Product distribution and mechanism of the OH − initiated tropospheric degradation of three CFC replacement candidates: CH 3 CF═CH 2 , (CF 3 ) 2 C═CH 2 and (E/Z)-CF 3 CF═CHF
- Autores
- Rivela Fretes, Cynthia Beatriz; Tovar Ramos, Carmen Maria; Gibilisco, Rodrigo Gastón; Teruel, Mariano Andres; Barnes, Ian; Wiesen, Peter; Blanco, Maria Belen
- Año de publicación
- 2019
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The OH radical initiated photodegradation of 2-fluoropropene (CH 3 CF═CH 2 ), 3,3,3-trifluoro-2-(tri-fluoromethyl)propene ((CF 3 ) 2 C═CH 2 ) and (E/Z)-1,2,3,3,3-pentafluoropropene ((E/Z)-CF 3 CF═CHF) has been investigated for the first time using a 1080 L quartz-glass environmental chamber at 298 ± 2 K and atmospheric pressure of synthetic air coupled with in situ FTIR spectroscopy to monitor reactants and products. The major products observed in the OH reaction were CH 3 C(O)F (98 ± 5)% together with HC(O)H (89 ± 7)% as a co-product, CF 3 C(O)F (103 ± 8)% together with HC(O)F (96 ± 7)% as a co-product and CF 3 C(O)CF 3 (91 ± 8)% together with HC(O)H (98 ± 12)% as a co-product from the C 1 -C 2 bond cleavage channel of the intermediate hydroxyalkoxy radical, formed by addition of OH to the terminal carbon of the double bond which is designated C 1 of 2-fluoropropene, (E/Z)-1,2,3,3,3-pentafluoropropene and 3,3,3-trifluoro-2-(tri-fluoromethyl)propene, respectively. The present results are compared with previous studies for the reaction of OH with the separate isomers (E) and (Z) of 1,2,3,3,3-pentafluoropropene. In addition, atmospheric implications of the reactions studied are discussed.
Fil: Rivela Fretes, Cynthia Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Tovar Ramos, Carmen Maria. Bergische Universitat Wuppertal; Alemania
Fil: Gibilisco, Rodrigo Gastón. Bergische Universitat Wuppertal; Alemania
Fil: Teruel, Mariano Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Barnes, Ian. Bergische Universitat Wuppertal; Alemania
Fil: Wiesen, Peter. Bergische Universitat Wuppertal; Alemania
Fil: Blanco, Maria Belen. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina - Materia
-
OH radical
2-fluoropropene
3,3,3-trifluoro-2-(tri-fluoromethyl)propene
(E/Z)-1,2,3,3,3 pentafluoropropene - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
.jpg)
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/120036
Ver los metadatos del registro completo
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Product distribution and mechanism of the OH − initiated tropospheric degradation of three CFC replacement candidates: CH 3 CF═CH 2 , (CF 3 ) 2 C═CH 2 and (E/Z)-CF 3 CF═CHFRivela Fretes, Cynthia BeatrizTovar Ramos, Carmen MariaGibilisco, Rodrigo GastónTeruel, Mariano AndresBarnes, IanWiesen, PeterBlanco, Maria BelenOH radical2-fluoropropene3,3,3-trifluoro-2-(tri-fluoromethyl)propene(E/Z)-1,2,3,3,3 pentafluoropropenehttps://purl.org/becyt/ford/1.5https://purl.org/becyt/ford/1The OH radical initiated photodegradation of 2-fluoropropene (CH 3 CF═CH 2 ), 3,3,3-trifluoro-2-(tri-fluoromethyl)propene ((CF 3 ) 2 C═CH 2 ) and (E/Z)-1,2,3,3,3-pentafluoropropene ((E/Z)-CF 3 CF═CHF) has been investigated for the first time using a 1080 L quartz-glass environmental chamber at 298 ± 2 K and atmospheric pressure of synthetic air coupled with in situ FTIR spectroscopy to monitor reactants and products. The major products observed in the OH reaction were CH 3 C(O)F (98 ± 5)% together with HC(O)H (89 ± 7)% as a co-product, CF 3 C(O)F (103 ± 8)% together with HC(O)F (96 ± 7)% as a co-product and CF 3 C(O)CF 3 (91 ± 8)% together with HC(O)H (98 ± 12)% as a co-product from the C 1 -C 2 bond cleavage channel of the intermediate hydroxyalkoxy radical, formed by addition of OH to the terminal carbon of the double bond which is designated C 1 of 2-fluoropropene, (E/Z)-1,2,3,3,3-pentafluoropropene and 3,3,3-trifluoro-2-(tri-fluoromethyl)propene, respectively. The present results are compared with previous studies for the reaction of OH with the separate isomers (E) and (Z) of 1,2,3,3,3-pentafluoropropene. In addition, atmospheric implications of the reactions studied are discussed.Fil: Rivela Fretes, Cynthia Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Tovar Ramos, Carmen Maria. Bergische Universitat Wuppertal; AlemaniaFil: Gibilisco, Rodrigo Gastón. Bergische Universitat Wuppertal; AlemaniaFil: Teruel, Mariano Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Barnes, Ian. Bergische Universitat Wuppertal; AlemaniaFil: Wiesen, Peter. Bergische Universitat Wuppertal; AlemaniaFil: Blanco, Maria Belen. