Hydrogen production by crude glycerol steam reforming over Ni-La-Ti mixed oxide catalysts,

Autores
Veiga, Santiago; Faccio, Ricardo; Segobia, Dario Jobino; Apesteguia, Carlos Rodolfo; Bussi, Juan
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The production of H2-rich gaseous mixtures from steam reforming of crude glycerol was investigated on ternary Ni-Le-Ti catalysts. Ni-La-Ti mixed oxides containing 15 wt% of Ni and a La/Ti atomic ratio of 1 were prepared by a coprecipitation method and characterized by a variety of physical and spectroscopic techniques. Samples were calcined in air at 700 ºC or 850 ºC for 2 h. Ni-La-Ti samples calcined at 700 ºC (NiLaTi700) showed a well definedNiO phase and an amorphous La-Ti mixed oxide, while those calcined at 850 ºC(NiLaTi850), exhibited two well defined phases of NiO and LaTiO3 perovskite, respectively. NiO was completely reduced to metallic Ni on both solids under pure H2 at 650 ºC and the resulting Ni0 phase remained as a separate phase under the steam reforming conditions. Standard catalytic tests for the steam reforming of glycerol were performed at 500 ºC or 650 ºC by feeding the fixed-bed tubular reactor with a crude glycerol:water solution containing 30 wt% glycerol. The best results were achieved on NiLaTi700 at 650 ºC, obtaining H2 yields and H2/CO2 molar ratios close to the theoretical values predicted by the steamreforming reaction stoichiometry. A slight activity decay was observed on NiLaTi700 with the progress of the reaction, probably reflecting the formation of small amounts of coke.
Fil: Veiga, Santiago. Universidad de la Republica. Facultad de Química; Uruguay
Fil: Faccio, Ricardo. Universidad de la Republica. Facultad de Química; Uruguay
Fil: Segobia, Dario Jobino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Apesteguia, Carlos Rodolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Bussi, Juan. Universidad de la Republica. Facultad de Química; Uruguay
Materia
Crude Glycerol
Hydrogen Production
Steam Reforming
Ni-La-Ti Catalysts
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/44155
Acceder
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Hydrogen production by crude glycerol steam reforming over Ni-La-Ti mixed oxide catalysts,Veiga, SantiagoFaccio, RicardoSegobia, Dario JobinoApesteguia, Carlos RodolfoBussi, JuanCrude GlycerolHydrogen ProductionSteam ReformingNi-La-Ti Catalystshttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The production of H2-rich gaseous mixtures from steam reforming of crude glycerol was investigated on ternary Ni-Le-Ti catalysts. Ni-La-Ti mixed oxides containing 15 wt% of Ni and a La/Ti atomic ratio of 1 were prepared by a coprecipitation method and characterized by a variety of physical and spectroscopic techniques. Samples were calcined in air at 700 ºC or 850 ºC for 2 h. Ni-La-Ti samples calcined at 700 ºC (NiLaTi700) showed a well definedNiO phase and an amorphous La-Ti mixed oxide, while those calcined at 850 ºC(NiLaTi850), exhibited two well defined phases of NiO and LaTiO3 perovskite, respectively. NiO was completely reduced to metallic Ni on both solids under pure H2 at 650 ºC and the resulting Ni0 phase remained as a separate phase under the steam reforming conditions. Standard catalytic tests for the steam reforming of glycerol were performed at 500 ºC or 650 ºC by feeding the fixed-bed tubular reactor with a crude glycerol:water solution containing 30 wt% glycerol. The best results were achieved on NiLaTi700 at 650 ºC, obtaining H2 yields and H2/CO2 molar ratios close to the theoretical values predicted by the steamreforming reaction stoichiometry. A slight activity decay was observed on NiLaTi700 with the progress of the reaction, probably reflecting the formation of small amounts of coke.Fil: Veiga, Santiago. Universidad de la Republica. Facultad de Química; UruguayFil: Faccio, Ricardo. Universidad de la Republica. Facultad de Química; UruguayFil: Segobia, Dario Jobino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Apesteguia, Carlos Rodolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Bussi, Juan. Universidad de la Republica. Facultad de Química; UruguayPergamon-Elsevier Science Ltd2017-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/44155Veiga, Santiago; Faccio, Ricardo; Segobia, Dario Jobino; Apesteguia, Carlos Rodolfo; Bussi, Juan; Hydrogen production by crude glycerol steam reforming over Ni-La-Ti mixed oxide catalysts,; Pergamon-Elsevier Science Ltd; International Journal of Hydrogen Energy; 42; 52; 12-2017; 30525-305340360-3199CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.ijhydene.2017.10.118info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:41:05Zoai:ri.conicet.gov.ar:11336/44155instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:41:06.233CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Hydrogen production by crude glycerol steam reforming over Ni-La-Ti mixed oxide catalysts,
title Hydrogen production by crude glycerol steam reforming over Ni-La-Ti mixed oxide catalysts,
spellingShingle Hydrogen production by crude glycerol steam reforming over Ni-La-Ti mixed oxide catalysts,
Veiga, Santiago
Crude Glycerol
Hydrogen Production
