Study of a pilot plant for the recovery of metals from spent alkaline and zinc-carbon batteries with biological sulphuric acid and polithionates production.

Autores
Thomas, Horacio Jorge; Falco, Maria Lorena Romina; Di Nanno, Maria Pia; Martinez, Analia Beatriz Luján; Curutchet, Gustavo Andres
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The recovery of Zn and Mn from spent alkaline and Zn-C batteries with a biohydro-metallurgycal process was studied in a pilot plant that consists in an air lift bio-reactor with a sulfur packed bed where Acidithiobacillus thiooxidans produces an acid-reducing medium; a leaching reactor where the acid-reducing medium is mixed with the battery powder and a recovery reactor where metals are recovered from the leaching liquor by electroly-sis. Results shows that with a 350 mM in proton me-dium produced in 12 days by Acidithiobacillus thiooxidans in the bio-reactor, an extraction of the 100% of Zn and 67% of the Mn present in the bat-tery powder was reached. The presence of polithionates in the medium produced in the bio-reactor allows the dissolution of the manganese. The solid remaining after bioleaching is a manganese oxide. The electrolysis of the leaching liquor pro-duced a cathodic deposit of metallic Zn and an an-odic deposit of a high surphase manganese oxide in one step at room temperature.
Fil: Thomas, Horacio Jorge. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Planta Piloto Multiproposito; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Falco, Maria Lorena Romina. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Planta Piloto Multiproposito; Argentina
Fil: Di Nanno, Maria Pia. Universidad Nacional de San Martin. Instituto de Inv. E Ingenieria Ambiental. Cent.de Estudios Ambientales; Argentina
Fil: Martinez, Analia Beatriz Luján. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Planta Piloto Multiproposito; Argentina
Fil: Curutchet, Gustavo Andres. Universidad Nacional de San Martin. Instituto de Investigaciones e Ingenieria Ambiental. Cent.de Estudios Ambientales; Argentina
Materia
batteries,
biohydrometallurgy,
Acidi-thiobacillus thiooxidans,
metal recovery.
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/2692
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/2692
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Study of a pilot plant for the recovery of metals from spent alkaline and zinc-carbon batteries with biological sulphuric acid and polithionates production.Thomas, Horacio JorgeFalco, Maria Lorena RominaDi Nanno, Maria PiaMartinez, Analia Beatriz LujánCurutchet, Gustavo Andresbatteries,biohydrometallurgy,Acidi-thiobacillus thiooxidans,metal recovery.https://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2The recovery of Zn and Mn from spent alkaline and Zn-C batteries with a biohydro-metallurgycal process was studied in a pilot plant that consists in an air lift bio-reactor with a sulfur packed bed where Acidithiobacillus thiooxidans produces an acid-reducing medium; a leaching reactor where the acid-reducing medium is mixed with the battery powder and a recovery reactor where metals are recovered from the leaching liquor by electroly-sis. Results shows that with a 350 mM in proton me-dium produced in 12 days by Acidithiobacillus thiooxidans in the bio-reactor, an extraction of the 100% of Zn and 67% of the Mn present in the bat-tery powder was reached. The presence of polithionates in the medium produced in the bio-reactor allows the dissolution of the manganese. The solid remaining after bioleaching is a manganese oxide. The electrolysis of the leaching liquor pro-duced a cathodic deposit of metallic Zn and an an-odic deposit of a high surphase manganese oxide in one step at room temperature.Fil: Thomas, Horacio Jorge. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Planta Piloto Multiproposito; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Falco, Maria Lorena Romina. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Planta Piloto Multiproposito; ArgentinaFil: Di Nanno, Maria Pia. Universidad Nacional de San Martin. Instituto de Inv. E Ingenieria Ambiental. Cent.de Estudios Ambientales; ArgentinaFil: Martinez, Analia Beatriz Luján. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Planta Piloto Multiproposito; ArgentinaFil: Curutchet, Gustavo Andres. Universidad Nacional de San Martin. Instituto de Investigaciones e Ingenieria Ambiental. Cent.de Estudios Ambientales; ArgentinaPlanta Piloto de Ingeniería Química2014-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/2692Thomas, Horacio Jorge; Falco, Maria Lorena Romina; Di Nanno, Maria Pia; Martinez, Analia Beatriz Luján; Curutchet, Gustavo Andres; Study of a pilot plant for the recovery of metals from spent alkaline and zinc-carbon batteries with biological sulphuric acid and polithionates production.; Planta Piloto de Ingeniería Química; Latin American Applied Research; 44; 2; 4-2014; 123-1290327-07931851-8796enginfo:eu-repo/semantics/altIdentifier/url/http://www.laar.uns.edu.ar/indexes/artic_v4402/44_02_123.pdfinfo:eu-repo/semantics/altIdentifier/url/http://www.laar.uns.edu.ar/indexes/i44_02.htminfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:18:49Zoai:ri.conicet.gov.ar:11336/2692instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:18:49.489CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Study of a pilot plant for the recovery of metals from spent alkaline and zinc-carbon batteries with biological sulphuric acid and polithionates production.
title Study of a pilot plant for the recovery of metals from spent alkaline and zinc-carbon batteries with biological sulphuric acid and polithionates production.
spellingShingle Study of a pilot plant for the recovery of metals from spent alkaline and zinc-carbon batteries with biological sulphuric acid and polithionates production.
