Synthesis and Characterization of High Temperature Properties of YBa2Cu3O6+δ Superconductor as Potential Cathode for Intermediate Temperature Solid Oxide Fuel Cells

Autores
Grassi, Joaquín; Macías, Mario A.; Basbus, Juan Felipe; Castiglioni, Jorge; Gauthier, Gilles H.; Serquis, Adriana Cristina; Suescun, Leopoldo
Año de publicación
2021
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
YBa2Cu3O6+δ (YBC) oxygen deficient perovskite was synthesized by an auto-combustion method and was studied as potential cathode for Intermediate Temperature Solid Oxide Fuel Cell (IT-SOFC). Synchrotron X-ray thermodiffraction in air shows a phase transition from orthorhombic Pmmm to tetragonal P4/mmm space groups at ~ 425 °C. The chemical compatibility with Ce0.9Gd0.1O1.95 (GDC) electrolyte was investigated in air where certain reactivity wasobserved above 800 °C. However, the main phase is Ba(Ce1-xYx)O3, a good ionic conductor. The catalytic performance in air was obtained by electrochemical impedance spectroscopy (EIS) measurements on YBC/GDC/YBC symmetrical cells. The area specific resistance (ASR) values change from 13.66 to 0.14 Ω cm2 between 500 and 800 °C, with activation energy (Ea) of 0.41 eV. The results suggest potential applications of YBC as IT-SOFC cathode.
Fil: Grassi, Joaquín. Universidad de la República. Facultad de Química; Uruguay
Fil: Macías, Mario A.. Universidad de los Andes; Colombia
Fil: Basbus, Juan Felipe. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología - Nodo Bariloche | Comisión Nacional de Energía Atómica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología - Nodo Bariloche; Argentina
Fil: Castiglioni, Jorge. Universidad de la República. Facultad de Química; Uruguay
Fil: Gauthier, Gilles H.. Universidad Industrial Santander; Colombia
Fil: Serquis, Adriana Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología - Nodo Bariloche | Comisión Nacional de Energía Atómica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología - Nodo Bariloche; Argentina
Fil: Suescun, Leopoldo. Universidad de la República. Facultad de Química; Uruguay
Materia
YBA2CU3O6+δ PEROVSKITE
IT-SOFC
CATHODE
AUTO-COMBUSTION SYNTHESIS
ELECTROCHEMICAL PERFORMANCE
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/182934
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/182934
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Synthesis and Characterization of High Temperature Properties of YBa2Cu3O6+δ Superconductor as Potential Cathode for Intermediate Temperature Solid Oxide Fuel CellsGrassi, JoaquínMacías, Mario A.Basbus, Juan FelipeCastiglioni, JorgeGauthier, Gilles H.Serquis, Adriana CristinaSuescun, LeopoldoYBA2CU3O6+δ PEROVSKITEIT-SOFCCATHODEAUTO-COMBUSTION SYNTHESISELECTROCHEMICAL PERFORMANCEhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2YBa2Cu3O6+δ (YBC) oxygen deficient perovskite was synthesized by an auto-combustion method and was studied as potential cathode for Intermediate Temperature Solid Oxide Fuel Cell (IT-SOFC). Synchrotron X-ray thermodiffraction in air shows a phase transition from orthorhombic Pmmm to tetragonal P4/mmm space groups at ~ 425 °C. The chemical compatibility with Ce0.9Gd0.1O1.95 (GDC) electrolyte was investigated in air where certain reactivity wasobserved above 800 °C. However, the main phase is Ba(Ce1-xYx)O3, a good ionic conductor. The catalytic performance in air was obtained by electrochemical impedance spectroscopy (EIS) measurements on YBC/GDC/YBC symmetrical cells. The area specific resistance (ASR) values change from 13.66 to 0.14 Ω cm2 between 500 and 800 °C, with activation energy (Ea) of 0.41 eV. The results suggest potential applications of YBC as IT-SOFC cathode.Fil: Grassi, Joaquín. Universidad de la República. Facultad de Química; UruguayFil: Macías, Mario A.. Universidad de los Andes; ColombiaFil: Basbus, Juan Felipe. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología - Nodo Bariloche | Comisión Nacional de Energía Atómica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología - Nodo Bariloche; ArgentinaFil: Castiglioni, Jorge. Universidad de la República. Facultad de Química; UruguayFil: Gauthier, Gilles H.. Universidad Industrial Santander; ColombiaFil: Serquis, Adriana Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología - Nodo Bariloche | Comisión Nacional de Energía Atómica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología - Nodo Bariloche; ArgentinaFil: Suescun, Leopoldo. Universidad de la República. Facultad de Química; UruguayZealpress2021-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/182934Grassi, Joaquín; Macías, Mario A.; Basbus, Juan Felipe; Castiglioni, Jorge; Gauthier, Gilles H.; et al.; Synthesis and Characterization of High Temperature Properties of YBa2Cu3O6+δ Superconductor as Potential Cathode for Intermediate Temperature Solid Oxide Fuel Cells; Zealpress; Journal of Material Science and Technology Research; 9-2021; 1-102410-4701CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.zealpress.com/jmstrv8a10/info:eu-repo/semantics/altIdentifier/doi/10.15377/2410-4701.2021.08.10info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:45:47Zoai:ri.conicet.gov.ar:11336/182934instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:45:47.535CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Synthesis and Characterization of High Temperature Properties of YBa2Cu3O6+δ Superconductor as Potential Cathode for Intermediate Temperature Solid Oxide Fuel Cells
title Synthesis and Characterization of High Temperature Properties of YBa2Cu3O6+δ Superconductor as Potential Cathode for Intermediate Temperature Solid Oxide Fuel Cells
spellingShingle Synthesis and Characterization of High Temperature Properties of YBa2Cu3O6+δ Superconductor as Potential Cathode for Intermediate Temperature Solid Oxide Fuel Cells
Grassi, Joaquín
YBA2CU3O6+δ PEROVSKITE
IT-SOFC
CATHODE
AUTO-COMBUSTION SYNTHESIS
ELECTROCHEMICAL PERFORMANCE
title_short Synthesis and Characterization of High Temperature Properties of YBa2Cu3O6+δ Superconductor as Potential Cathode for Intermediate Temperature Solid Oxide Fuel Cells
title_full Synthesis and Characterization of High Temperature Properties of YBa2Cu3O6+δ Superconductor as Potential Cathode for Intermediate Temperature Solid Oxide Fuel Cells
title_fullStr Synthesis and Characterization of High Temperature Properties of YBa2Cu3O6+δ Superconductor as Potential Cathode for Intermediate Temperature Solid Oxide Fuel Cells
title_full_unstemmed Synthesis and Characterization of High Temperature Properties of YBa2Cu3O6+δ Superconductor as Potential Cathode for Intermediate Temperature Solid Oxide Fuel Cells
title_sort Synthesis and Characterization of High Temperature Properties of YBa2Cu3O6+δ Superconductor as Potential Cathode for Intermediate Temperature Solid Oxide Fuel Cells
dc.creator.none.fl_str_mv Grassi, Joaquín
Macías, Mario A.
Basbus, Juan Felipe
Castiglioni, Jorge
Gauthier, Gilles H.
Serquis, Adriana Cristina
Suescun, Leopoldo
author Grassi, Joaquín
author_facet Grassi, Joaquín
Macías, Mario A.
Basbus, Juan Felipe
Castiglioni, Jorge
Gauthier, Gilles H.
Serquis, Adriana Cristina
Suescun, Leopoldo
author_role author
author2 Macías, Mario A.
Basbus, Juan Felipe
Castiglioni, Jorge
Gauthier, Gilles H.