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaRoyal Society of Chemistry2019-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/120036Rivela Fretes, Cynthia Beatriz; Tovar Ramos, Carmen Maria; Gibilisco, Rodrigo Gastón; Teruel, Mariano Andres; Barnes, Ian; et al.; Product distribution and mechanism of the OH − initiated tropospheric degradation of three CFC replacement candidates: CH 3 CF═CH 2 , (CF 3 ) 2 C═CH 2 and (E/Z)-CF 3 CF═CHF; Royal Society of Chemistry; RSC Advances; 9; 10; 2-2019; 5592-55982046-2069CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://xlink.rsc.org/?DOI=C8RA09627Ainfo:eu-repo/semantics/altIdentifier/doi/10.1039/C8RA09627Ainfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T15:46:10Zoai:ri.conicet.gov.ar:11336/120036instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 15:46:10.858CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
| dc.title.none.fl_str_mv |
Product distribution and mechanism of the OH − initiated tropospheric degradation of three CFC replacement candidates: CH 3 CF═CH 2 , (CF 3 ) 2 C═CH 2 and (E/Z)-CF 3 CF═CHF |
| title |
Product distribution and mechanism of the OH − initiated tropospheric degradation of three CFC replacement candidates: CH 3 CF═CH 2 , (CF 3 ) 2 C═CH 2 and (E/Z)-CF 3 CF═CHF |
| spellingShingle |
Product distribution and mechanism of the OH − initiated tropospheric degradation of three CFC replacement candidates: CH 3 CF═CH 2 , (CF 3 ) 2 C═CH 2 and (E/Z)-CF 3 CF═CHF Rivela Fretes, Cynthia Beatriz OH radical 2-fluoropropene 3,3,3-trifluoro-2-(tri-fluoromethyl)propene (E/Z)-1,2,3,3,3 pentafluoropropene |
| title_short |
Product distribution and mechanism of the OH − initiated tropospheric degradation of three CFC replacement candidates: CH 3 CF═CH 2 , (CF 3 ) 2 C═CH 2 and (E/Z)-CF 3 CF═CHF |
| title_full |
Product distribution and mechanism of the OH − initiated tropospheric degradation of three CFC replacement candidates: CH 3 CF═CH 2 , (CF 3 ) 2 C═CH 2 and (E/Z)-CF 3 CF═CHF |
| title_fullStr |
Product distribution and mechanism of the OH − initiated tropospheric degradation of three CFC replacement candidates: CH 3 CF═CH 2 , (CF 3 ) 2 C═CH 2 and (E/Z)-CF 3 CF═CHF |
| title_full_unstemmed |
Product distribution and mechanism of the OH − initiated tropospheric degradation of three CFC replacement candidates: CH 3 CF═CH 2 , (CF 3 ) 2 C═CH 2 and (E/Z)-CF 3 CF═CHF |
| title_sort |
Product distribution and mechanism of the OH − initiated tropospheric degradation of three CFC replacement candidates: CH 3 CF═CH 2 , (CF 3 ) 2 C═CH 2 and (E/Z)-CF 3 CF═CHF |
| dc.creator.none.fl_str_mv |
Rivela Fretes, Cynthia Beatriz Tovar Ramos, Carmen Maria Gibilisco, Rodrigo Gastón Teruel, Mariano Andres Barnes, Ian Wiesen, Peter Blanco, Maria Belen |
| author |
Rivela Fretes, Cynthia Beatriz |
| author_facet |
Rivela Fretes, Cynthia Beatriz Tovar Ramos, Carmen Maria Gibilisco, Rodrigo Gastón Teruel, Mariano Andres Barnes, Ian Wiesen, Peter Blanco, Maria Belen |
| author_role |
author |
| author2 |
Tovar Ramos, Carmen Maria Gibilisco, Rodrigo Gastón Teruel, Mariano Andres Barnes, Ian Wiesen, Peter Blanco, Maria Belen |
| author2_role |
author author author author author author |
| dc.subject.none.fl_str_mv |
OH radical 2-fluoropropene 3,3,3-trifluoro-2-(tri-fluoromethyl)propene (E/Z)-1,2,3,3,3 pentafluoropropene |
| topic |
OH radical 2-fluoropropene 3,3,3-trifluoro-2-(tri-fluoromethyl)propene (E/Z)-1,2,3,3,3 pentafluoropropene |
| purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.5 https://purl.org/becyt/ford/1 |
| dc.description.none.fl_txt_mv |
The OH radical initiated photodegradation of 2-fluoropropene (CH 3 CF═CH 2 ), 3,3,3-trifluoro-2-(tri-fluoromethyl)propene ((CF 3 ) 2 C═CH 2 ) and (E/Z)-1,2,3,3,3-pentafluoropropene ((E/Z)-CF 3 CF═CHF) has been investigated for the first time using a 1080 L quartz-glass environmental chamber at 298 ± 2 K and atmospheric pressure of synthetic air coupled with in situ FTIR spectroscopy to monitor reactants and products. The major products observed in the OH reaction were CH 3 C(O)F (98 ± 5)% together with HC(O)H (89 ± 7)% as a co-product, CF 3 C(O)F (103 ± 8)% together with HC(O)F (96 ± 7)% as a co-product and CF 3 C(O)CF 3 (91 ± 8)% together with HC(O)H (98 ± 12)% as a co-product from the C 1 -C 2 bond cleavage channel of the intermediate hydroxyalkoxy radical, formed by addition of OH to the terminal carbon of the double bond which is designated C 1 of 2-fluoropropene, (E/Z)-1,2,3,3,3-pentafluoropropene