Thomas, Horacio Jorge
batteries,
biohydrometallurgy,
Acidi-thiobacillus thiooxidans,
metal recovery.
title_short Study of a pilot plant for the recovery of metals from spent alkaline and zinc-carbon batteries with biological sulphuric acid and polithionates production.
title_full Study of a pilot plant for the recovery of metals from spent alkaline and zinc-carbon batteries with biological sulphuric acid and polithionates production.
title_fullStr Study of a pilot plant for the recovery of metals from spent alkaline and zinc-carbon batteries with biological sulphuric acid and polithionates production.
title_full_unstemmed Study of a pilot plant for the recovery of metals from spent alkaline and zinc-carbon batteries with biological sulphuric acid and polithionates production.
title_sort Study of a pilot plant for the recovery of metals from spent alkaline and zinc-carbon batteries with biological sulphuric acid and polithionates production.
dc.creator.none.fl_str_mv Thomas, Horacio Jorge
Falco, Maria Lorena Romina
Di Nanno, Maria Pia
Martinez, Analia Beatriz Luján
Curutchet, Gustavo Andres
author Thomas, Horacio Jorge
author_facet Thomas, Horacio Jorge
Falco, Maria Lorena Romina
Di Nanno, Maria Pia
Martinez, Analia Beatriz Luján
Curutchet, Gustavo Andres
author_role author
author2 Falco, Maria Lorena Romina
Di Nanno, Maria Pia
Martinez, Analia Beatriz Luján
Curutchet, Gustavo Andres
author2_role author
author
author
author
dc.subject.none.fl_str_mv batteries,
biohydrometallurgy,
Acidi-thiobacillus thiooxidans,
metal recovery.
topic batteries,
biohydrometallurgy,
Acidi-thiobacillus thiooxidans,
metal recovery.
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The recovery of Zn and Mn from spent alkaline and Zn-C batteries with a biohydro-metallurgycal process was studied in a pilot plant that consists in an air lift bio-reactor with a sulfur packed bed where Acidithiobacillus thiooxidans produces an acid-reducing medium; a leaching reactor where the acid-reducing medium is mixed with the battery powder and a recovery reactor where metals are recovered from the leaching liquor by electroly-sis. Results shows that with a 350 mM in proton me-dium produced in 12 days by Acidithiobacillus thiooxidans in the bio-reactor, an extraction of the 100% of Zn and 67% of the Mn present in the bat-tery powder was reached. The presence of polithionates in the medium produced in the bio-reactor allows the dissolution of the manganese. The solid remaining after bioleaching is a manganese oxide. The electrolysis of the leaching liquor pro-duced a cathodic deposit of metallic Zn and an an-odic deposit of a high surphase manganese oxide in one step at room temperature.
Fil: Thomas, Horacio Jorge. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Planta Piloto Multiproposito; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Falco, Maria Lorena Romina. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Planta Piloto Multiproposito; Argentina
Fil: Di Nanno, Maria Pia. Universidad Nacional de San Martin. Instituto de Inv. E Ingenieria Ambiental. Cent.de Estudios Ambientales; Argentina
Fil: Martinez, Analia Beatriz Luján. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Planta Piloto Multiproposito; Argentina
Fil: Curutchet, Gustavo Andres. Universidad Nacional de San Martin. Instituto de Investigaciones e Ingenieria Ambiental. Cent.de Estudios Ambientales; Argentina
description The recovery of Zn and Mn from spent alkaline and Zn-C batteries with a biohydro-metallurgycal process was studied in a pilot plant that consists in an air lift bio-reactor with a sulfur packed bed where Acidithiobacillus thiooxidans produces an acid-reducing medium; a leaching reactor where the acid-reducing medium is mixed with the battery powder and a recovery reactor where metals are recovered from the leaching liquor by electroly-sis. Results shows that with a 350 mM in proton me-dium produced in 12 days by Acidithiobacillus thiooxidans in the bio-reactor, an extraction of the 100% of Zn and 67% of the Mn present in the bat-tery powder was reached. The presence of polithionates in the medium produced in the bio-reactor allows the dissolution of the manganese. The solid remaining after bioleaching is a manganese oxide. The electrolysis of the leaching liquor pro-duced a cathodic deposit of metallic Zn and an an-odic deposit of a high surphase manganese oxide in one step at room temperature.
publishDate 2014
dc.date.none.fl_str_mv 2014-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/2692
Thomas, Horacio Jorge; Falco, Maria Lorena Romina; Di Nanno, Maria Pia; Martinez, Analia Beatriz Luján; Curutchet, Gustavo Andres; Study of a pilot plant for the recovery of metals from spent alkaline and zinc-carbon batteries with biological sulphuric acid and polithionates production.; Planta Piloto de Ingeniería Química; Latin American Applied Research; 44; 2; 4-2014; 123-129
0327-0793
1851-8796
url http://hdl.handle.net/11336/2692
identifier_str_mv Thomas, Horacio Jorge; Falco, Maria Lorena Romina; Di Nanno, Maria Pia; Martinez, Analia Beatriz Luján; Curutchet, Gustavo Andres; Study of a pilot plant for the recovery of metals from spent alkaline and zinc-carbon batteries with biological sulphuric acid and polithionates production.; Planta Piloto de Ingeniería Química; Latin American Applied Research; 44; 2; 4-2014; 123-129
0327-0793
1851-8796
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.laar.uns.edu.ar/indexes/artic_v4402/44_02_123.pdf
info:eu-repo/semantics/altIdentifier/url/http://www.laar.uns.edu.ar/indexes/i44_02.htm
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Planta Piloto de Ingeniería Química
publisher.none.fl_str_mv Planta Piloto de Ingeniería Química
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844614154046930944
score 13.070432

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