High macroscopic neutron capture cross section ceramics based on bauxite and Gd2O3

Autores
Hernández, Maria Florencia; Herrera, Maria Silvia; Anaya, Ricardo Javier; Martinez, Juan Manuel; Cipollone, Mariano Enrique; Conconi, María Susana; Rendtorff Birrer, Nicolás Maximiliano
Año de publicación
2020
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The effect of the addition of Gadolinium oxide (Gd2O3) up to 10 wt.% in bauxite was studied and its thermal behavior compared with pure bauxite. The incorporation of Gd2O3 is of technological interest for the design of smart traceable ceramic proppants used for unconventional gas and oil well stimulation. These high macroscopic neutron capture cross section proppants are used to obtain relevant information, such as the location and height of the created hydraulic fractures, through a neutron based detection technology. The study comprised a set of thermal and sintering behavior analyses up to 1500 °C of mixtures up to 10 wt.% addition of Gd2O3. The developed texture and microstructure was also assessed. A simple mechanical characterization was performed as well. Fully-dense pore-free microstructures were developed, with alumina and mullite as the main crystalline phases. Gadolinium secondary and ternary alumino-silicate phases were also observed after thermal treatment. These present a needle morphology that might result in reinforcement mechanisms. No important glassy phase was detected; although sintering was enhanced, the Gd2O3 oxide main role was found to be as a sintering aid rather than a strict flux agent. The mechanical behavior remained fragile with the rare oxide addition. In fact, the mechanical resistance increased up to 20 wt.% for the 10 wt.% added sample. The oxide addition together with the bauxite dehydroxilation mass loss resulted in materials with up to 1.5 x 105 (c.u.) macroscopic neutron capture cross section materials. The obtained results permit to define design strategies of high macroscopic neutron capture ceramic materials for wellbore and developed fractures description.
Fil: Hernández, Maria Florencia. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina
Fil: Herrera, Maria Silvia. YPF - Tecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Anaya, Ricardo Javier. YPF - Tecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Martinez, Juan Manuel. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina
Fil: Cipollone, Mariano Enrique. YPF - Tecnología; Argentina
Fil: Conconi, María Susana. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina
Fil: Rendtorff Birrer, Nicolás Maximiliano. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina
Materia
BAUXITE
GADOLINIUM OXIDE
RARE EARTH
SMART CERAMIC PROPPANTS
THERMAL NEUTRON CAPTURE CROSS SECTION
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/180826
Acceder
id CONICETDig_b7a25655dc90ccffc7203464db1bf2ba
oai_identifier_str oai:ri.conicet.gov.ar:11336/180826
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling High macroscopic neutron capture cross section ceramics based on bauxite and Gd2O3Hernández, Maria FlorenciaHerrera, Maria SilviaAnaya, Ricardo JavierMartinez, Juan ManuelCipollone, Mariano EnriqueConconi, María SusanaRendtorff Birrer, Nicolás MaximilianoBAUXITEGADOLINIUM OXIDERARE EARTHSMART CERAMIC PROPPANTSTHERMAL NEUTRON CAPTURE CROSS SECTIONhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2The effect of the addition of Gadolinium oxide (Gd2O3) up to 10 wt.% in bauxite was studied and its thermal behavior compared with pure bauxite. The incorporation of Gd2O3 is of technological interest for the design of smart traceable ceramic proppants used for unconventional gas and oil well stimulation. These high macroscopic neutron capture cross section proppants are used to obtain relevant information, such as the location and height of the created hydraulic fractures, through a neutron based detection technology. The study comprised a set of thermal and sintering behavior analyses up to 1500 °C of mixtures up to 10 wt.% addition of Gd2O3. The developed texture and microstructure was also assessed. A simple mechanical characterization was performed as well. Fully-dense pore-free microstructures were developed, with alumina and mullite as the main crystalline phases. Gadolinium secondary and ternary alumino-silicate phases were also observed after thermal treatment. These present a needle morphology that might result in reinforcement mechanisms. No important glassy phase was detected; although sintering was enhanced, the Gd2O3 oxide main role was found to be as a sintering aid rather than a strict flux agent. The mechanical behavior remained fragile with the rare oxide addition. In fact, the mechanical resistance increased up to 20 wt.% for the 10 wt.% added sample. The oxide addition together with the bauxite dehydroxilation mass loss resulted in materials with up to 1.5 x 105 (c.u.) macroscopic neutron capture cross section materials. The obtained results permit to define design strategies of high macroscopic neutron capture ceramic materials for wellbore and developed fractures description.Fil: Hernández, Maria Florencia. