Fluorous molecules for dye-sensitized solar cells: Synthesis and properties of di-branched, di-anchoring organic sensitizers containing fluorene subunits

Autores
Pecnikaj, Ilir; Minudri, Daniela; Otero, Luis Alberto; Fungo, Fernando Gabriel; Cavazzini, Marco; Orlandi, Simonetta; Pozzi, Gianluca
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Four organic sensitizers having a di-branched molecular structure D-(π-A)2 (D = para-substituted arylamine, π = 9,9-dibutylfluorene, A = cyanoacrylic acid) were synthesized, characterized, and applied in the development of dye-sensitized solar cells (DSSCs). It was found that the nature of the para-substituent affects the behavior of these sensitizers. In particular, the introduction of a C11 linear fluorous alkoxy group led to an improvement in the power conversion efficiency with respect to the commonly employed nonfluorous alkoxy substituents.
Fil: Pecnikaj, Ilir. Catholic University Our Lady Of Good Counsel; Albania
Fil: Minudri, Daniela. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina
Fil: Otero, Luis Alberto. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina
Fil: Fungo, Fernando Gabriel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina
Fil: Cavazzini, Marco. Consiglio Nazionale delle Ricerche; Italia
Fil: Orlandi, Simonetta. Consiglio Nazionale delle Ricerche; Italia
Fil: Pozzi, Gianluca. Consiglio Nazionale delle Ricerche; Italia
Materia
organic sensitizers
dye-sensitized solar cells (DSSCs)
di-anchoring
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/75122
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/75122
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Fluorous molecules for dye-sensitized solar cells: Synthesis and properties of di-branched, di-anchoring organic sensitizers containing fluorene subunitsPecnikaj, IlirMinudri, DanielaOtero, Luis AlbertoFungo, Fernando GabrielCavazzini, MarcoOrlandi, SimonettaPozzi, Gianlucaorganic sensitizersdye-sensitized solar cells (DSSCs)di-anchoringhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Four organic sensitizers having a di-branched molecular structure D-(π-A)2 (D = para-substituted arylamine, π = 9,9-dibutylfluorene, A = cyanoacrylic acid) were synthesized, characterized, and applied in the development of dye-sensitized solar cells (DSSCs). It was found that the nature of the para-substituent affects the behavior of these sensitizers. In particular, the introduction of a C11 linear fluorous alkoxy group led to an improvement in the power conversion efficiency with respect to the commonly employed nonfluorous alkoxy substituents.Fil: Pecnikaj, Ilir. Catholic University Our Lady Of Good Counsel; AlbaniaFil: Minudri, Daniela. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; ArgentinaFil: Otero, Luis Alberto. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; ArgentinaFil: Fungo, Fernando Gabriel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; ArgentinaFil: Cavazzini, Marco. Consiglio Nazionale delle Ricerche; ItaliaFil: Orlandi, Simonetta. Consiglio Nazionale delle Ricerche; ItaliaFil: Pozzi, Gianluca. Consiglio Nazionale delle Ricerche; ItaliaRoyal Society of Chemistry2017-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/75122Pecnikaj, Ilir; Minudri, Daniela; Otero, Luis Alberto; Fungo, Fernando Gabriel; Cavazzini, Marco; et al.; Fluorous molecules for dye-sensitized solar cells: Synthesis and properties of di-branched, di-anchoring organic sensitizers containing fluorene subunits; Royal Society of Chemistry; New Journal of Chemistry; 41; 15; 6-2017; 7729-77381144-05461369-9261CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://pubs.rsc.org/en/Content/ArticleLanding/2017/NJ/C7NJ01516Jinfo:eu-repo/semantics/altIdentifier/doi/10.1039/C7NJ01516Jinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:55:44Zoai:ri.conicet.gov.ar:11336/75122instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:55:44.341CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Fluorous molecules for dye-sensitized solar cells: Synthesis and properties of di-branched, di-anchoring organic sensitizers containing fluorene subunits
title Fluorous molecules for dye-sensitized solar cells: Synthesis and properties of di-branched, di-anchoring organic sensitizers containing fluorene subunits
spellingShingle Fluorous molecules for dye-sensitized solar cells: Synthesis and properties of di-branched, di-anchoring organic sensitizers containing fluorene subunits
