Facile, efficient and eco-friendly synthesis of 5-sulfenyl tetrazole derivatives of indoles and pyrroles
- Autores
- Kuhn, Bruna L.; Fortes, Margiani P.; Kaufman, Teodoro Saul; Silveira, Claudio C.
- Año de publicación
- 2014
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- A concise, two-step eco-friendly approach towards the synthesis of 5-sulfenyl tetrazole derivatives of indoles and pyrroles, is reported. The synthesis comprises the oxone-mediated thiocyanation of the starting heterocycles towards intermediate 3-thiocyanato indoles and 2-thiocyanato pyrroles, and their subsequent treatment with sodium azide in 2-propanol/water under zinc bromide promotion.
Fil: Kuhn, Bruna L.. Universidade Federal de Santa Maria. Departamento de Química; Brasil
Fil: Fortes, Margiani P.. Universidade Federal de Santa Maria. Departamento de Química; Brasil
Fil: Kaufman, Teodoro Saul. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Rosario. Instituto de Química Rosario; Argentina
Fil: Silveira, Claudio C.. Universidade Federal de Santa Maria. Departamento de Química; Brasil - Materia
-
5-Sulfenyl Tetrazoles
Pyrrole And Indole Derivatives-Thiocyanation
Eco-Friendly Functionalization of Heterocycles
Zinc Bromide Promoted Reaction - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
- Repositorio
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- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/6013
Ver los metadatos del registro completo
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Facile, efficient and eco-friendly synthesis of 5-sulfenyl tetrazole derivatives of indoles and pyrrolesKuhn, Bruna L.Fortes, Margiani P.Kaufman, Teodoro SaulSilveira, Claudio C.5-Sulfenyl TetrazolesPyrrole And Indole Derivatives-ThiocyanationEco-Friendly Functionalization of HeterocyclesZinc Bromide Promoted Reactionhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A concise, two-step eco-friendly approach towards the synthesis of 5-sulfenyl tetrazole derivatives of indoles and pyrroles, is reported. The synthesis comprises the oxone-mediated thiocyanation of the starting heterocycles towards intermediate 3-thiocyanato indoles and 2-thiocyanato pyrroles, and their subsequent treatment with sodium azide in 2-propanol/water under zinc bromide promotion.Fil: Kuhn, Bruna L.. Universidade Federal de Santa Maria. Departamento de Química; BrasilFil: Fortes, Margiani P.. Universidade Federal de Santa Maria. Departamento de Química; BrasilFil: Kaufman, Teodoro Saul. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Rosario. Instituto de Química Rosario; ArgentinaFil: Silveira, Claudio C.. Universidade Federal de Santa Maria. Departamento de Química; BrasilElsevier2014-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/6013Kuhn, Bruna L.; Fortes, Margiani P.; Kaufman, Teodoro Saul; Silveira, Claudio C.; Facile, efficient and eco-friendly synthesis of 5-sulfenyl tetrazole derivatives of indoles and pyrroles; Elsevier; Tetrahedron Letters; 55; 9; 2-2014; 1648-16520040-4039enginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0040403914001476info:eu-repo/semantics/altIdentifier/doi/info:eu-repo/semantics/altIdentifier/doi/10.1016/j.tetlet.2014.01.101info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:07:38Zoai:ri.conicet.gov.ar:11336/6013instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:07:38.71CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
| dc.title.none.fl_str_mv |
Facile, efficient and eco-friendly synthesis of 5-sulfenyl tetrazole derivatives of indoles and pyrroles |
| title |
Facile, efficient and eco-friendly synthesis of 5-sulfenyl tetrazole derivatives of indoles and pyrroles |
| spellingShingle |
Facile, efficient and eco-friendly synthesis of 5-sulfenyl tetrazole derivatives of indoles and pyrroles Kuhn, Bruna L. 5-Sulfenyl Tetrazoles Pyrrole And Indole Derivatives-Thiocyanation Eco-Friendly Functionalization of Heterocycles Zinc Bromide Promoted Reaction |
