Removal of humic acid by organo-montmorillonites: Influence of surfactant loading and chain length of alkylammonium cations

Autores
Fernandez, Mariela Alejandra; Curutchet, Gustavo Andres; Torres Sanchez, Rosa Maria
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this study, the characterization and adsorption properties of montmorillonite (MMT) and organomontmorillonites with different surfactant/cationic exchange capacity (CEC) ratios (1 and 2) of tetradecyl trimethylammonium (TDTMA+) and hexadecyl trimethylammonium (HDTMA+) cations were evaluated. The particle apparent diameter, determined by laser and scanning electron microscopy showed aggregate formation, which varied with loading and cation length of the surfactant used. X-ray diffraction analysis revealed the formation of a pseudotrilayer arrangement of both surfactants in the interlayer space, FTIR showed the characteristic bands of the surfactants and micelle formations, and zeta potential determinations indicated neutral or negative surface charge values, except for sample obtained with one CEC concentration exchanged with HDTMA+ (HDTMA1-MMT) where a charge reversal to positive was found. Higher adsorption amounts of humic acid (HA) were found for HDTMA1-MMT and TDTMA1-MMT samples than for MMT sample, while the increase in the loading of both surfactants decreased the amounts of HA adsorbed could be assigned to a higher micelle formation and different packing density of alkyl chain, in the external surface. The correlation found between the total surface area and negative zeta potential values and the HA adsorption rate, within each surfactant, indicated the strong influence that these properties have on HA adsorption.
Fil: Fernandez, Mariela Alejandra. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina
Fil: Curutchet, Gustavo Andres. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología. Laboratorio de Análisis Ambiental; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Torres Sanchez, Rosa Maria. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina
Materia
ADSORPTION
HUMIC ACID
ORGANO-MONTMORILLONITES
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/99918
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/99918
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Removal of humic acid by organo-montmorillonites: Influence of surfactant loading and chain length of alkylammonium cationsFernandez, Mariela AlejandraCurutchet, Gustavo AndresTorres Sanchez, Rosa MariaADSORPTIONHUMIC ACIDORGANO-MONTMORILLONITEShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1In this study, the characterization and adsorption properties of montmorillonite (MMT) and organomontmorillonites with different surfactant/cationic exchange capacity (CEC) ratios (1 and 2) of tetradecyl trimethylammonium (TDTMA+) and hexadecyl trimethylammonium (HDTMA+) cations were evaluated. The particle apparent diameter, determined by laser and scanning electron microscopy showed aggregate formation, which varied with loading and cation length of the surfactant used. X-ray diffraction analysis revealed the formation of a pseudotrilayer arrangement of both surfactants in the interlayer space, FTIR showed the characteristic bands of the surfactants and micelle formations, and zeta potential determinations indicated neutral or negative surface charge values, except for sample obtained with one CEC concentration exchanged with HDTMA+ (HDTMA1-MMT) where a charge reversal to positive was found. Higher adsorption amounts of humic acid (HA) were found for HDTMA1-MMT and TDTMA1-MMT samples than for MMT sample, while the increase in the loading of both surfactants decreased the amounts of HA adsorbed could be assigned to a higher micelle formation and different packing density of alkyl chain, in the external surface. The correlation found between the total surface area and negative zeta potential values and the HA adsorption rate, within each surfactant, indicated the strong influence that these properties have on HA adsorption.Fil: Fernandez, Mariela Alejandra. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; ArgentinaFil: Curutchet, Gustavo Andres. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología. Laboratorio de Análisis Ambiental; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Torres Sanchez, Rosa Maria. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; ArgentinaSpringer2014-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/99918Fernandez, Mariela Alejandra; Curutchet, Gustavo Andres; Torres Sanchez, Rosa Maria; Removal of humic acid by organo-montmorillonites: Influence of surfactant loading and chain length of alkylammonium cations; Springer; Water, Air and Soil Pollution; 225; 6; 5-2014; 1987-19980049-6979CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1007/s11270-014-1987-9info:eu-repo/semantics/altIdentifier/doi/10.1007/s11270-014-1987-9info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:02:03Zoai:ri.conicet.gov.ar:11336/99918instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:02:03.828CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Removal of humic acid by organo-montmorillonites: Influence of surfactant loading and chain length of alkylammonium cations
title Removal of humic acid by organo-montmorillonites: Influence of surfactant loading and chain length of alkylammonium cations
spellingShingle Removal of humic acid by organo-montmorillonites: Influence of surfactant loading and chain length of alkylammonium cations
Fernandez, Mariela Alejandra
ADSORPTION
HUMIC ACID
ORGANO-MONTMORILLONITES
