CO2 capture via catalytic hydrogenation to methanol: Thermodynamic limit vs. 'kinetic limit

Autores
Fornero, Esteban Luis; Chiavassa, Dante Luis; Bonivardi, Adrian Lionel; Baltanas, Miguel Angel
Año de publicación
2011
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The production of methanol via the catalytic hydrogenation of carbon oxides was simulated in a reacting system that included the recycling of noncondensable gases (H2, CO2 and CO) to evaluate the CO2 capture capability of the process. As a first step, the asymptotic responses of the system 'operating in thermodynamic equilibrium' (i.e., overall recoveries of CO2 and H2, CH3OH selectivity and productivity) were analyzed for various industrial conditions of pressure (3-5 MPa), temperature (508-538 K), feed composition (H 2/CO2 = 1.5/1 to 4/1) and mole recycle ratio (R) with respect to the molar feed flow rate. Then the performance of two catalysts (a novel one, Pd-Ga2O3/SiO2 and a commercial CuO/ZnO/Al2O3 type) in an ideal isothermal, isobaric, pseudohomogeneous fixed-bed reactor was studied for a broad range of W/FCO 2 ratios. It was found that, whereas the 'reactor in equilibrium' would allow up to 100% CO2 capture, the capture values upon using these catalysts were significantly lower. Nevertheless, such recoveries always increased whenever R was raised, which implies that catalyst development efforts in this field should prioritize achievement of the highest catalytic activity (i.e., specific productivity) rather than attempt catalyst selectivity improvements.
Fil: Fornero, Esteban Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Chiavassa, Dante Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Bonivardi, Adrian Lionel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Baltanas, Miguel Angel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Materia
CAPTURE
CARBON DIOXIDE
FIXED-BED CATALYTIC REACTORS
METHANOL
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/133608
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/133608
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling CO2 capture via catalytic hydrogenation to methanol: Thermodynamic limit vs. 'kinetic limitFornero, Esteban LuisChiavassa, Dante LuisBonivardi, Adrian LionelBaltanas, Miguel AngelCAPTURECARBON DIOXIDEFIXED-BED CATALYTIC REACTORSMETHANOLhttps://purl.org/becyt/ford/2.7https://purl.org/becyt/ford/2https://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The production of methanol via the catalytic hydrogenation of carbon oxides was simulated in a reacting system that included the recycling of noncondensable gases (H2, CO2 and CO) to evaluate the CO2 capture capability of the process. As a first step, the asymptotic responses of the system 'operating in thermodynamic equilibrium' (i.e., overall recoveries of CO2 and H2, CH3OH selectivity and productivity) were analyzed for various industrial conditions of pressure (3-5 MPa), temperature (508-538 K), feed composition (H 2/CO2 = 1.5/1 to 4/1) and mole recycle ratio (R) with respect to the molar feed flow rate. Then the performance of two catalysts (a novel one, Pd-Ga2O3/SiO2 and a commercial CuO/ZnO/Al2O3 type) in an ideal isothermal, isobaric, pseudohomogeneous fixed-bed reactor was studied for a broad range of W/FCO 2 ratios. It was found that, whereas the 'reactor in equilibrium' would allow up to 100% CO2 capture, the capture values upon using these catalysts were significantly lower. Nevertheless, such recoveries always increased whenever R was raised, which implies that catalyst development efforts in this field should prioritize achievement of the highest catalytic activity (i.e., specific productivity) rather than attempt catalyst selectivity improvements.Fil: Fornero, Esteban Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Chiavassa, Dante Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Bonivardi, Adrian Lionel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Baltanas, Miguel Angel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaElsevier Science2011-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/133608Fornero, Esteban Luis; Chiavassa, Dante Luis; Bonivardi, Adrian Lionel; Baltanas, Miguel Angel; CO2 capture via catalytic hydrogenation to methanol: Thermodynamic limit vs. 'kinetic limit; Elsevier Science; Catalysis Today; 172; 1; 8-2011; 158-1650920-5861CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.cattod.2011.02.036info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:39:15Zoai:ri.conicet.gov.ar:11336/133608instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:39:15.673CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv CO2 capture via catalytic hydrogenation to methanol: Thermodynamic limit vs. 'kinetic limit
title CO2 capture via catalytic hydrogenation to methanol: Thermodynamic limit vs. 'kinetic limit
spellingShingle CO2 capture via catalytic hydrogenation to methanol: Thermodynamic limit vs. 'kinetic limit
Fornero, Esteban Luis