| title_short |
Facile, efficient and eco-friendly synthesis of 5-sulfenyl tetrazole derivatives of indoles and pyrroles |
| title_full |
Facile, efficient and eco-friendly synthesis of 5-sulfenyl tetrazole derivatives of indoles and pyrroles |
| title_fullStr |
Facile, efficient and eco-friendly synthesis of 5-sulfenyl tetrazole derivatives of indoles and pyrroles |
| title_full_unstemmed |
Facile, efficient and eco-friendly synthesis of 5-sulfenyl tetrazole derivatives of indoles and pyrroles |
| title_sort |
Facile, efficient and eco-friendly synthesis of 5-sulfenyl tetrazole derivatives of indoles and pyrroles |
| dc.creator.none.fl_str_mv |
Kuhn, Bruna L. Fortes, Margiani P. Kaufman, Teodoro Saul Silveira, Claudio C. |
| author |
Kuhn, Bruna L. |
| author_facet |
Kuhn, Bruna L. Fortes, Margiani P. Kaufman, Teodoro Saul Silveira, Claudio C. |
| author_role |
author |
| author2 |
Fortes, Margiani P. Kaufman, Teodoro Saul Silveira, Claudio C. |
| author2_role |
author author author |
| dc.subject.none.fl_str_mv |
5-Sulfenyl Tetrazoles Pyrrole And Indole Derivatives-Thiocyanation Eco-Friendly Functionalization of Heterocycles Zinc Bromide Promoted Reaction |
| topic |
5-Sulfenyl Tetrazoles Pyrrole And Indole Derivatives-Thiocyanation Eco-Friendly Functionalization of Heterocycles Zinc Bromide Promoted Reaction |
| purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
| dc.description.none.fl_txt_mv |
A concise, two-step eco-friendly approach towards the synthesis of 5-sulfenyl tetrazole derivatives of indoles and pyrroles, is reported. The synthesis comprises the oxone-mediated thiocyanation of the starting heterocycles towards intermediate 3-thiocyanato indoles and 2-thiocyanato pyrroles, and their subsequent treatment with sodium azide in 2-propanol/water under zinc bromide promotion. Fil: Kuhn, Bruna L.. Universidade Federal de Santa Maria. Departamento de Química; Brasil Fil: Fortes, Margiani P.. Universidade Federal de Santa Maria. Departamento de Química; Brasil Fil: Kaufman, Teodoro Saul. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Rosario. Instituto de Química Rosario; Argentina Fil: Silveira, Claudio C.. Universidade Federal de Santa Maria. Departamento de Química; Brasil |
| description |
A concise, two-step eco-friendly approach towards the synthesis of 5-sulfenyl tetrazole derivatives of indoles and pyrroles, is reported. The synthesis comprises the oxone-mediated thiocyanation of the starting heterocycles towards intermediate 3-thiocyanato indoles and 2-thiocyanato pyrroles, and their subsequent treatment with sodium azide in 2-propanol/water under zinc bromide promotion. |
| publishDate |
2014 |
| dc.date.none.fl_str_mv |
2014-02 |
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info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
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article |
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publishedVersion |
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http://hdl.handle.net/11336/6013 Kuhn, Bruna L.; Fortes, Margiani P.; Kaufman, Teodoro Saul; Silveira, Claudio C.; Facile, efficient and eco-friendly synthesis of 5-sulfenyl tetrazole derivatives of indoles and pyrroles; Elsevier; Tetrahedron Letters; 55; 9; 2-2014; 1648-1652 0040-4039 |
| url |
http://hdl.handle.net/11336/6013 |
| identifier_str_mv |
Kuhn, Bruna L.; Fortes, Margiani P.; Kaufman, Teodoro Saul; Silveira, Claudio C.; Facile, efficient and eco-friendly synthesis of 5-sulfenyl tetrazole derivatives of indoles and pyrroles; Elsevier; Tetrahedron Letters; 55; 9; 2-2014; 1648-1652 0040-4039 |
| dc.language.none.fl_str_mv |
eng |
| language |
eng |
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Elsevier |
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Elsevier |
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