Pecnikaj, Ilir
organic sensitizers
dye-sensitized solar cells (DSSCs)
di-anchoring
title_short Fluorous molecules for dye-sensitized solar cells: Synthesis and properties of di-branched, di-anchoring organic sensitizers containing fluorene subunits
title_full Fluorous molecules for dye-sensitized solar cells: Synthesis and properties of di-branched, di-anchoring organic sensitizers containing fluorene subunits
title_fullStr Fluorous molecules for dye-sensitized solar cells: Synthesis and properties of di-branched, di-anchoring organic sensitizers containing fluorene subunits
title_full_unstemmed Fluorous molecules for dye-sensitized solar cells: Synthesis and properties of di-branched, di-anchoring organic sensitizers containing fluorene subunits
title_sort Fluorous molecules for dye-sensitized solar cells: Synthesis and properties of di-branched, di-anchoring organic sensitizers containing fluorene subunits
dc.creator.none.fl_str_mv Pecnikaj, Ilir
Minudri, Daniela
Otero, Luis Alberto
Fungo, Fernando Gabriel
Cavazzini, Marco
Orlandi, Simonetta
Pozzi, Gianluca
author Pecnikaj, Ilir
author_facet Pecnikaj, Ilir
Minudri, Daniela
Otero, Luis Alberto
Fungo, Fernando Gabriel
Cavazzini, Marco
Orlandi, Simonetta
Pozzi, Gianluca
author_role author
author2 Minudri, Daniela
Otero, Luis Alberto
Fungo, Fernando Gabriel
Cavazzini, Marco
Orlandi, Simonetta
Pozzi, Gianluca
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv organic sensitizers
dye-sensitized solar cells (DSSCs)
di-anchoring
topic organic sensitizers
dye-sensitized solar cells (DSSCs)
di-anchoring
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Four organic sensitizers having a di-branched molecular structure D-(π-A)2 (D = para-substituted arylamine, π = 9,9-dibutylfluorene, A = cyanoacrylic acid) were synthesized, characterized, and applied in the development of dye-sensitized solar cells (DSSCs). It was found that the nature of the para-substituent affects the behavior of these sensitizers. In particular, the introduction of a C11 linear fluorous alkoxy group led to an improvement in the power conversion efficiency with respect to the commonly employed nonfluorous alkoxy substituents.
Fil: Pecnikaj, Ilir. Catholic University Our Lady Of Good Counsel; Albania
Fil: Minudri, Daniela. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina
Fil: Otero, Luis Alberto. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina
Fil: Fungo, Fernando Gabriel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina
Fil: Cavazzini, Marco. Consiglio Nazionale delle Ricerche; Italia
Fil: Orlandi, Simonetta. Consiglio Nazionale delle Ricerche; Italia
Fil: Pozzi, Gianluca. Consiglio Nazionale delle Ricerche; Italia
description Four organic sensitizers having a di-branched molecular structure D-(π-A)2 (D = para-substituted arylamine, π = 9,9-dibutylfluorene, A = cyanoacrylic acid) were synthesized, characterized, and applied in the development of dye-sensitized solar cells (DSSCs). It was found that the nature of the para-substituent affects the behavior of these sensitizers. In particular, the introduction of a C11 linear fluorous alkoxy group led to an improvement in the power conversion efficiency with respect to the commonly employed nonfluorous alkoxy substituents.
publishDate 2017
dc.date.none.fl_str_mv 2017-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/75122
Pecnikaj, Ilir; Minudri, Daniela; Otero, Luis Alberto; Fungo, Fernando Gabriel; Cavazzini, Marco; et al.; Fluorous molecules for dye-sensitized solar cells: Synthesis and properties of di-branched, di-anchoring organic sensitizers containing fluorene subunits; Royal Society of Chemistry; New Journal of Chemistry; 41; 15; 6-2017; 7729-7738
1144-0546
1369-9261
CONICET Digital
CONICET
url http://hdl.handle.net/11336/75122
identifier_str_mv Pecnikaj, Ilir; Minudri, Daniela; Otero, Luis Alberto; Fungo, Fernando Gabriel; Cavazzini, Marco; et al.; Fluorous molecules for dye-sensitized solar cells: Synthesis and properties of di-branched, di-anchoring organic sensitizers containing fluorene subunits; Royal Society of Chemistry; New Journal of Chemistry; 41; 15; 6-2017; 7729-7738
1144-0546
1369-9261
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://pubs.rsc.org/en/Content/ArticleLanding/2017/NJ/C7NJ01516J
info:eu-repo/semantics/altIdentifier/doi/10.1039/C7NJ01516J
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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