Hyperfine Field and Isomer Shift Evolution in Hydrogenated Nd–Fe–B Alloy

Autores
Saccone, F. D.; RodrÍguez Torres, Claudia Elena; Sánchez, Francisco Homero; Fernández van Raap, Marcela Beatriz
Año de publicación
2001
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
RE2Fe14B (RE=rare earth) materials are capable of absorbing hydrogen to form a stable solid solution at room temperature. Hydrogenation produces a number of significant changes in the hyperfine interactions. In this work, 57Fe Mössbauer effect spectroscopy and X-ray diffraction measurements were performed on Nd14.01Hf0.08Fe78.91B7.00 alloys submitted to thermal treatment in hydrogen atmosphere. A non-linear increase of the hyperfine fields and isomer shifts with hydrogen concentration was observed. The hyperfine parameters of the 8j1 site exhibit a rather different evolution than those experienced by the other major sites (8j2, 16k1, 16k2). The origin of the hyperfine field enhancement is analyzed in terms of volume expansion and H nearest neighbors to the Fe sites. A linear expression on these two effects to give account of isomer shift evolution for 8j1 site is given.
Fil: Saccone, F. D.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: RodrÍguez Torres, Claudia Elena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Sánchez, Francisco Homero. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Física; Argentina
Fil: Fernández van Raap, Marcela Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Materia
PERMANENT MAGNETS
ISOMER SHIFT
HYDORGENATION
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/98036
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Hyperfine Field and Isomer Shift Evolution in Hydrogenated Nd–Fe–B AlloySaccone, F. D.RodrÍguez Torres, Claudia ElenaSánchez, Francisco HomeroFernández van Raap, Marcela BeatrizPERMANENT MAGNETSISOMER SHIFTHYDORGENATIONhttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1RE2Fe14B (RE=rare earth) materials are capable of absorbing hydrogen to form a stable solid solution at room temperature. Hydrogenation produces a number of significant changes in the hyperfine interactions. In this work, 57Fe Mössbauer effect spectroscopy and X-ray diffraction measurements were performed on Nd14.01Hf0.08Fe78.91B7.00 alloys submitted to thermal treatment in hydrogen atmosphere. A non-linear increase of the hyperfine fields and isomer shifts with hydrogen concentration was observed. The hyperfine parameters of the 8j1 site exhibit a rather different evolution than those experienced by the other major sites (8j2, 16k1, 16k2). The origin of the hyperfine field enhancement is analyzed in terms of volume expansion and H nearest neighbors to the Fe sites. A linear expression on these two effects to give account of isomer shift evolution for 8j1 site is given.Fil: Saccone, F. D.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; ArgentinaFil: RodrÍguez Torres, Claudia Elena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; ArgentinaFil: Sánchez, Francisco Homero. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Física; ArgentinaFil: Fernández van Raap, Marcela Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; ArgentinaKluwer Academic/Plenum Publ2001-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/98036Saccone, F. D.; RodrÍguez Torres, Claudia Elena; Sánchez, Francisco Homero; Fernández van Raap, Marcela Beatriz; Hyperfine Field and Isomer Shift Evolution in Hydrogenated Nd–Fe–B Alloy; Kluwer Academic/Plenum Publ; Hyperfine Interactions; 134; 1; 6-2001; 123-1290304-3843CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://link.springer.com/article/10.1023%2FA%3A1013878315620info:eu-repo/semantics/altIdentifier/doi/10.1023/A:1013878315620info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-29T11:54:54Zoai:ri.conicet.gov.ar:11336/98036instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-29 11:54:54.783CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Hyperfine Field and Isomer Shift Evolution in Hydrogenated Nd–Fe–B Alloy
title Hyperfine Field and Isomer Shift Evolution in Hydrogenated Nd–Fe–B Alloy
spellingShingle Hyperfine Field and Isomer Shift Evolution in Hydrogenated Nd–Fe–B Alloy
Saccone, F. D.
