Comparative analysis of the chlorination of mixtures iron–aluminum and the binary alloy FeAl3

Autores
Alvarez, Fabiola J.; Pasquevich, Daniel Miguel; Bohe, Ana Ester
Año de publicación
2006
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A comparative study of the behavior of a binary alloy FeAl3 and an equivalent mixture of the pure metals towards chlorine, was carried out between 150 and 300 ◦C. The present work focuses at the analysis of the interactions between metals and the possibility of their separation. According to the composition determined for the AlCl3 obtained from the reactants, the separation of the metals was more effective in the case of the alloy, while for the FeCl3 the segregation of the aluminum from the iron was better in the mixture than in the alloy. The last result could be revealing a stronger interaction between the chlorides in the alloy. The reactants, products and residues were identified, characterized and quantified by X-ray diffraction (XRD), scanning electron microscopy (SEM), Mossbauer spectroscopy (MS), chemical analysis (atomic absorption, spectrophotometry and gravimetry) and X-ray fluorescence spec- ¨ trometry (XRF).
Fil: Alvarez, Fabiola J.. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina
Fil: Pasquevich, Daniel Miguel. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina
Fil: Bohe, Ana Ester. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina. Universidad Nacional del Comahue; Argentina
Materia
CHLORINATION
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
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oai:ri.conicet.gov.ar:11336/279571
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Comparative analysis of the chlorination of mixtures iron–aluminum and the binary alloy FeAl3Alvarez, Fabiola J.Pasquevich, Daniel MiguelBohe, Ana EsterCHLORINATIONhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2A comparative study of the behavior of a binary alloy FeAl3 and an equivalent mixture of the pure metals towards chlorine, was carried out between 150 and 300 ◦C. The present work focuses at the analysis of the interactions between metals and the possibility of their separation. According to the composition determined for the AlCl3 obtained from the reactants, the separation of the metals was more effective in the case of the alloy, while for the FeCl3 the segregation of the aluminum from the iron was better in the mixture than in the alloy. The last result could be revealing a stronger interaction between the chlorides in the alloy. The reactants, products and residues were identified, characterized and quantified by X-ray diffraction (XRD), scanning electron microscopy (SEM), Mossbauer spectroscopy (MS), chemical analysis (atomic absorption, spectrophotometry and gravimetry) and X-ray fluorescence spec- ¨ trometry (XRF).Fil: Alvarez, Fabiola J.. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; ArgentinaFil: Pasquevich, Daniel Miguel. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; ArgentinaFil: Bohe, Ana Ester. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina. Universidad Nacional del Comahue; ArgentinaElsevier Science SA2006-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/279571Alvarez, Fabiola J.; Pasquevich, Daniel Miguel; Bohe, Ana Ester; Comparative analysis of the chlorination of mixtures iron–aluminum and the binary alloy FeAl3; Elsevier Science SA; Journal of Alloys and Compounds; 424; 1-2; 12-2006; 78-870925-8388CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0925838806000041info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jallcom.2005.12.079info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2026-02-26T09:59:16Zoai:ri.conicet.gov.ar:11336/279571instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982026-02-26 09:59:16.951CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Comparative analysis of the chlorination of mixtures iron–aluminum and the binary alloy FeAl3
title Comparative analysis of the chlorination of mixtures iron–aluminum and the binary alloy FeAl3
spellingShingle Comparative analysis of the chlorination of mixtures iron–aluminum and the binary alloy FeAl3
Alvarez, Fabiola J.
CHLORINATION
title_short Comparative analysis of the chlorination of mixtures iron–aluminum and the binary alloy FeAl3
title_full Comparative analysis of the chlorination of mixtures iron–aluminum and the binary alloy FeAl3
title_fullStr Comparative analysis of the chlorination of mixtures iron–aluminum and the binary alloy FeAl3
title_full_unstemmed Comparative analysis of the chlorination of mixtures iron–aluminum and the binary alloy FeAl3
title_sort Comparative analysis of the chlorination of mixtures iron–aluminum and the binary alloy FeAl3
dc.creator.none.fl_str_mv Alvarez, Fabiola J.
Pasquevich, Daniel Miguel
Bohe, Ana Ester
author Alvarez, Fabiola J.
author_facet Alvarez, Fabiola J.
Pasquevich, Daniel Miguel
Bohe, Ana Ester
author_role author
author2 Pasquevich, Daniel Miguel
Bohe, Ana Ester
author2_role author
author
dc.subject.none.fl_str_mv CHLORINATION
topic CHLORINATION
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv A comparative study of the behavior of a binary alloy FeAl3 and an equivalent mixture of the pure metals towards chlorine, was carried out between 150 and 300 ◦C. The present work focuses at the analysis of the interactions between metals and the possibility of their separation. According to the composition determined for the AlCl3 obtained from the reactants, the separation of the metals was more effective in the case of the alloy, while for the FeCl3 the segregation of the aluminum from the iron was better in the mixture than in the alloy. The last result could be revealing a stronger interaction between the chlorides in the alloy. The reactants, products and residues were identified, characterized and quantified by X-ray diffraction (XRD), scanning electron microscopy (SEM), Mossbauer spectroscopy (MS), chemical analysis (atomic absorption, spectrophotometry and gravimetry) and X-ray fluorescence spec- ¨ trometry (XRF).
Fil: Alvarez, Fabiola J.. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina
Fil: Pasquevich, Daniel Miguel. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina
Fil: Bohe, Ana Ester. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina. Universidad Nacional del Comahue; Argentina
description A comparative study of the behavior of a binary alloy FeAl3 and an equivalent mixture of the pure metals towards chlorine, was carried out between 150 and 300 ◦C. The present work focuses at the analysis of the interactions between metals and the possibility of their separation. According to the composition determined for the AlCl3 obtained from the reactants, the separation of the metals was more effective in the case of the alloy, while for the FeCl3 the segregation of the aluminum from the iron was better in the mixture than in the alloy. The last result could be revealing a stronger interaction between the chlorides in the alloy. The reactants, products and residues were identified, characterized and quantified by X-ray diffraction (XRD), scanning electron microscopy (SEM), Mossbauer spectroscopy (MS), chemical analysis (atomic absorption, spectrophotometry and gravimetry) and X-ray fluorescence spec- ¨ trometry (XRF).
publishDate 2006
dc.date.none.fl_str_mv 2006-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/279571
Alvarez, Fabiola J.; Pasquevich, Daniel Miguel; Bohe, Ana Ester; Comparative analysis of the chlorination of mixtures iron–aluminum and the binary alloy FeAl3; Elsevier Science SA; Journal of Alloys and Compounds; 424; 1-2; 12-2006; 78-87
0925-8388
CONICET Digital
CONICET
url http://hdl.handle.net/11336/279571
identifier_str_mv Alvarez, Fabiola J.; Pasquevich, Daniel Miguel; Bohe, Ana Ester; Comparative analysis of the chlorination of mixtures iron–aluminum and the binary alloy FeAl3; Elsevier Science SA; Journal of Alloys and Compounds; 424; 1-2; 12-2006; 78-87
0925-8388
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0925838806000041
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jallcom.2005.12.079
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science SA
publisher.none.fl_str_mv Elsevier Science SA
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.176822

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