HKUST-1 MOF: a matrix to synthesize CuO and CuO-CeO2 nanoparticle catalysts for CO oxidation

Autores
Zamaro, Juan Manuel; Pérez, Claudio Nicolás; Miro, Eduardo Ernesto; Casado, Clara; Seoane, Beatriz; Téllez, Carlos; Coronas, Joaquin
Año de publicación
2012
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The oxidation of carbon monoxide using the metal organic framework (MOF) HKUST-1 is studied. Catalytic results and characterizations by XRD, TEM, H2-TPR, SEM and LRS show that HKUST-1 itself is not effective in CO oxidation, but is activated in the reaction atmosphere segregating active 5–15 nm CuO particles upon the collapse of the MOF structure. Furthermore, the microporous structure of HKUST-1 is effective to disperse Ce precursors which, upon activation, allow the synthesis of a mixture of CuO and CeO2 nanoparticles in intimate contact. These nanoparticles present a very high activity in CO oxidation. It is shown that this synthesis route employing HKUST-1 as a matrix is useful to immobilize CuO–Ce2O nanoparticles in a monolithic reactor, while keeping a high catalytic activity.
Fil: Zamaro, Juan Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Pérez, Claudio Nicolás. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Miro, Eduardo Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Casado, Clara. Universidad de Zaragoza. Instituto de Nanociencia de Aragón; España
Fil: Seoane, Beatriz. Universidad de Zaragoza. Instituto de Nanociencia de Aragón; España
Fil: Téllez, Carlos. Universidad de Zaragoza. Instituto de Nanociencia de Aragón; España
Fil: Coronas, Joaquin. Universidad de Zaragoza. Instituto de Nanociencia de Aragón; España
Materia
Metal-Organic Framework
Cu3(Btc)2
Carbon Monoxide Oxidation
Cuo-Ceo2
Nanoparticle Synthesis
Monolith
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/53046

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network_name_str CONICET Digital (CONICET)
spelling HKUST-1 MOF: a matrix to synthesize CuO and CuO-CeO2 nanoparticle catalysts for CO oxidationZamaro, Juan ManuelPérez, Claudio NicolásMiro, Eduardo ErnestoCasado, ClaraSeoane, BeatrizTéllez, CarlosCoronas, JoaquinMetal-Organic FrameworkCu3(Btc)2Carbon Monoxide OxidationCuo-Ceo2Nanoparticle SynthesisMonolithhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The oxidation of carbon monoxide using the metal organic framework (MOF) HKUST-1 is studied. Catalytic results and characterizations by XRD, TEM, H2-TPR, SEM and LRS show that HKUST-1 itself is not effective in CO oxidation, but is activated in the reaction atmosphere segregating active 5–15 nm CuO particles upon the collapse of the MOF structure. Furthermore, the microporous structure of HKUST-1 is effective to disperse Ce precursors which, upon activation, allow the synthesis of a mixture of CuO and CeO2 nanoparticles in intimate contact. These nanoparticles present a very high activity in CO oxidation. It is shown that this synthesis route employing HKUST-1 as a matrix is useful to immobilize CuO–Ce2O nanoparticles in a monolithic reactor, while keeping a high catalytic activity.Fil: Zamaro, Juan Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Pérez, Claudio Nicolás. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Miro, Eduardo Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Casado, Clara. Universidad de Zaragoza. Instituto de Nanociencia de Aragón; EspañaFil: Seoane, Beatriz. Universidad de Zaragoza. Instituto de Nanociencia de Aragón; EspañaFil: Téllez, Carlos. Universidad de Zaragoza. Instituto de Nanociencia de Aragón; EspañaFil: Coronas, Joaquin. Universidad de Zaragoza. Instituto de Nanociencia de Aragón; EspañaElsevier Science Sa2012-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/53046Zamaro, Juan Manuel; Pérez, Claudio Nicolás; Miro, Eduardo Ernesto; Casado, Clara; Seoane, Beatriz; et al.; HKUST-1 MOF: a matrix to synthesize CuO and CuO-CeO2 nanoparticle catalysts for CO oxidation; Elsevier Science Sa; Chemical Engineering Journal; 195; 5-2012; 180-1871385-8947CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1385894712005554info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cej.2012.04.091info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:39:35Zoai:ri.conicet.gov.ar:11336/53046instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:39:35.657CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv HKUST-1 MOF: a matrix to synthesize CuO and CuO-CeO2 nanoparticle catalysts for CO oxidation
title HKUST-1 MOF: a matrix to synthesize CuO and CuO-CeO2 nanoparticle catalysts for CO oxidation
spellingShingle HKUST-1 MOF: a matrix to synthesize CuO and CuO-CeO2 nanoparticle catalysts for CO oxidation