title_short Removal of humic acid by organo-montmorillonites: Influence of surfactant loading and chain length of alkylammonium cations
title_full Removal of humic acid by organo-montmorillonites: Influence of surfactant loading and chain length of alkylammonium cations
title_fullStr Removal of humic acid by organo-montmorillonites: Influence of surfactant loading and chain length of alkylammonium cations
title_full_unstemmed Removal of humic acid by organo-montmorillonites: Influence of surfactant loading and chain length of alkylammonium cations
title_sort Removal of humic acid by organo-montmorillonites: Influence of surfactant loading and chain length of alkylammonium cations
dc.creator.none.fl_str_mv Fernandez, Mariela Alejandra
Curutchet, Gustavo Andres
Torres Sanchez, Rosa Maria
author Fernandez, Mariela Alejandra
author_facet Fernandez, Mariela Alejandra
Curutchet, Gustavo Andres
Torres Sanchez, Rosa Maria
author_role author
author2 Curutchet, Gustavo Andres
Torres Sanchez, Rosa Maria
author2_role author
author
dc.subject.none.fl_str_mv ADSORPTION
HUMIC ACID
ORGANO-MONTMORILLONITES
topic ADSORPTION
HUMIC ACID
ORGANO-MONTMORILLONITES
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv In this study, the characterization and adsorption properties of montmorillonite (MMT) and organomontmorillonites with different surfactant/cationic exchange capacity (CEC) ratios (1 and 2) of tetradecyl trimethylammonium (TDTMA+) and hexadecyl trimethylammonium (HDTMA+) cations were evaluated. The particle apparent diameter, determined by laser and scanning electron microscopy showed aggregate formation, which varied with loading and cation length of the surfactant used. X-ray diffraction analysis revealed the formation of a pseudotrilayer arrangement of both surfactants in the interlayer space, FTIR showed the characteristic bands of the surfactants and micelle formations, and zeta potential determinations indicated neutral or negative surface charge values, except for sample obtained with one CEC concentration exchanged with HDTMA+ (HDTMA1-MMT) where a charge reversal to positive was found. Higher adsorption amounts of humic acid (HA) were found for HDTMA1-MMT and TDTMA1-MMT samples than for MMT sample, while the increase in the loading of both surfactants decreased the amounts of HA adsorbed could be assigned to a higher micelle formation and different packing density of alkyl chain, in the external surface. The correlation found between the total surface area and negative zeta potential values and the HA adsorption rate, within each surfactant, indicated the strong influence that these properties have on HA adsorption.
Fil: Fernandez, Mariela Alejandra. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina
Fil: Curutchet, Gustavo Andres. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología. Laboratorio de Análisis Ambiental; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Torres Sanchez, Rosa Maria. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina
description In this study, the characterization and adsorption properties of montmorillonite (MMT) and organomontmorillonites with different surfactant/cationic exchange capacity (CEC) ratios (1 and 2) of tetradecyl trimethylammonium (TDTMA+) and hexadecyl trimethylammonium (HDTMA+) cations were evaluated. The particle apparent diameter, determined by laser and scanning electron microscopy showed aggregate formation, which varied with loading and cation length of the surfactant used. X-ray diffraction analysis revealed the formation of a pseudotrilayer arrangement of both surfactants in the interlayer space, FTIR showed the characteristic bands of the surfactants and micelle formations, and zeta potential determinations indicated neutral or negative surface charge values, except for sample obtained with one CEC concentration exchanged with HDTMA+ (HDTMA1-MMT) where a charge reversal to positive was found. Higher adsorption amounts of humic acid (HA) were found for HDTMA1-MMT and TDTMA1-MMT samples than for MMT sample, while the increase in the loading of both surfactants decreased the amounts of HA adsorbed could be assigned to a higher micelle formation and different packing density of alkyl chain, in the external surface. The correlation found between the total surface area and negative zeta potential values and the HA adsorption rate, within each surfactant, indicated the strong influence that these properties have on HA adsorption.
publishDate 2014
dc.date.none.fl_str_mv 2014-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/99918
Fernandez, Mariela Alejandra; Curutchet, Gustavo Andres; Torres Sanchez, Rosa Maria; Removal of humic acid by organo-montmorillonites: Influence of surfactant loading and chain length of alkylammonium cations; Springer; Water, Air and Soil Pollution; 225; 6; 5-2014; 1987-1998
0049-6979
CONICET Digital
CONICET
url http://hdl.handle.net/11336/99918
identifier_str_mv Fernandez, Mariela Alejandra; Curutchet, Gustavo Andres; Torres Sanchez, Rosa Maria; Removal of humic acid by organo-montmorillonites: Influence of surfactant loading and chain length of alkylammonium cations; Springer; Water, Air and Soil Pollution; 225; 6; 5-2014; 1987-1998
0049-6979
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1007/s11270-014-1987-9
info:eu-repo/semantics/altIdentifier/doi/10.1007/s11270-014-1987-9
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Springer
publisher.none.fl_str_mv Springer
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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