PERMANENT MAGNETS
ISOMER SHIFT
HYDORGENATION
title_short Hyperfine Field and Isomer Shift Evolution in Hydrogenated Nd–Fe–B Alloy
title_full Hyperfine Field and Isomer Shift Evolution in Hydrogenated Nd–Fe–B Alloy
title_fullStr Hyperfine Field and Isomer Shift Evolution in Hydrogenated Nd–Fe–B Alloy
title_full_unstemmed Hyperfine Field and Isomer Shift Evolution in Hydrogenated Nd–Fe–B Alloy
title_sort Hyperfine Field and Isomer Shift Evolution in Hydrogenated Nd–Fe–B Alloy
dc.creator.none.fl_str_mv Saccone, F. D.
RodrÍguez Torres, Claudia Elena
Sánchez, Francisco Homero
Fernández van Raap, Marcela Beatriz
author Saccone, F. D.
author_facet Saccone, F. D.
RodrÍguez Torres, Claudia Elena
Sánchez, Francisco Homero
Fernández van Raap, Marcela Beatriz
author_role author
author2 RodrÍguez Torres, Claudia Elena
Sánchez, Francisco Homero
Fernández van Raap, Marcela Beatriz
author2_role author
author
author
dc.subject.none.fl_str_mv PERMANENT MAGNETS
ISOMER SHIFT
HYDORGENATION
topic PERMANENT MAGNETS
ISOMER SHIFT
HYDORGENATION
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv RE2Fe14B (RE=rare earth) materials are capable of absorbing hydrogen to form a stable solid solution at room temperature. Hydrogenation produces a number of significant changes in the hyperfine interactions. In this work, 57Fe Mössbauer effect spectroscopy and X-ray diffraction measurements were performed on Nd14.01Hf0.08Fe78.91B7.00 alloys submitted to thermal treatment in hydrogen atmosphere. A non-linear increase of the hyperfine fields and isomer shifts with hydrogen concentration was observed. The hyperfine parameters of the 8j1 site exhibit a rather different evolution than those experienced by the other major sites (8j2, 16k1, 16k2). The origin of the hyperfine field enhancement is analyzed in terms of volume expansion and H nearest neighbors to the Fe sites. A linear expression on these two effects to give account of isomer shift evolution for 8j1 site is given.
Fil: Saccone, F. D.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: RodrÍguez Torres, Claudia Elena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Sánchez, Francisco Homero. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Física; Argentina
Fil: Fernández van Raap, Marcela Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
description RE2Fe14B (RE=rare earth) materials are capable of absorbing hydrogen to form a stable solid solution at room temperature. Hydrogenation produces a number of significant changes in the hyperfine interactions. In this work, 57Fe Mössbauer effect spectroscopy and X-ray diffraction measurements were performed on Nd14.01Hf0.08Fe78.91B7.00 alloys submitted to thermal treatment in hydrogen atmosphere. A non-linear increase of the hyperfine fields and isomer shifts with hydrogen concentration was observed. The hyperfine parameters of the 8j1 site exhibit a rather different evolution than those experienced by the other major sites (8j2, 16k1, 16k2). The origin of the hyperfine field enhancement is analyzed in terms of volume expansion and H nearest neighbors to the Fe sites. A linear expression on these two effects to give account of isomer shift evolution for 8j1 site is given.
publishDate 2001
dc.date.none.fl_str_mv 2001-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/98036
Saccone, F. D.; RodrÍguez Torres, Claudia Elena; Sánchez, Francisco Homero; Fernández van Raap, Marcela Beatriz; Hyperfine Field and Isomer Shift Evolution in Hydrogenated Nd–Fe–B Alloy; Kluwer Academic/Plenum Publ; Hyperfine Interactions; 134; 1; 6-2001; 123-129
0304-3843
CONICET Digital
CONICET
url http://hdl.handle.net/11336/98036
identifier_str_mv Saccone, F. D.; RodrÍguez Torres, Claudia Elena; Sánchez, Francisco Homero; Fernández van Raap, Marcela Beatriz; Hyperfine Field and Isomer Shift Evolution in Hydrogenated Nd–Fe–B Alloy; Kluwer Academic/Plenum Publ; Hyperfine Interactions; 134; 1; 6-2001; 123-129
0304-3843
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://link.springer.com/article/10.1023%2FA%3A1013878315620
info:eu-repo/semantics/altIdentifier/doi/10.1023/A:1013878315620
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Kluwer Academic/Plenum Publ
publisher.none.fl_str_mv Kluwer Academic/Plenum Publ
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.10058

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