HKUST-1 MOF: a matrix to synthesize CuO and CuO-CeO2 nanoparticle catalysts for CO oxidation
- Autores
- Zamaro, Juan Manuel; Pérez, Claudio Nicolás; Miro, Eduardo Ernesto; Casado, Clara; Seoane, Beatriz; Téllez, Carlos; Coronas, Joaquin
- Año de publicación
- 2012
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The oxidation of carbon monoxide using the metal organic framework (MOF) HKUST-1 is studied. Catalytic results and characterizations by XRD, TEM, H2-TPR, SEM and LRS show that HKUST-1 itself is not effective in CO oxidation, but is activated in the reaction atmosphere segregating active 5–15 nm CuO particles upon the collapse of the MOF structure. Furthermore, the microporous structure of HKUST-1 is effective to disperse Ce precursors which, upon activation, allow the synthesis of a mixture of CuO and CeO2 nanoparticles in intimate contact. These nanoparticles present a very high activity in CO oxidation. It is shown that this synthesis route employing HKUST-1 as a matrix is useful to immobilize CuO–Ce2O nanoparticles in a monolithic reactor, while keeping a high catalytic activity.
Fil: Zamaro, Juan Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Pérez, Claudio Nicolás. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Miro, Eduardo Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Casado, Clara. Universidad de Zaragoza. Instituto de Nanociencia de Aragón; España
Fil: Seoane, Beatriz. Universidad de Zaragoza. Instituto de Nanociencia de Aragón; España
Fil: Téllez, Carlos. Universidad de Zaragoza. Instituto de Nanociencia de Aragón; España
Fil: Coronas, Joaquin. Universidad de Zaragoza. Instituto de Nanociencia de Aragón; España - Materia
-
Metal-Organic Framework
Cu3(Btc)2
Carbon Monoxide Oxidation
Cuo-Ceo2
Nanoparticle Synthesis
Monolith - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/53046
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HKUST-1 MOF: a matrix to synthesize CuO and CuO-CeO2 nanoparticle catalysts for CO oxidationZamaro, Juan ManuelPérez, Claudio NicolásMiro, Eduardo ErnestoCasado, ClaraSeoane, BeatrizTéllez, CarlosCoronas, JoaquinMetal-Organic FrameworkCu3(Btc)2Carbon Monoxide OxidationCuo-Ceo2Nanoparticle SynthesisMonolithhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The oxidation of carbon monoxide using the metal organic framework (MOF) HKUST-1 is studied. Catalytic results and characterizations by XRD, TEM, H2-TPR, SEM and LRS show that HKUST-1 itself is not effective in CO oxidation, but is activated in the reaction atmosphere segregating active 5–15 nm CuO particles upon the collapse of the MOF structure. Furthermore, the microporous structure of HKUST-1 is effective to disperse Ce precursors which, upon activation, allow the synthesis of a mixture of CuO and CeO2 nanoparticles in intimate contact. These nanoparticles present a very high activity in CO oxidation. It is shown that this synthesis route employing HKUST-1 as a matrix is useful to immobilize CuO–Ce2O nanoparticles in a monolithic reactor, while keeping a high catalytic activity.Fil: Zamaro, Juan Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Pérez, Claudio Nicolás. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Miro, Eduardo Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Casado, Clara. Universidad de Zaragoza. Instituto de Nanociencia de Aragón; EspañaFil: Seoane, Beatriz. Universidad de Zaragoza. Instituto de Nanociencia de Aragón; EspañaFil: Téllez, Carlos. Universidad de Zaragoza. Instituto de Nanociencia de Aragón; EspañaFil: Coronas, Joaquin. Universidad de Zaragoza. Instituto de Nanociencia de Aragón; EspañaElsevier Science Sa2012-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/53046Zamaro, Juan Manuel; Pérez, Claudio Nicolás; Miro, Eduardo Ernesto; Casado, Clara; Seoane, Beatriz; et al.; HKUST-1 MOF: a matrix to synthesize CuO and CuO-CeO2 nanoparticle catalysts for CO oxidation; Elsevier Science Sa; Chemical Engineering Journal; 195; 5-2012; 180-1871385-8947CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1385894712005554info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cej.2012.04.091info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:39:35Zoai:ri.conicet.gov.ar:11336/53046instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:39:35.657CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
HKUST-1 MOF: a matrix to synthesize CuO and CuO-CeO2 nanoparticle catalysts for CO oxidation |
title |
HKUST-1 MOF: a matrix to synthesize CuO and CuO-CeO2 nanoparticle catalysts for CO oxidation |
spellingShingle |
HKUST-1 MOF: a matrix to synthesize CuO and CuO-CeO2 nanoparticle catalysts for CO oxidation Zamaro, Juan Manuel Metal-Organic Framework Cu3(Btc)2 Carbon Monoxide Oxidation Cuo-Ceo2 Nanoparticle Synthesis Monolith |