CAPTURE
CARBON DIOXIDE
FIXED-BED CATALYTIC REACTORS
METHANOL
title_short CO2 capture via catalytic hydrogenation to methanol: Thermodynamic limit vs. 'kinetic limit
title_full CO2 capture via catalytic hydrogenation to methanol: Thermodynamic limit vs. 'kinetic limit
title_fullStr CO2 capture via catalytic hydrogenation to methanol: Thermodynamic limit vs. 'kinetic limit
title_full_unstemmed CO2 capture via catalytic hydrogenation to methanol: Thermodynamic limit vs. 'kinetic limit
title_sort CO2 capture via catalytic hydrogenation to methanol: Thermodynamic limit vs. 'kinetic limit
dc.creator.none.fl_str_mv Fornero, Esteban Luis
Chiavassa, Dante Luis
Bonivardi, Adrian Lionel
Baltanas, Miguel Angel
author Fornero, Esteban Luis
author_facet Fornero, Esteban Luis
Chiavassa, Dante Luis
Bonivardi, Adrian Lionel
Baltanas, Miguel Angel
author_role author
author2 Chiavassa, Dante Luis
Bonivardi, Adrian Lionel
Baltanas, Miguel Angel
author2_role author
author
author
dc.subject.none.fl_str_mv CAPTURE
CARBON DIOXIDE
FIXED-BED CATALYTIC REACTORS
METHANOL
topic CAPTURE
CARBON DIOXIDE
FIXED-BED CATALYTIC REACTORS
METHANOL
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.7
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The production of methanol via the catalytic hydrogenation of carbon oxides was simulated in a reacting system that included the recycling of noncondensable gases (H2, CO2 and CO) to evaluate the CO2 capture capability of the process. As a first step, the asymptotic responses of the system 'operating in thermodynamic equilibrium' (i.e., overall recoveries of CO2 and H2, CH3OH selectivity and productivity) were analyzed for various industrial conditions of pressure (3-5 MPa), temperature (508-538 K), feed composition (H 2/CO2 = 1.5/1 to 4/1) and mole recycle ratio (R) with respect to the molar feed flow rate. Then the performance of two catalysts (a novel one, Pd-Ga2O3/SiO2 and a commercial CuO/ZnO/Al2O3 type) in an ideal isothermal, isobaric, pseudohomogeneous fixed-bed reactor was studied for a broad range of W/FCO 2 ratios. It was found that, whereas the 'reactor in equilibrium' would allow up to 100% CO2 capture, the capture values upon using these catalysts were significantly lower. Nevertheless, such recoveries always increased whenever R was raised, which implies that catalyst development efforts in this field should prioritize achievement of the highest catalytic activity (i.e., specific productivity) rather than attempt catalyst selectivity improvements.
Fil: Fornero, Esteban Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Chiavassa, Dante Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Bonivardi, Adrian Lionel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Baltanas, Miguel Angel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
description The production of methanol via the catalytic hydrogenation of carbon oxides was simulated in a reacting system that included the recycling of noncondensable gases (H2, CO2 and CO) to evaluate the CO2 capture capability of the process. As a first step, the asymptotic responses of the system 'operating in thermodynamic equilibrium' (i.e., overall recoveries of CO2 and H2, CH3OH selectivity and productivity) were analyzed for various industrial conditions of pressure (3-5 MPa), temperature (508-538 K), feed composition (H 2/CO2 = 1.5/1 to 4/1) and mole recycle ratio (R) with respect to the molar feed flow rate. Then the performance of two catalysts (a novel one, Pd-Ga2O3/SiO2 and a commercial CuO/ZnO/Al2O3 type) in an ideal isothermal, isobaric, pseudohomogeneous fixed-bed reactor was studied for a broad range of W/FCO 2 ratios. It was found that, whereas the 'reactor in equilibrium' would allow up to 100% CO2 capture, the capture values upon using these catalysts were significantly lower. Nevertheless, such recoveries always increased whenever R was raised, which implies that catalyst development efforts in this field should prioritize achievement of the highest catalytic activity (i.e., specific productivity) rather than attempt catalyst selectivity improvements.
publishDate 2011
dc.date.none.fl_str_mv 2011-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/133608
Fornero, Esteban Luis; Chiavassa, Dante Luis; Bonivardi, Adrian Lionel; Baltanas, Miguel Angel; CO2 capture via catalytic hydrogenation to methanol: Thermodynamic limit vs. 'kinetic limit; Elsevier Science; Catalysis Today; 172; 1; 8-2011; 158-165
0920-5861
CONICET Digital
CONICET
url http://hdl.handle.net/11336/133608
identifier_str_mv Fornero, Esteban Luis; Chiavassa, Dante Luis; Bonivardi, Adrian Lionel; Baltanas, Miguel Angel; CO2 capture via catalytic hydrogenation to methanol: Thermodynamic limit vs. 'kinetic limit; Elsevier Science; Catalysis Today; 172; 1; 8-2011; 158-165
0920-5861
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cattod.2011.02.036
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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