Steam Reforming
Ni-La-Ti Catalysts
title_short Hydrogen production by crude glycerol steam reforming over Ni-La-Ti mixed oxide catalysts,
title_full Hydrogen production by crude glycerol steam reforming over Ni-La-Ti mixed oxide catalysts,
title_fullStr Hydrogen production by crude glycerol steam reforming over Ni-La-Ti mixed oxide catalysts,
title_full_unstemmed Hydrogen production by crude glycerol steam reforming over Ni-La-Ti mixed oxide catalysts,
title_sort Hydrogen production by crude glycerol steam reforming over Ni-La-Ti mixed oxide catalysts,
dc.creator.none.fl_str_mv Veiga, Santiago
Faccio, Ricardo
Segobia, Dario Jobino
Apesteguia, Carlos Rodolfo
Bussi, Juan
author Veiga, Santiago
author_facet Veiga, Santiago
Faccio, Ricardo
Segobia, Dario Jobino
Apesteguia, Carlos Rodolfo
Bussi, Juan
author_role author
author2 Faccio, Ricardo
Segobia, Dario Jobino
Apesteguia, Carlos Rodolfo
Bussi, Juan
author2_role author
author
author
author
dc.subject.none.fl_str_mv Crude Glycerol
Hydrogen Production
Steam Reforming
Ni-La-Ti Catalysts
topic Crude Glycerol
Hydrogen Production
Steam Reforming
Ni-La-Ti Catalysts
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The production of H2-rich gaseous mixtures from steam reforming of crude glycerol was investigated on ternary Ni-Le-Ti catalysts. Ni-La-Ti mixed oxides containing 15 wt% of Ni and a La/Ti atomic ratio of 1 were prepared by a coprecipitation method and characterized by a variety of physical and spectroscopic techniques. Samples were calcined in air at 700 ºC or 850 ºC for 2 h. Ni-La-Ti samples calcined at 700 ºC (NiLaTi700) showed a well definedNiO phase and an amorphous La-Ti mixed oxide, while those calcined at 850 ºC(NiLaTi850), exhibited two well defined phases of NiO and LaTiO3 perovskite, respectively. NiO was completely reduced to metallic Ni on both solids under pure H2 at 650 ºC and the resulting Ni0 phase remained as a separate phase under the steam reforming conditions. Standard catalytic tests for the steam reforming of glycerol were performed at 500 ºC or 650 ºC by feeding the fixed-bed tubular reactor with a crude glycerol:water solution containing 30 wt% glycerol. The best results were achieved on NiLaTi700 at 650 ºC, obtaining H2 yields and H2/CO2 molar ratios close to the theoretical values predicted by the steamreforming reaction stoichiometry. A slight activity decay was observed on NiLaTi700 with the progress of the reaction, probably reflecting the formation of small amounts of coke.
Fil: Veiga, Santiago. Universidad de la Republica. Facultad de Química; Uruguay
Fil: Faccio, Ricardo. Universidad de la Republica. Facultad de Química; Uruguay
Fil: Segobia, Dario Jobino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Apesteguia, Carlos Rodolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Bussi, Juan. Universidad de la Republica. Facultad de Química; Uruguay
description The production of H2-rich gaseous mixtures from steam reforming of crude glycerol was investigated on ternary Ni-Le-Ti catalysts. Ni-La-Ti mixed oxides containing 15 wt% of Ni and a La/Ti atomic ratio of 1 were prepared by a coprecipitation method and characterized by a variety of physical and spectroscopic techniques. Samples were calcined in air at 700 ºC or 850 ºC for 2 h. Ni-La-Ti samples calcined at 700 ºC (NiLaTi700) showed a well definedNiO phase and an amorphous La-Ti mixed oxide, while those calcined at 850 ºC(NiLaTi850), exhibited two well defined phases of NiO and LaTiO3 perovskite, respectively. NiO was completely reduced to metallic Ni on both solids under pure H2 at 650 ºC and the resulting Ni0 phase remained as a separate phase under the steam reforming conditions. Standard catalytic tests for the steam reforming of glycerol were performed at 500 ºC or 650 ºC by feeding the fixed-bed tubular reactor with a crude glycerol:water solution containing 30 wt% glycerol. The best results were achieved on NiLaTi700 at 650 ºC, obtaining H2 yields and H2/CO2 molar ratios close to the theoretical values predicted by the steamreforming reaction stoichiometry. A slight activity decay was observed on NiLaTi700 with the progress of the reaction, probably reflecting the formation of small amounts of coke.
publishDate 2017
dc.date.none.fl_str_mv 2017-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/44155
Veiga, Santiago; Faccio, Ricardo; Segobia, Dario Jobino; Apesteguia, Carlos Rodolfo; Bussi, Juan; Hydrogen production by crude glycerol steam reforming over Ni-La-Ti mixed oxide catalysts,; Pergamon-Elsevier Science Ltd; International Journal of Hydrogen Energy; 42; 52; 12-2017; 30525-30534
0360-3199
CONICET Digital
CONICET
url http://hdl.handle.net/11336/44155
identifier_str_mv Veiga, Santiago; Faccio, Ricardo; Segobia, Dario Jobino; Apesteguia, Carlos Rodolfo; Bussi, Juan; Hydrogen production by crude glycerol steam reforming over Ni-La-Ti mixed oxide catalysts,; Pergamon-Elsevier Science Ltd; International Journal of Hydrogen Energy; 42; 52; 12-2017; 30525-30534
0360-3199
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ijhydene.2017.10.118
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.069144

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