Study of Kβ X-ray emission spectroscopy applied to Mn(2−x)V(1+x)O4 (x=0 and 1/3) oxyspinel and comparison with XANES

Autores
Ceppi, Sergio Andres; Mesquita, A.; Pomiro, Fernando; Pannunzio Miner, Elisa Victoria; Tirao, German Alfredo
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Oxidation state and coordination of transition metal cations seems to be hard to assess when considering multiple cations, each one with different possible oxidation states. In fact, this is the case of the spinel-type double oxides family. High resolution Kβ X-ray fluorescence spectra were measured in Mn(2−x)V(1+x)O4 (x=0 and 13) spinels-type double oxides in order to determine the oxidation state and coordination of V and Mn cations. The relative intensity of radiative Auger effect KM2,3M4,5 to the total intensity and the integral absolute difference value were used as reference parameters for the characterization of Mn oxidation states. The coordination of Mn ions was inferred by the intensity of the Kβ5 line. In the case of V compounds, it was used as the intensity of the line Kβ′ relative to the total area of Kβ region. The obtained results were further compared with X-ray absorption spectra analysis, showing good agreements regarding the oxidation state characterization. However, there were found some discrepancies in coordination, due to customary oversimplifications in the Kβ5 line origin. The obtained results might represent valuable and useful data for chemical scopes of characterizing spinel-type oxides family.
Fil: Ceppi, Sergio Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina
Fil: Mesquita, A.. Universidade Estadual Paulista Julio de Mesquita Filho; Brasil
Fil: Pomiro, Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Pannunzio Miner, Elisa Victoria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Tirao, German Alfredo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina
Materia
Oxides
Xafs
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/31380
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Study of Kβ X-ray emission spectroscopy applied to Mn(2−x)V(1+x)O4 (x=0 and 1/3) oxyspinel and comparison with XANESCeppi, Sergio AndresMesquita, A.Pomiro, FernandoPannunzio Miner, Elisa VictoriaTirao, German AlfredoOxidesXafshttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1Oxidation state and coordination of transition metal cations seems to be hard to assess when considering multiple cations, each one with different possible oxidation states. In fact, this is the case of the spinel-type double oxides family. High resolution Kβ X-ray fluorescence spectra were measured in Mn(2−x)V(1+x)O4 (x=0 and 13) spinels-type double oxides in order to determine the oxidation state and coordination of V and Mn cations. The relative intensity of radiative Auger effect KM2,3M4,5 to the total intensity and the integral absolute difference value were used as reference parameters for the characterization of Mn oxidation states. The coordination of Mn ions was inferred by the intensity of the Kβ5 line. In the case of V compounds, it was used as the intensity of the line Kβ′ relative to the total area of Kβ region. The obtained results were further compared with X-ray absorption spectra analysis, showing good agreements regarding the oxidation state characterization. However, there were found some discrepancies in coordination, due to customary oversimplifications in the Kβ5 line origin. The obtained results might represent valuable and useful data for chemical scopes of characterizing spinel-type oxides family.Fil: Ceppi, Sergio Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; ArgentinaFil: Mesquita, A.. Universidade Estadual Paulista Julio de Mesquita Filho; BrasilFil: Pomiro, Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Pannunzio Miner, Elisa Victoria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Tirao, German Alfredo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; ArgentinaPergamon-Elsevier Science Ltd.2014-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/31380Tirao, German Alfredo; Pannunzio Miner, Elisa Victoria; Pomiro, Fernando; Mesquita, A.; Ceppi, Sergio Andres; Study of Kβ X-ray emission spectroscopy applied to Mn(2−x)V(1+x)O4 (x=0 and 1/3) oxyspinel and comparison with XANES; Pergamon-Elsevier Science Ltd.; Journal of Physics and Chemistry of Solids; 75; 3; 1-2014; 366-3730022-3697CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.jpcs.2013.11.002info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0022369713003715info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:12:47Zoai:ri.conicet.gov.ar:11336/31380instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:12:47.369CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Study of Kβ X-ray emission spectroscopy applied to Mn(2−x)V(1+x)O4 (x=0 and 1/3) oxyspinel and comparison with XANES
title Study of Kβ X-ray emission spectroscopy applied to Mn(2−x)V(1+x)O4 (x=0 and 1/3) oxyspinel and comparison with XANES
spellingShingle Study of Kβ X-ray emission spectroscopy applied to Mn(2−x)V(1+x)O4 (x=0 and 1/3) oxyspinel and comparison with XANES
Ceppi, Sergio Andres
Oxides
Xafs
title_short Study of Kβ X-ray emission spectroscopy applied to Mn(2−x)V(1+x)O4 (x=0 and 1/3) oxyspinel and comparison with XANES
title_full Study of Kβ X-ray emission spectroscopy applied to Mn(2−x)V(1+x)O4 (x=0 and 1/3) oxyspinel and comparison with XANES
title_fullStr Study of Kβ X-ray emission spectroscopy applied to Mn(2−x)V(1+x)O4 (x=0 and 1/3) oxyspinel and comparison with XANES
title_full_unstemmed Study of Kβ X-ray emission spectroscopy applied to Mn(2−x)V(1+x)O4 (x=0 and 1/3) oxyspinel and comparison with XANES
title_sort Study of Kβ X-ray emission spectroscopy applied to Mn(2−x)V(1+x)O4 (x=0 and 1/3) oxyspinel and comparison with XANES
dc.creator.none.fl_str_mv Ceppi, Sergio Andres
Mesquita, A.