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; ArgentinaFil: Herrera, Maria Silvia. YPF - Tecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Anaya, Ricardo Javier. YPF - Tecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Martinez, Juan Manuel. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; ArgentinaFil: Cipollone, Mariano Enrique. YPF - Tecnología; ArgentinaFil: Conconi, María Susana. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; ArgentinaFil: Rendtorff Birrer, Nicolás Maximiliano. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; ArgentinaInt Inst Science Sintering (i I S S)2020-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/180826Hernández, Maria Florencia; Herrera, Maria Silvia; Anaya, Ricardo Javier; Martinez, Juan Manuel; Cipollone, Mariano Enrique; et al.; High macroscopic neutron capture cross section ceramics based on bauxite and Gd2O3; Int Inst Science Sintering (i I S S); Science Of Sintering; 52; 4; 11-2020; 387-4030350-820XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.2298/SOS2004387Hinfo:eu-repo/semantics/altIdentifier/url/http://www.doiserbia.nb.rs/Article.aspx?ID=0350-820X2004387Hinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:19:01Zoai:ri.conicet.gov.ar:11336/180826instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:19:01.727CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv High macroscopic neutron capture cross section ceramics based on bauxite and Gd2O3
title High macroscopic neutron capture cross section ceramics based on bauxite and Gd2O3
spellingShingle High macroscopic neutron capture cross section ceramics based on bauxite and Gd2O3
Hernández, Maria Florencia
BAUXITE
GADOLINIUM OXIDE
RARE EARTH
SMART CERAMIC PROPPANTS
THERMAL NEUTRON CAPTURE CROSS SECTION
title_short High macroscopic neutron capture cross section ceramics based on bauxite and Gd2O3
title_full High macroscopic neutron capture cross section ceramics based on bauxite and Gd2O3
title_fullStr High macroscopic neutron capture cross section ceramics based on bauxite and Gd2O3
title_full_unstemmed High macroscopic neutron capture cross section ceramics based on bauxite and Gd2O3
title_sort High macroscopic neutron capture cross section ceramics based on bauxite and Gd2O3
dc.creator.none.fl_str_mv Hernández, Maria Florencia
Herrera, Maria Silvia
Anaya, Ricardo Javier
Martinez, Juan Manuel
Cipollone, Mariano Enrique
Conconi, María Susana
Rendtorff Birrer, Nicolás Maximiliano
author Hernández, Maria Florencia
author_facet Hernández, Maria Florencia
Herrera, Maria Silvia
Anaya, Ricardo Javier
Martinez, Juan Manuel
Cipollone, Mariano Enrique
Conconi, María Susana
Rendtorff Birrer, Nicolás Maximiliano
author_role author
author2 Herrera, Maria Silvia
Anaya, Ricardo Javier
Martinez, Juan Manuel
Cipollone, Mariano Enrique
Conconi, María Susana
Rendtorff Birrer, Nicolás Maximiliano
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv BAUXITE
GADOLINIUM OXIDE
RARE EARTH
SMART CERAMIC PROPPANTS
THERMAL NEUTRON CAPTURE CROSS SECTION
topic BAUXITE
GADOLINIUM OXIDE
RARE EARTH
SMART CERAMIC PROPPANTS
THERMAL NEUTRON CAPTURE CROSS SECTION
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The effect of the addition of Gadolinium oxide (Gd2O3) up to 10 wt.% in bauxite was studied and its thermal behavior compared with pure bauxite. The incorporation of Gd2O3 is of technological interest for the design of smart traceable ceramic proppants used for unconventional gas and oil well stimulation. These high macroscopic neutron capture cross section proppants are used to obtain relevant information, such as the location and height of the created hydraulic fractures, through a neutron based detection technology. The study comprised a set of thermal and sintering behavior analyses up to 1500 °C of mixtures up to 10 wt.% addition of Gd2O3. The developed texture and microstructure was also assessed. A simple mechanical characterization was performed as well. Fully-dense pore-free microstructures were developed, with alumina and mullite as the main crystalline phases. Gadolinium secondary and ternary alumino-silicate phases were also observed after thermal treatment. These present a needle morphology that might result in reinforcement mechanisms. No important glassy phase was detected; although sintering was enhanced, the Gd2O3 oxide main role was found to be as a sintering aid rather than a strict flux agent. The mechanical behavior remained fragile with the rare oxide addition. In fact, the mechanical resistance increased up to 20 wt.% for the 10 wt.% added sample. The oxide addition together with the bauxite dehydroxilation mass loss resulted in materials with up to 1.5 x 105 (c.u.) macroscopic neutron capture cross section materials. The obtained results permit to define design strategies of high macroscopic neutron capture ceramic materials for wellbore and developed fractures description.
