Angular distributions and rovibrational excitation of N2 molecules recombined on N-covered Ag(1 1 1) by the Eley?Rideal mechanism
- Autores
- Juaristi, J.I.; Díaz, E.; Bocan, Gisela Anahí; Alducin, M.; Díez Muino, R.; Blanco-Rey, M.
- Año de publicación
- 2015
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Former calculations showed that atomic N incident at energies of a few eV on N-covered Ag(1 1 1) forms N2 molecules by the Eley?Rideal (ER) mechanism, i.e. by direct pick-up of adsorbates. Here, we calculate the azimuthal angle distributions and the rovibrational energies of those ER products. We observe a non-trivial angle dependence that may result in very low in-plane ER yield for some given incident azimuthal angles. We find that most of the energy released upon N N bond formation, about 7 eV, is stored in the rovibrational degrees of freedom independently of the incidence energy considered.
Fil: Juaristi, J.I.. Departamento de Física de Materiales, Facultad de Químicas UPV/EHU; España. Centro de Física de Materiales CFM/MPC (CSIC-UPV/EHU); España. Donostia International Physics Center; España
Fil: Díaz, E.. Donostia International Physics Center; España
Fil: Bocan, Gisela Anahí. Comisión Nacional de Energía Atómica; Argentina. Comision Nacional de Investigacion Cientifica y Tecnologica; Chile
Fil: Alducin, M.. Centro de Física de Materiales CFM/MPC (CSIC-UPV/EHU); España. Donostia International Physics Center; España
Fil: Díez Muino, R.. Centro de Física de Materiales CFM/MPC (CSIC-UPV/EHU); España. Donostia International Physics Center; España
Fil: Blanco-Rey, M.. Departamento de Física de Materiales, Facultad de Químicas UPV/EHU; España. Donostia International Physics Center; España - Materia
-
Eley-Rideal
N2/N/Ag(111)
Gas-Surface-Dynamics
Potential-Energy-Surface
Atomic N - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/3489
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Angular distributions and rovibrational excitation of N2 molecules recombined on N-covered Ag(1 1 1) by the Eley?Rideal mechanismJuaristi, J.I.Díaz, E.Bocan, Gisela AnahíAlducin, M.Díez Muino, R.Blanco-Rey, M.Eley-RidealN2/N/Ag(111)Gas-Surface-DynamicsPotential-Energy-SurfaceAtomic Nhttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1Former calculations showed that atomic N incident at energies of a few eV on N-covered Ag(1 1 1) forms N2 molecules by the Eley?Rideal (ER) mechanism, i.e. by direct pick-up of adsorbates. Here, we calculate the azimuthal angle distributions and the rovibrational energies of those ER products. We observe a non-trivial angle dependence that may result in very low in-plane ER yield for some given incident azimuthal angles. We find that most of the energy released upon N N bond formation, about 7 eV, is stored in the rovibrational degrees of freedom independently of the incidence energy considered.Fil: Juaristi, J.I.. Departamento de Física de Materiales, Facultad de Químicas UPV/EHU; España. Centro de Física de Materiales CFM/MPC (CSIC-UPV/EHU); España. Donostia International Physics Center; EspañaFil: Díaz, E.. Donostia International Physics Center; EspañaFil: Bocan, Gisela Anahí. Comisión Nacional de Energía Atómica; Argentina. Comision Nacional de Investigacion Cientifica y Tecnologica; ChileFil: Alducin, M.. Centro de Física de Materiales CFM/MPC (CSIC-UPV/EHU); España. Donostia International Physics Center; EspañaFil: Díez Muino, R.. Centro de Física de Materiales CFM/MPC (CSIC-UPV/EHU); España. Donostia International Physics Center; EspañaFil: Blanco-Rey, M.. Departamento de Física de Materiales, Facultad de Químicas UPV/EHU; España. Donostia International Physics Center; EspañaElsevier Science2015-04-15info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/3489Juaristi, J.I.; Díaz, E.; Bocan, Gisela Anahí; Alducin, M.; Díez Muino, R.; et al.; Angular distributions and rovibrational excitation of N2 molecules recombined on N-covered Ag(1 1 1) by the Eley?Rideal mechanism; Elsevier Science; Catalysis Today; 244; 15-4-2015; 115-1210920-5861enginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.cattod.2014.06.028info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0920586114004520info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:16:11Zoai:ri.conicet.gov.ar:11336/3489instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:16:11.902CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Angular distributions and rovibrational excitation of N2 molecules recombined on N-covered Ag(1 1 1) by the Eley?Rideal mechanism |
title |
Angular distributions and rovibrational excitation of N2 molecules recombined on N-covered Ag(1 1 1) by the Eley?Rideal mechanism |
spellingShingle |