Zamaro, Juan Manuel
Metal-Organic Framework
Cu3(Btc)2
Carbon Monoxide Oxidation
Cuo-Ceo2
Nanoparticle Synthesis
Monolith
title_short HKUST-1 MOF: a matrix to synthesize CuO and CuO-CeO2 nanoparticle catalysts for CO oxidation
title_full HKUST-1 MOF: a matrix to synthesize CuO and CuO-CeO2 nanoparticle catalysts for CO oxidation
title_fullStr HKUST-1 MOF: a matrix to synthesize CuO and CuO-CeO2 nanoparticle catalysts for CO oxidation
title_full_unstemmed HKUST-1 MOF: a matrix to synthesize CuO and CuO-CeO2 nanoparticle catalysts for CO oxidation
title_sort HKUST-1 MOF: a matrix to synthesize CuO and CuO-CeO2 nanoparticle catalysts for CO oxidation
dc.creator.none.fl_str_mv Zamaro, Juan Manuel
Pérez, Claudio Nicolás
Miro, Eduardo Ernesto
Casado, Clara
Seoane, Beatriz
Téllez, Carlos
Coronas, Joaquin
author Zamaro, Juan Manuel
author_facet Zamaro, Juan Manuel
Pérez, Claudio Nicolás
Miro, Eduardo Ernesto
Casado, Clara
Seoane, Beatriz
Téllez, Carlos
Coronas, Joaquin
author_role author
author2 Pérez, Claudio Nicolás
Miro, Eduardo Ernesto
Casado, Clara
Seoane, Beatriz
Téllez, Carlos
Coronas, Joaquin
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Metal-Organic Framework
Cu3(Btc)2
Carbon Monoxide Oxidation
Cuo-Ceo2
Nanoparticle Synthesis
Monolith
topic Metal-Organic Framework
Cu3(Btc)2
Carbon Monoxide Oxidation
Cuo-Ceo2
Nanoparticle Synthesis
Monolith
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The oxidation of carbon monoxide using the metal organic framework (MOF) HKUST-1 is studied. Catalytic results and characterizations by XRD, TEM, H2-TPR, SEM and LRS show that HKUST-1 itself is not effective in CO oxidation, but is activated in the reaction atmosphere segregating active 5–15 nm CuO particles upon the collapse of the MOF structure. Furthermore, the microporous structure of HKUST-1 is effective to disperse Ce precursors which, upon activation, allow the synthesis of a mixture of CuO and CeO2 nanoparticles in intimate contact. These nanoparticles present a very high activity in CO oxidation. It is shown that this synthesis route employing HKUST-1 as a matrix is useful to immobilize CuO–Ce2O nanoparticles in a monolithic reactor, while keeping a high catalytic activity.
Fil: Zamaro, Juan Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Pérez, Claudio Nicolás. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Miro, Eduardo Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Casado, Clara. Universidad de Zaragoza. Instituto de Nanociencia de Aragón; España
Fil: Seoane, Beatriz. Universidad de Zaragoza. Instituto de Nanociencia de Aragón; España
Fil: Téllez, Carlos. Universidad de Zaragoza. Instituto de Nanociencia de Aragón; España
Fil: Coronas, Joaquin. Universidad de Zaragoza. Instituto de Nanociencia de Aragón; España
description The oxidation of carbon monoxide using the metal organic framework (MOF) HKUST-1 is studied. Catalytic results and characterizations by XRD, TEM, H2-TPR, SEM and LRS show that HKUST-1 itself is not effective in CO oxidation, but is activated in the reaction atmosphere segregating active 5–15 nm CuO particles upon the collapse of the MOF structure. Furthermore, the microporous structure of HKUST-1 is effective to disperse Ce precursors which, upon activation, allow the synthesis of a mixture of CuO and CeO2 nanoparticles in intimate contact. These nanoparticles present a very high activity in CO oxidation. It is shown that this synthesis route employing HKUST-1 as a matrix is useful to immobilize CuO–Ce2O nanoparticles in a monolithic reactor, while keeping a high catalytic activity.
publishDate 2012
dc.date.none.fl_str_mv 2012-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/53046
Zamaro, Juan Manuel; Pérez, Claudio Nicolás; Miro, Eduardo Ernesto; Casado, Clara; Seoane, Beatriz; et al.; HKUST-1 MOF: a matrix to synthesize CuO and CuO-CeO2 nanoparticle catalysts for CO oxidation; Elsevier Science Sa; Chemical Engineering Journal; 195; 5-2012; 180-187
1385-8947
CONICET Digital
CONICET
url http://hdl.handle.net/11336/53046
identifier_str_mv Zamaro, Juan Manuel; Pérez, Claudio Nicolás; Miro, Eduardo Ernesto; Casado, Clara; Seoane, Beatriz; et al.; HKUST-1 MOF: a matrix to synthesize CuO and CuO-CeO2 nanoparticle catalysts for CO oxidation; Elsevier Science Sa; Chemical Engineering Journal; 195; 5-2012; 180-187
1385-8947
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1385894712005554
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cej.2012.04.091
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science Sa
publisher.none.fl_str_mv Elsevier Science Sa
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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