Fil: Hernández, Maria Florencia. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina
Fil: Herrera, Maria Silvia. YPF - Tecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Anaya, Ricardo Javier. YPF - Tecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Martinez, Juan Manuel. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina
Fil: Cipollone, Mariano Enrique. YPF - Tecnología; Argentina
Fil: Conconi, María Susana. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina
Fil: Rendtorff Birrer, Nicolás Maximiliano. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina
description The effect of the addition of Gadolinium oxide (Gd2O3) up to 10 wt.% in bauxite was studied and its thermal behavior compared with pure bauxite. The incorporation of Gd2O3 is of technological interest for the design of smart traceable ceramic proppants used for unconventional gas and oil well stimulation. These high macroscopic neutron capture cross section proppants are used to obtain relevant information, such as the location and height of the created hydraulic fractures, through a neutron based detection technology. The study comprised a set of thermal and sintering behavior analyses up to 1500 °C of mixtures up to 10 wt.% addition of Gd2O3. The developed texture and microstructure was also assessed. A simple mechanical characterization was performed as well. Fully-dense pore-free microstructures were developed, with alumina and mullite as the main crystalline phases. Gadolinium secondary and ternary alumino-silicate phases were also observed after thermal treatment. These present a needle morphology that might result in reinforcement mechanisms. No important glassy phase was detected; although sintering was enhanced, the Gd2O3 oxide main role was found to be as a sintering aid rather than a strict flux agent. The mechanical behavior remained fragile with the rare oxide addition. In fact, the mechanical resistance increased up to 20 wt.% for the 10 wt.% added sample. The oxide addition together with the bauxite dehydroxilation mass loss resulted in materials with up to 1.5 x 105 (c.u.) macroscopic neutron capture cross section materials. The obtained results permit to define design strategies of high macroscopic neutron capture ceramic materials for wellbore and developed fractures description.
publishDate 2020
dc.date.none.fl_str_mv 2020-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/180826
Hernández, Maria Florencia; Herrera, Maria Silvia; Anaya, Ricardo Javier; Martinez, Juan Manuel; Cipollone, Mariano Enrique; et al.; High macroscopic neutron capture cross section ceramics based on bauxite and Gd2O3; Int Inst Science Sintering (i I S S); Science Of Sintering; 52; 4; 11-2020; 387-403
0350-820X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/180826
identifier_str_mv Hernández, Maria Florencia; Herrera, Maria Silvia; Anaya, Ricardo Javier; Martinez, Juan Manuel; Cipollone, Mariano Enrique; et al.; High macroscopic neutron capture cross section ceramics based on bauxite and Gd2O3; Int Inst Science Sintering (i I S S); Science Of Sintering; 52; 4; 11-2020; 387-403
0350-820X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.2298/SOS2004387H
info:eu-repo/semantics/altIdentifier/url/http://www.doiserbia.nb.rs/Article.aspx?ID=0350-820X2004387H
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Int Inst Science Sintering (i I S S)
publisher.none.fl_str_mv Int Inst Science Sintering (i I S S)
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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