Serquis, Adriana Cristina
Suescun, Leopoldo
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv YBA2CU3O6+δ PEROVSKITE
IT-SOFC
CATHODE
AUTO-COMBUSTION SYNTHESIS
ELECTROCHEMICAL PERFORMANCE
topic YBA2CU3O6+δ PEROVSKITE
IT-SOFC
CATHODE
AUTO-COMBUSTION SYNTHESIS
ELECTROCHEMICAL PERFORMANCE
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv YBa2Cu3O6+δ (YBC) oxygen deficient perovskite was synthesized by an auto-combustion method and was studied as potential cathode for Intermediate Temperature Solid Oxide Fuel Cell (IT-SOFC). Synchrotron X-ray thermodiffraction in air shows a phase transition from orthorhombic Pmmm to tetragonal P4/mmm space groups at ~ 425 °C. The chemical compatibility with Ce0.9Gd0.1O1.95 (GDC) electrolyte was investigated in air where certain reactivity wasobserved above 800 °C. However, the main phase is Ba(Ce1-xYx)O3, a good ionic conductor. The catalytic performance in air was obtained by electrochemical impedance spectroscopy (EIS) measurements on YBC/GDC/YBC symmetrical cells. The area specific resistance (ASR) values change from 13.66 to 0.14 Ω cm2 between 500 and 800 °C, with activation energy (Ea) of 0.41 eV. The results suggest potential applications of YBC as IT-SOFC cathode.
Fil: Grassi, Joaquín. Universidad de la República. Facultad de Química; Uruguay
Fil: Macías, Mario A.. Universidad de los Andes; Colombia
Fil: Basbus, Juan Felipe. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología - Nodo Bariloche | Comisión Nacional de Energía Atómica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología - Nodo Bariloche; Argentina
Fil: Castiglioni, Jorge. Universidad de la República. Facultad de Química; Uruguay
Fil: Gauthier, Gilles H.. Universidad Industrial Santander; Colombia
Fil: Serquis, Adriana Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología - Nodo Bariloche | Comisión Nacional de Energía Atómica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología - Nodo Bariloche; Argentina
Fil: Suescun, Leopoldo. Universidad de la República. Facultad de Química; Uruguay
description YBa2Cu3O6+δ (YBC) oxygen deficient perovskite was synthesized by an auto-combustion method and was studied as potential cathode for Intermediate Temperature Solid Oxide Fuel Cell (IT-SOFC). Synchrotron X-ray thermodiffraction in air shows a phase transition from orthorhombic Pmmm to tetragonal P4/mmm space groups at ~ 425 °C. The chemical compatibility with Ce0.9Gd0.1O1.95 (GDC) electrolyte was investigated in air where certain reactivity wasobserved above 800 °C. However, the main phase is Ba(Ce1-xYx)O3, a good ionic conductor. The catalytic performance in air was obtained by electrochemical impedance spectroscopy (EIS) measurements on YBC/GDC/YBC symmetrical cells. The area specific resistance (ASR) values change from 13.66 to 0.14 Ω cm2 between 500 and 800 °C, with activation energy (Ea) of 0.41 eV. The results suggest potential applications of YBC as IT-SOFC cathode.
publishDate 2021
dc.date.none.fl_str_mv 2021-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/182934
Grassi, Joaquín; Macías, Mario A.; Basbus, Juan Felipe; Castiglioni, Jorge; Gauthier, Gilles H.; et al.; Synthesis and Characterization of High Temperature Properties of YBa2Cu3O6+δ Superconductor as Potential Cathode for Intermediate Temperature Solid Oxide Fuel Cells; Zealpress; Journal of Material Science and Technology Research; 9-2021; 1-10
2410-4701
CONICET Digital
CONICET
url http://hdl.handle.net/11336/182934
identifier_str_mv Grassi, Joaquín; Macías, Mario A.; Basbus, Juan Felipe; Castiglioni, Jorge; Gauthier, Gilles H.; et al.; Synthesis and Characterization of High Temperature Properties of YBa2Cu3O6+δ Superconductor as Potential Cathode for Intermediate Temperature Solid Oxide Fuel Cells; Zealpress; Journal of Material Science and Technology Research; 9-2021; 1-10
2410-4701
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.zealpress.com/jmstrv8a10/
info:eu-repo/semantics/altIdentifier/doi/10.15377/2410-4701.2021.08.10
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Zealpress
publisher.none.fl_str_mv Zealpress
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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