Pomiro, Fernando
Pannunzio Miner, Elisa Victoria
Tirao, German Alfredo
author Ceppi, Sergio Andres
author_facet Ceppi, Sergio Andres
Mesquita, A.
Pomiro, Fernando
Pannunzio Miner, Elisa Victoria
Tirao, German Alfredo
author_role author
author2 Mesquita, A.
Pomiro, Fernando
Pannunzio Miner, Elisa Victoria
Tirao, German Alfredo
author2_role author
author
author
author
dc.subject.none.fl_str_mv Oxides
Xafs
topic Oxides
Xafs
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Oxidation state and coordination of transition metal cations seems to be hard to assess when considering multiple cations, each one with different possible oxidation states. In fact, this is the case of the spinel-type double oxides family. High resolution Kβ X-ray fluorescence spectra were measured in Mn(2−x)V(1+x)O4 (x=0 and 13) spinels-type double oxides in order to determine the oxidation state and coordination of V and Mn cations. The relative intensity of radiative Auger effect KM2,3M4,5 to the total intensity and the integral absolute difference value were used as reference parameters for the characterization of Mn oxidation states. The coordination of Mn ions was inferred by the intensity of the Kβ5 line. In the case of V compounds, it was used as the intensity of the line Kβ′ relative to the total area of Kβ region. The obtained results were further compared with X-ray absorption spectra analysis, showing good agreements regarding the oxidation state characterization. However, there were found some discrepancies in coordination, due to customary oversimplifications in the Kβ5 line origin. The obtained results might represent valuable and useful data for chemical scopes of characterizing spinel-type oxides family.
Fil: Ceppi, Sergio Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina
Fil: Mesquita, A.. Universidade Estadual Paulista Julio de Mesquita Filho; Brasil
Fil: Pomiro, Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Pannunzio Miner, Elisa Victoria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Tirao, German Alfredo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina
description Oxidation state and coordination of transition metal cations seems to be hard to assess when considering multiple cations, each one with different possible oxidation states. In fact, this is the case of the spinel-type double oxides family. High resolution Kβ X-ray fluorescence spectra were measured in Mn(2−x)V(1+x)O4 (x=0 and 13) spinels-type double oxides in order to determine the oxidation state and coordination of V and Mn cations. The relative intensity of radiative Auger effect KM2,3M4,5 to the total intensity and the integral absolute difference value were used as reference parameters for the characterization of Mn oxidation states. The coordination of Mn ions was inferred by the intensity of the Kβ5 line. In the case of V compounds, it was used as the intensity of the line Kβ′ relative to the total area of Kβ region. The obtained results were further compared with X-ray absorption spectra analysis, showing good agreements regarding the oxidation state characterization. However, there were found some discrepancies in coordination, due to customary oversimplifications in the Kβ5 line origin. The obtained results might represent valuable and useful data for chemical scopes of characterizing spinel-type oxides family.
publishDate 2014
dc.date.none.fl_str_mv 2014-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/31380
Tirao, German Alfredo; Pannunzio Miner, Elisa Victoria; Pomiro, Fernando; Mesquita, A.; Ceppi, Sergio Andres; Study of Kβ X-ray emission spectroscopy applied to Mn(2−x)V(1+x)O4 (x=0 and 1/3) oxyspinel and comparison with XANES; Pergamon-Elsevier Science Ltd.; Journal of Physics and Chemistry of Solids; 75; 3; 1-2014; 366-373
0022-3697
CONICET Digital
CONICET
url http://hdl.handle.net/11336/31380
identifier_str_mv Tirao, German Alfredo; Pannunzio Miner, Elisa Victoria; Pomiro, Fernando; Mesquita, A.; Ceppi, Sergio Andres; Study of Kβ X-ray emission spectroscopy applied to Mn(2−x)V(1+x)O4 (x=0 and 1/3) oxyspinel and comparison with XANES; Pergamon-Elsevier Science Ltd.; Journal of Physics and Chemistry of Solids; 75; 3; 1-2014; 366-373
0022-3697
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jpcs.2013.11.002
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0022369713003715
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd.
publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd.
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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