Angular distributions and rovibrational excitation of N2 molecules recombined on N-covered Ag(1 1 1) by the Eley?Rideal mechanism

Autores
Juaristi, J.I.; Díaz, E.; Bocan, Gisela Anahí; Alducin, M.; Díez Muino, R.; Blanco-Rey, M.
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Former calculations showed that atomic N incident at energies of a few eV on N-covered Ag(1 1 1) forms N2 molecules by the Eley?Rideal (ER) mechanism, i.e. by direct pick-up of adsorbates. Here, we calculate the azimuthal angle distributions and the rovibrational energies of those ER products. We observe a non-trivial angle dependence that may result in very low in-plane ER yield for some given incident azimuthal angles. We find that most of the energy released upon N N bond formation, about 7 eV, is stored in the rovibrational degrees of freedom independently of the incidence energy considered.
Fil: Juaristi, J.I.. Departamento de Física de Materiales, Facultad de Químicas UPV/EHU; España. Centro de Física de Materiales CFM/MPC (CSIC-UPV/EHU); España. Donostia International Physics Center; España
Fil: Díaz, E.. Donostia International Physics Center; España
Fil: Bocan, Gisela Anahí. Comisión Nacional de Energía Atómica; Argentina. Comision Nacional de Investigacion Cientifica y Tecnologica; Chile
Fil: Alducin, M.. Centro de Física de Materiales CFM/MPC (CSIC-UPV/EHU); España. Donostia International Physics Center; España
Fil: Díez Muino, R.. Centro de Física de Materiales CFM/MPC (CSIC-UPV/EHU); España. Donostia International Physics Center; España
Fil: Blanco-Rey, M.. Departamento de Física de Materiales, Facultad de Químicas UPV/EHU; España. Donostia International Physics Center; España
Materia
Eley-Rideal
N2/N/Ag(111)
Gas-Surface-Dynamics
Potential-Energy-Surface
Atomic N
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/3489
Acceder
id CONICETDig_b8878412b3fd1a043a682d3998978255
oai_identifier_str oai:ri.conicet.gov.ar:11336/3489
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Angular distributions and rovibrational excitation of N2 molecules recombined on N-covered Ag(1 1 1) by the Eley?Rideal mechanismJuaristi, J.I.Díaz, E.Bocan, Gisela AnahíAlducin, M.Díez Muino, R.Blanco-Rey, M.Eley-RidealN2/N/Ag(111)Gas-Surface-DynamicsPotential-Energy-SurfaceAtomic Nhttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1Former calculations showed that atomic N incident at energies of a few eV on N-covered Ag(1 1 1) forms N2 molecules by the Eley?Rideal (ER) mechanism, i.e. by direct pick-up of adsorbates. Here, we calculate the azimuthal angle distributions and the rovibrational energies of those ER products. We observe a non-trivial angle dependence that may result in very low in-plane ER yield for some given incident azimuthal angles. We find that most of the energy released upon N N bond formation, about 7 eV, is stored in the rovibrational degrees of freedom independently of the incidence energy considered.Fil: Juaristi, J.I.. Departamento de Física de Materiales, Facultad de Químicas UPV/EHU; España. Centro de Física de Materiales CFM/MPC (CSIC-UPV/EHU); España. Donostia International Physics Center; EspañaFil: Díaz, E.. Donostia International Physics Center; EspañaFil: Bocan, Gisela Anahí. Comisión Nacional de Energía Atómica; Argentina. Comision Nacional de Investigacion Cientifica y Tecnologica; ChileFil: Alducin, M.. Centro de Física de Materiales CFM/MPC (CSIC-UPV/EHU); España. Donostia International Physics Center; EspañaFil: Díez Muino, R.. Centro de Física de Materiales CFM/MPC (CSIC-UPV/EHU); España. Donostia International Physics Center; EspañaFil: Blanco-Rey, M.. Departamento de Física de Materiales, Facultad de Químicas UPV/EHU; España. Donostia International Physics Center; EspañaElsevier Science2015-04-15info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/3489Juaristi, J.I.; Díaz, E.; Bocan, Gisela Anahí; Alducin, M.; Díez Muino, R.; et al.; Angular distributions and rovibrational excitation of N2 molecules recombined on N-covered Ag(1 1 1) by the Eley?Rideal mechanism; Elsevier Science; Catalysis Today; 244; 15-4-2015; 115-1210920-5861enginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.cattod.2014.06.028info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0920586114004520info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T15:13:26Zoai:ri.conicet.gov.ar:11336/3489instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 15:13:26.858CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Angular distributions and rovibrational excitation of N2 molecules recombined on N-covered Ag(1 1 1) by the Eley?Rideal mechanism
title Angular distributions and rovibrational excitation of N2 molecules recombined on N-covered Ag(1 1 1) by the Eley?Rideal mechanism
spellingShingle Angular distributions and rovibrational excitation of N2 molecules recombined on N-covered Ag(1 1 1) by the Eley?Rideal mechanism
Juaristi, J.I.