and 3,3,3-trifluoro-2-(tri-fluoromethyl)propene, respectively. The present results are compared with previous studies for the reaction of OH with the separate isomers (E) and (Z) of 1,2,3,3,3-pentafluoropropene. In addition, atmospheric implications of the reactions studied are discussed. Fil: Rivela Fretes, Cynthia Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina Fil: Tovar Ramos, Carmen Maria. Bergische Universitat Wuppertal; Alemania Fil: Gibilisco, Rodrigo Gastón. Bergische Universitat Wuppertal; Alemania Fil: Teruel, Mariano Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina Fil: Barnes, Ian. Bergische Universitat Wuppertal; Alemania Fil: Wiesen, Peter. Bergische Universitat Wuppertal; Alemania Fil: Blanco, Maria Belen. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina |
| description |
The OH radical initiated photodegradation of 2-fluoropropene (CH 3 CF═CH 2 ), 3,3,3-trifluoro-2-(tri-fluoromethyl)propene ((CF 3 ) 2 C═CH 2 ) and (E/Z)-1,2,3,3,3-pentafluoropropene ((E/Z)-CF 3 CF═CHF) has been investigated for the first time using a 1080 L quartz-glass environmental chamber at 298 ± 2 K and atmospheric pressure of synthetic air coupled with in situ FTIR spectroscopy to monitor reactants and products. The major products observed in the OH reaction were CH 3 C(O)F (98 ± 5)% together with HC(O)H (89 ± 7)% as a co-product, CF 3 C(O)F (103 ± 8)% together with HC(O)F (96 ± 7)% as a co-product and CF 3 C(O)CF 3 (91 ± 8)% together with HC(O)H (98 ± 12)% as a co-product from the C 1 -C 2 bond cleavage channel of the intermediate hydroxyalkoxy radical, formed by addition of OH to the terminal carbon of the double bond which is designated C 1 of 2-fluoropropene, (E/Z)-1,2,3,3,3-pentafluoropropene and 3,3,3-trifluoro-2-(tri-fluoromethyl)propene, respectively. The present results are compared with previous studies for the reaction of OH with the separate isomers (E) and (Z) of 1,2,3,3,3-pentafluoropropene. In addition, atmospheric implications of the reactions studied are discussed. |
| publishDate |
2019 |
| dc.date.none.fl_str_mv |
2019-02 |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
| format |
article |
| status_str |
publishedVersion |
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http://hdl.handle.net/11336/120036 Rivela Fretes, Cynthia Beatriz; Tovar Ramos, Carmen Maria; Gibilisco, Rodrigo Gastón; Teruel, Mariano Andres; Barnes, Ian; et al.; Product distribution and mechanism of the OH − initiated tropospheric degradation of three CFC replacement candidates: CH 3 CF═CH 2 , (CF 3 ) 2 C═CH 2 and (E/Z)-CF 3 CF═CHF; Royal Society of Chemistry; RSC Advances; 9; 10; 2-2019; 5592-5598 2046-2069 CONICET Digital CONICET |
| url |
http://hdl.handle.net/11336/120036 |
| identifier_str_mv |
Rivela Fretes, Cynthia Beatriz; Tovar Ramos, Carmen Maria; Gibilisco, Rodrigo Gastón; Teruel, Mariano Andres; Barnes, Ian; et al.; Product distribution and mechanism of the OH − initiated tropospheric degradation of three CFC replacement candidates: CH 3 CF═CH 2 , (CF 3 ) 2 C═CH 2 and (E/Z)-CF 3 CF═CHF; Royal Society of Chemistry; RSC Advances; 9; 10; 2-2019; 5592-5598 2046-2069 CONICET Digital CONICET |
| dc.language.none.fl_str_mv |
eng |
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eng |
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info:eu-repo/semantics/altIdentifier/url/http://xlink.rsc.org/?DOI=C8RA09627A info:eu-repo/semantics/altIdentifier/doi/10.1039/C8RA09627A |
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info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
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openAccess |
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https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
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application/pdf application/pdf application/pdf application/pdf |
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Royal Society of Chemistry |
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Royal Society of Chemistry |
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reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
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Consejo Nacional de Investigaciones Científicas y Técnicas |
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CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
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dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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