title_short |
HKUST-1 MOF: a matrix to synthesize CuO and CuO-CeO2 nanoparticle catalysts for CO oxidation |
title_full |
HKUST-1 MOF: a matrix to synthesize CuO and CuO-CeO2 nanoparticle catalysts for CO oxidation |
title_fullStr |
HKUST-1 MOF: a matrix to synthesize CuO and CuO-CeO2 nanoparticle catalysts for CO oxidation |
title_full_unstemmed |
HKUST-1 MOF: a matrix to synthesize CuO and CuO-CeO2 nanoparticle catalysts for CO oxidation |
title_sort |
HKUST-1 MOF: a matrix to synthesize CuO and CuO-CeO2 nanoparticle catalysts for CO oxidation |
dc.creator.none.fl_str_mv |
Zamaro, Juan Manuel Pérez, Claudio Nicolás Miro, Eduardo Ernesto Casado, Clara Seoane, Beatriz Téllez, Carlos Coronas, Joaquin |
author |
Zamaro, Juan Manuel |
author_facet |
Zamaro, Juan Manuel Pérez, Claudio Nicolás Miro, Eduardo Ernesto Casado, Clara Seoane, Beatriz Téllez, Carlos Coronas, Joaquin |
author_role |
author |
author2 |
Pérez, Claudio Nicolás Miro, Eduardo Ernesto Casado, Clara Seoane, Beatriz Téllez, Carlos Coronas, Joaquin |
author2_role |
author author author author author author |
dc.subject.none.fl_str_mv |
Metal-Organic Framework Cu3(Btc)2 Carbon Monoxide Oxidation Cuo-Ceo2 Nanoparticle Synthesis Monolith |
topic |
Metal-Organic Framework Cu3(Btc)2 Carbon Monoxide Oxidation Cuo-Ceo2 Nanoparticle Synthesis Monolith |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
The oxidation of carbon monoxide using the metal organic framework (MOF) HKUST-1 is studied. Catalytic results and characterizations by XRD, TEM, H2-TPR, SEM and LRS show that HKUST-1 itself is not effective in CO oxidation, but is activated in the reaction atmosphere segregating active 5–15 nm CuO particles upon the collapse of the MOF structure. Furthermore, the microporous structure of HKUST-1 is effective to disperse Ce precursors which, upon activation, allow the synthesis of a mixture of CuO and CeO2 nanoparticles in intimate contact. These nanoparticles present a very high activity in CO oxidation. It is shown that this synthesis route employing HKUST-1 as a matrix is useful to immobilize CuO–Ce2O nanoparticles in a monolithic reactor, while keeping a high catalytic activity. Fil: Zamaro, Juan Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina Fil: Pérez, Claudio Nicolás. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina Fil: Miro, Eduardo Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina Fil: Casado, Clara. Universidad de Zaragoza. Instituto de Nanociencia de Aragón; España Fil: Seoane, Beatriz. Universidad de Zaragoza. Instituto de Nanociencia de Aragón; España Fil: Téllez, Carlos. Universidad de Zaragoza. Instituto de Nanociencia de Aragón; España Fil: Coronas, Joaquin. Universidad de Zaragoza. Instituto de Nanociencia de Aragón; España |
description |
The oxidation of carbon monoxide using the metal organic framework (MOF) HKUST-1 is studied. Catalytic results and characterizations by XRD, TEM, H2-TPR, SEM and LRS show that HKUST-1 itself is not effective in CO oxidation, but is activated in the reaction atmosphere segregating active 5–15 nm CuO particles upon the collapse of the MOF structure. Furthermore, the microporous structure of HKUST-1 is effective to disperse Ce precursors which, upon activation, allow the synthesis of a mixture of CuO and CeO2 nanoparticles in intimate contact. These nanoparticles present a very high activity in CO oxidation. It is shown that this synthesis route employing HKUST-1 as a matrix is useful to immobilize CuO–Ce2O nanoparticles in a monolithic reactor, while keeping a high catalytic activity. |
publishDate |
2012 |
dc.date.none.fl_str_mv |
2012-05 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/53046 Zamaro, Juan Manuel; Pérez, Claudio Nicolás; Miro, Eduardo Ernesto; Casado, Clara; Seoane, Beatriz; et al.; HKUST-1 MOF: a matrix to synthesize CuO and CuO-CeO2 nanoparticle catalysts for CO oxidation; Elsevier Science Sa; Chemical Engineering Journal; 195; 5-2012; 180-187 1385-8947 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/53046 |
identifier_str_mv |
Zamaro, Juan Manuel; Pérez, Claudio Nicolás; Miro, Eduardo Ernesto; Casado, Clara; Seoane, Beatriz; et al.; HKUST-1 MOF: a matrix to synthesize CuO and CuO-CeO2 nanoparticle catalysts for CO oxidation; Elsevier Science Sa; Chemical Engineering Journal; 195; 5-2012; 180-187 1385-8947 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1385894712005554 info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cej.2012.04.091 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science Sa |
publisher.none.fl_str_mv |
Elsevier Science Sa |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613252792713216 |
score |
13.070432 |