Eley-Rideal
N2/N/Ag(111)
Gas-Surface-Dynamics
Potential-Energy-Surface
Atomic N
title_short Angular distributions and rovibrational excitation of N2 molecules recombined on N-covered Ag(1 1 1) by the Eley?Rideal mechanism
title_full Angular distributions and rovibrational excitation of N2 molecules recombined on N-covered Ag(1 1 1) by the Eley?Rideal mechanism
title_fullStr Angular distributions and rovibrational excitation of N2 molecules recombined on N-covered Ag(1 1 1) by the Eley?Rideal mechanism
title_full_unstemmed Angular distributions and rovibrational excitation of N2 molecules recombined on N-covered Ag(1 1 1) by the Eley?Rideal mechanism
title_sort Angular distributions and rovibrational excitation of N2 molecules recombined on N-covered Ag(1 1 1) by the Eley?Rideal mechanism
dc.creator.none.fl_str_mv Juaristi, J.I.
Díaz, E.
Bocan, Gisela Anahí
Alducin, M.
Díez Muino, R.
Blanco-Rey, M.
author Juaristi, J.I.
author_facet Juaristi, J.I.
Díaz, E.
Bocan, Gisela Anahí
Alducin, M.
Díez Muino, R.
Blanco-Rey, M.
author_role author
author2 Díaz, E.
Bocan, Gisela Anahí
Alducin, M.
Díez Muino, R.
Blanco-Rey, M.
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Eley-Rideal
N2/N/Ag(111)
Gas-Surface-Dynamics
Potential-Energy-Surface
Atomic N
topic Eley-Rideal
N2/N/Ag(111)
Gas-Surface-Dynamics
Potential-Energy-Surface
Atomic N
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Former calculations showed that atomic N incident at energies of a few eV on N-covered Ag(1 1 1) forms N2 molecules by the Eley?Rideal (ER) mechanism, i.e. by direct pick-up of adsorbates. Here, we calculate the azimuthal angle distributions and the rovibrational energies of those ER products. We observe a non-trivial angle dependence that may result in very low in-plane ER yield for some given incident azimuthal angles. We find that most of the energy released upon N N bond formation, about 7 eV, is stored in the rovibrational degrees of freedom independently of the incidence energy considered.
Fil: Juaristi, J.I.. Departamento de Física de Materiales, Facultad de Químicas UPV/EHU; España. Centro de Física de Materiales CFM/MPC (CSIC-UPV/EHU); España. Donostia International Physics Center; España
Fil: Díaz, E.. Donostia International Physics Center; España
Fil: Bocan, Gisela Anahí. Comisión Nacional de Energía Atómica; Argentina. Comision Nacional de Investigacion Cientifica y Tecnologica; Chile
Fil: Alducin, M.. Centro de Física de Materiales CFM/MPC (CSIC-UPV/EHU); España. Donostia International Physics Center; España
Fil: Díez Muino, R.. Centro de Física de Materiales CFM/MPC (CSIC-UPV/EHU); España. Donostia International Physics Center; España
Fil: Blanco-Rey, M.. Departamento de Física de Materiales, Facultad de Químicas UPV/EHU; España. Donostia International Physics Center; España
description Former calculations showed that atomic N incident at energies of a few eV on N-covered Ag(1 1 1) forms N2 molecules by the Eley?Rideal (ER) mechanism, i.e. by direct pick-up of adsorbates. Here, we calculate the azimuthal angle distributions and the rovibrational energies of those ER products. We observe a non-trivial angle dependence that may result in very low in-plane ER yield for some given incident azimuthal angles. We find that most of the energy released upon N N bond formation, about 7 eV, is stored in the rovibrational degrees of freedom independently of the incidence energy considered.
publishDate 2015
dc.date.none.fl_str_mv 2015-04-15
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/3489
Juaristi, J.I.; Díaz, E.; Bocan, Gisela Anahí; Alducin, M.; Díez Muino, R.; et al.; Angular distributions and rovibrational excitation of N2 molecules recombined on N-covered Ag(1 1 1) by the Eley?Rideal mechanism; Elsevier Science; Catalysis Today; 244; 15-4-2015; 115-121
0920-5861
url http://hdl.handle.net/11336/3489
identifier_str_mv Juaristi, J.I.; Díaz, E.; Bocan, Gisela Anahí; Alducin, M.; Díez Muino, R.; et al.; Angular distributions and rovibrational excitation of N2 molecules recombined on N-covered Ag(1 1 1) by the Eley?Rideal mechanism; Elsevier Science; Catalysis Today; 244; 15-4-2015; 115-121
0920-5861
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cattod.2014.06.028
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0920586114004520
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846083282057297920
score 13.22299

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