Angular distributions and rovibrational excitation of N2 molecules recombined on N-covered Ag(1 1 1) by the Eley?Rideal mechanism Juaristi, J.I. Eley-Rideal N2/N/Ag(111) Gas-Surface-Dynamics Potential-Energy-Surface Atomic N |
title_short |
Angular distributions and rovibrational excitation of N2 molecules recombined on N-covered Ag(1 1 1) by the Eley?Rideal mechanism |
title_full |
Angular distributions and rovibrational excitation of N2 molecules recombined on N-covered Ag(1 1 1) by the Eley?Rideal mechanism |
title_fullStr |
Angular distributions and rovibrational excitation of N2 molecules recombined on N-covered Ag(1 1 1) by the Eley?Rideal mechanism |
title_full_unstemmed |
Angular distributions and rovibrational excitation of N2 molecules recombined on N-covered Ag(1 1 1) by the Eley?Rideal mechanism |
title_sort |
Angular distributions and rovibrational excitation of N2 molecules recombined on N-covered Ag(1 1 1) by the Eley?Rideal mechanism |
dc.creator.none.fl_str_mv |
Juaristi, J.I. Díaz, E. Bocan, Gisela Anahí Alducin, M. Díez Muino, R. Blanco-Rey, M. |
author |
Juaristi, J.I. |
author_facet |
Juaristi, J.I. Díaz, E. Bocan, Gisela Anahí Alducin, M. Díez Muino, R. Blanco-Rey, M. |
author_role |
author |
author2 |
Díaz, E. Bocan, Gisela Anahí Alducin, M. Díez Muino, R. Blanco-Rey, M. |
author2_role |
author author author author author |
dc.subject.none.fl_str_mv |
Eley-Rideal N2/N/Ag(111) Gas-Surface-Dynamics Potential-Energy-Surface Atomic N |
topic |
Eley-Rideal N2/N/Ag(111) Gas-Surface-Dynamics Potential-Energy-Surface Atomic N |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.3 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
Former calculations showed that atomic N incident at energies of a few eV on N-covered Ag(1 1 1) forms N2 molecules by the Eley?Rideal (ER) mechanism, i.e. by direct pick-up of adsorbates. Here, we calculate the azimuthal angle distributions and the rovibrational energies of those ER products. We observe a non-trivial angle dependence that may result in very low in-plane ER yield for some given incident azimuthal angles. We find that most of the energy released upon N N bond formation, about 7 eV, is stored in the rovibrational degrees of freedom independently of the incidence energy considered. Fil: Juaristi, J.I.. Departamento de Física de Materiales, Facultad de Químicas UPV/EHU; España. Centro de Física de Materiales CFM/MPC (CSIC-UPV/EHU); España. Donostia International Physics Center; España Fil: Díaz, E.. Donostia International Physics Center; España Fil: Bocan, Gisela Anahí. Comisión Nacional de Energía Atómica; Argentina. Comision Nacional de Investigacion Cientifica y Tecnologica; Chile Fil: Alducin, M.. Centro de Física de Materiales CFM/MPC (CSIC-UPV/EHU); España. Donostia International Physics Center; España Fil: Díez Muino, R.. Centro de Física de Materiales CFM/MPC (CSIC-UPV/EHU); España. Donostia International Physics Center; España Fil: Blanco-Rey, M.. Departamento de Física de Materiales, Facultad de Químicas UPV/EHU; España. Donostia International Physics Center; España |
description |
Former calculations showed that atomic N incident at energies of a few eV on N-covered Ag(1 1 1) forms N2 molecules by the Eley?Rideal (ER) mechanism, i.e. by direct pick-up of adsorbates. Here, we calculate the azimuthal angle distributions and the rovibrational energies of those ER products. We observe a non-trivial angle dependence that may result in very low in-plane ER yield for some given incident azimuthal angles. We find that most of the energy released upon N N bond formation, about 7 eV, is stored in the rovibrational degrees of freedom independently of the incidence energy considered. |
publishDate |
2015 |
dc.date.none.fl_str_mv |
2015-04-15 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/3489 Juaristi, J.I.; Díaz, E.; Bocan, Gisela Anahí; Alducin, M.; Díez Muino, R.; et al.; Angular distributions and rovibrational excitation of N2 molecules recombined on N-covered Ag(1 1 1) by the Eley?Rideal mechanism; Elsevier Science; Catalysis Today; 244; 15-4-2015; 115-121 0920-5861 |
url |
http://hdl.handle.net/11336/3489 |
identifier_str_mv |
Juaristi, J.I.; Díaz, E.; Bocan, Gisela Anahí; Alducin, M.; Díez Muino, R.; et al.; Angular distributions and rovibrational excitation of N2 molecules recombined on N-covered Ag(1 1 1) by the Eley?Rideal mechanism; Elsevier Science; Catalysis Today; 244; 15-4-2015; 115-121 0920-5861 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cattod.2014.06.028 info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0920586114004520 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science |
publisher.none.fl_str_mv |
Elsevier Science |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
_version_ |
1844614104020418560 |
score |
13.070432 |