted to be used with any other mixing model for this type of reactor.
publishDate 2000
dc.date.none.fl_str_mv 2000-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/40138
Sarmoria, Claudia; Brandolin, Adriana; López, Antonio R.; Whiteley, Ken S.; Del Amo Fernández, Bernardo; Modeling of molecular weights in industrial autoclave reactors for high pressure polymerization of ethylene and ethylene-vinyl acetate; John Wiley & Sons Inc; Polymer Engineering and Science; 40; 6; 6-2000; 1480-1494
0032-3888
CONICET Digital
CONICET
url http://hdl.handle.net/11336/40138
identifier_str_mv Sarmoria, Claudia; Brandolin, Adriana; López, Antonio R.; Whiteley, Ken S.; Del Amo Fernández, Bernardo; Modeling of molecular weights in industrial autoclave reactors for high pressure polymerization of ethylene and ethylene-vinyl acetate; John Wiley & Sons Inc; Polymer Engineering and Science; 40; 6; 6-2000; 1480-1494
0032-3888
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/pen.11277
info:eu-repo/semantics/altIdentifier/doi/10.1002/pen.11277
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv John Wiley & Sons Inc
publisher.none.fl_str_mv John Wiley & Sons Inc
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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